75640-14-1Relevant articles and documents
PTSA-catalyzed Mannich-type-cyclization-oxidation tandem reactions: One-pot synthesis of 1,3,5-substituted pyrazoles from aldehydes, hydrazines and alkynes
Liu, Pei,Pan, Ying-Ming,Xu, Yan-Li,Wang, Heng-Shan
, p. 4696 - 4698 (2012)
A convenient one-pot Mannich-type-cyclization-oxidation tandem process has been developed for the synthesis of 1,3,5-trisubstituted pyrazoles derivatives from aldehydes, hydrazines and alkynes using p-toluenesulfonic acid monohydrate (PTSA) as a multifunctional catalyst. This method provides a flexible and rapid route to 1,3,5-trisubstituted pyrazoles.
Photooxidation of 3,5-diaryl-1-phenyl-2-pyrazolines: Experimental and computational studies
Soltani, Marzieh,Memarian, Hamid Reza,Sabzyan, Hassan
, (2019/12/23)
Photooxidation of various 2-pyrazolines is studied experimentally and computationally. Experimental results show that the electron-donating/withdrawing substituents increases/decreases the rate of this photoreaction. The proposed light-induced electron-tr
Solvent-free synthesis of 1, 3-diphenyl-5-arylpyrazole derivatives
Li, Ji-Tai,Yin, Ying,Meng, Xian-Tao
experimental part, p. 384 - 386 (2010/04/23)
The synthesis of 1, 3-diphenyl-5-arylpyrazoles via the reactions of 2, 3-epoxy-1-phenyl-3-aryl-1-propanones with phenylhydrazine was carried out in 48-84% yields at 230 °C under solvent-free condition within 1.5 h. This method provides several advantages