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Cas Database

100018-62-0

100018-62-0

Identification

  • Product Name:(1R,2S)-2-Butylamino-1,2-diphenyl-ethanol

  • CAS Number: 100018-62-0

  • EINECS:

  • Molecular Weight:269.387

  • Molecular Formula:C18H23NO

  • HS Code:

  • Mol File:100018-62-0.mol

Synonyms:(1R,2S)-2-Butylamino-1,2-diphenyl-ethanol

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    Relevant articles and documentsAll total 1 Articles be found

    New 1-amino-1,2-diphenylethanols as ligands for the enantioselective addition of alkyllithiums to benzaldehyde

    Schoen, Michael,Naef, Reto

    , p. 169 - 176 (2007/10/03)

    In the presence of equimolar amounts of lithium alkoxides derived from N-substituted 2-amino-1,2-diphenylethanols, alkyllithium reagents add to benzaldehyde to furnish optically active secondary alcohols with enantiomeric excesses of up to 86%. The best results were obtained using the N-isopropyl- N-methyl substituted amino-alcohol.

    Process route upstream and downstream products

    Process route

    erythro-2-butylamino-1,2-diphenylethanol
    58268-10-3,58268-13-6,100018-62-0,100018-63-1,101781-34-4

    erythro-2-butylamino-1,2-diphenylethanol

    Conditions
    ConditionsYield
    With aluminum isopropoxide; isopropyl alcohol;
    1-bromo-butane
    109-65-9

    1-bromo-butane

    (1R,2S)-2-Amino-1,2-diphenylethanol
    23190-16-1

    (1R,2S)-2-Amino-1,2-diphenylethanol

    (1R,2S)-2-Butylamino-1,2-diphenyl-ethanol
    100018-62-0

    (1R,2S)-2-Butylamino-1,2-diphenyl-ethanol

    (1R,2S)-2-Dibutylamino-1,2-diphenyl-ethanol

    (1R,2S)-2-Dibutylamino-1,2-diphenyl-ethanol

    Conditions
    ConditionsYield
    With potassium carbonate;Inethanol;for 24h; Heating;
    59%
    27%
    cis-1,2-diphenyloxirane
    1689-71-0

    cis-1,2-diphenyloxirane

    threo-2-butylamino-1,2-diphenylethanol
    58268-10-3,58268-13-6,100018-62-0,100018-63-1,101781-34-4

    threo-2-butylamino-1,2-diphenylethanol

    Conditions
    ConditionsYield
    trans-Stilbene oxide
    1439-07-2

    trans-Stilbene oxide

    erythro-2-butylamino-1,2-diphenylethanol
    58268-10-3,58268-13-6,100018-62-0,100018-63-1,101781-34-4

    erythro-2-butylamino-1,2-diphenylethanol

    Conditions
    ConditionsYield
    threo-2-butylamino-1,2-diphenylethanol
    58268-10-3,58268-13-6,100018-62-0,100018-63-1,101781-34-4

    threo-2-butylamino-1,2-diphenylethanol

    Conditions
    ConditionsYield
    With water;
    erythro-2-butylamino-1,2-diphenylethanol
    58268-10-3,58268-13-6,100018-62-0,100018-63-1,101781-34-4

    erythro-2-butylamino-1,2-diphenylethanol

    Conditions
    ConditionsYield
    With aluminum isopropoxide; isopropyl alcohol;
    1-bromo-butane
    109-65-9

    1-bromo-butane

    (1R,2S)-2-Amino-1,2-diphenylethanol
    23190-16-1

    (1R,2S)-2-Amino-1,2-diphenylethanol

    (1R,2S)-2-Butylamino-1,2-diphenyl-ethanol
    100018-62-0

    (1R,2S)-2-Butylamino-1,2-diphenyl-ethanol

    (1R,2S)-2-Dibutylamino-1,2-diphenyl-ethanol

    (1R,2S)-2-Dibutylamino-1,2-diphenyl-ethanol

    Conditions
    ConditionsYield
    With potassium carbonate;Inethanol;for 24h; Heating;
    59%
    27%
    cis-1,2-diphenyloxirane
    1689-71-0

    cis-1,2-diphenyloxirane

    threo-2-butylamino-1,2-diphenylethanol
    58268-10-3,58268-13-6,100018-62-0,100018-63-1,101781-34-4

    threo-2-butylamino-1,2-diphenylethanol

    Conditions
    ConditionsYield
    trans-Stilbene oxide
    1439-07-2

    trans-Stilbene oxide

    erythro-2-butylamino-1,2-diphenylethanol
    58268-10-3,58268-13-6,100018-62-0,100018-63-1,101781-34-4

    erythro-2-butylamino-1,2-diphenylethanol

    Conditions
    ConditionsYield
    threo-2-butylamino-1,2-diphenylethanol
    58268-10-3,58268-13-6,100018-62-0,100018-63-1,101781-34-4

    threo-2-butylamino-1,2-diphenylethanol

    Conditions
    ConditionsYield
    With water;

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