100008-84-2Relevant articles and documents
Synthesis of dibenzopyranones and pyrazolobenzopyranones through copper(0)/Selectfluor system-catalyzed double C[sbnd]H activation/oxygen insertion of 2-arylbenzaldehydes and 5-arylpyrazole-4-carbaldehydes
Zhang, Jian,Shi, Dongdong,Zhang, Haifeng,Xu, Zheng,Bao, Hanyang,Jin, Hongwei,Liu, Yunkui
, p. 154 - 163 (2016/12/23)
A mild and efficient protocol for the synthesis of dibenzopyranones and pyrazolobenzopyranones was developed involving a copper(0)/Selectfluor system-catalyzed double C[sbnd]H activation/oxygen insertion of 2-arylbenzaldehydes and 5-arylpyrazole-4-carbaldehydes. Preliminary mechanistic studies suggest that both water and dioxygen act as the oxygen source in the formation of pyranone scaffolds.
REGIOCHEMISTRY OF THE CYCLOADDITIONS OF DIPHENYLNITRILIMINE TO COUMARIN, 3-ETHOXYCARBONYL AND 3-ACETYL COUMARINS. A REINVESTIGATION
Fathi, Toufik,Dinh An, Nguyen,Schmitt, Gerard,Cerutti, Ernest,Laude, Bernard
, p. 4527 - 4536 (2007/10/02)
The cycloaddition reactions of diphenylnitrilimine to coumarin, 3-ethoxycarbonyl and 3-acetylcoumarins were studied.The observed regiochemistry of the reaction with the coumarin 4a was the same as the one suggested by other researchers.For the coumarins 4