100-96-9

Basic information

• Product Name: 1,3-Benzenediamine, 5-methoxy-
• CAS NO: 100-96-9
• Molecular Formula: C7H10N2O
• Molecular Weight: 138.169
• Mol File: 100-96-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1,3-Benzenediamine, 5-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Benzenediamine, 5-methoxy-(100-96-9)
• EPA Substance Registry System: 1,3-Benzenediamine, 5-methoxy-(100-96-9)

Safety Data

• Hazardous Substances Data: 100-96-9(Hazardous Substances Data)

Usage

General Description

1,3-Benzenediamine, 5-methoxy- is a chemical compound that belongs to the family of benzenediamine derivatives. It is an aromatic amine that is commonly used in the production of dyes and pigments. 1,3-Benzenediamine, 5-methoxy- is also used in the synthesis of pharmaceuticals and as an intermediate in organic synthesis. It is characterized by its methoxy group attached to the benzene ring, which gives it unique chemical and biological properties. This chemical compound is considered to be potentially harmful if ingested, inhaled, or comes into contact with the skin, and proper safety precautions should be taken when handling it.

Upstream product

• 33719-74-3 3,5-dichloroanisole 
• 74137-36-3 3,5-dibromoanisole 
• 7647-01-0 hydrogenchloride 
• 861792-66-7 2,4,6-tribromo-3-methoxy-5-nitro-aniline 
• 5327-44-6 3,5-dinitroanisole 

Downstream Products

• 53882-31-8 N-[3-(Ethoxyoxalyl-amino)-5-methoxy-phenyl]-oxalamic acid ethyl ester 

Relevant articles and documents

Assembly of Primary (Hetero)Arylamines via CuI/Oxalic Diamide-Catalyzed Coupling of Aryl Chlorides and Ammonia

A general and practical catalytic system for aryl amination of aryl chlorides with aqueous or gaseous ammonia has been developed, with CuI as the catalyst and bisaryl oxalic diamides as the ligands. The reaction proceeds at 105-120°C to provide a diverse set of primary (hetero)aryl amines in high yields with various functional groups.

Homogenous bimetallic catalysis on amination of ArX and ArX2 in aqueous medium-synergistic effect of dicopper complexes

A dicopper complex [Cu2(bpnp)(OH)(CF3COO) 3] (1) (bpnp = 2,7-bis(pyridin-2-yl)-l,8-naphthyridine) was found to be an excellent catalyst on amination of aryl halides and aryl dihalides with ammonia in aqueous solutions leading to the corresponding anilines and aryldiamines, respectively. Catalytic activity of 1 toward amination appears to be superior to those of other mono nuclear copper complexes. Furthermore, the bimetallic catalyst 1 gave exclusively diamination product in the reaction of ArX2 with ammonia, but other copper complexes showed poor selectivity. Kinetic product distribution study suggests that the dicopper metal ions in this catalysis promote the second amination efficiently.