1003-13-0Relevant articles and documents
Palladium(II)-Catalyzed Cyclopropanation of Simple Allyloxy and Allylamino Compounds and of 1-Oxy-1,3-butadienes with Diazomethane
Tomilov, Yu. V.,Kostitsyn, A. B.,Shulishov, E. V.,Nefedov, O. M.
, p. 246 - 248 (1990)
(Alkyloxymethyl)-, (aminomethyl)-, (2-alkoxyethenyl)-, (2-acetoxyethenyl)-, and (2-siloxyethenyl)cyclopropanes are obtained in high yields by reaction of allyl alcohol or derivatives, allylamines, 1-alkoxy-, 1-acetoxy-, and 1-trimethylsiloxy-1,3-butadienes with diazomethane in dichloromethane/diethylether in the presence of bis(benzonitrile)palladium dichloride.
Dynamic behaviour of carbocations on zeolites: Mobility and rearrangement of the C4H7+ system
Kling, Diego P.,Machado, Erick S.A.,Chagas, Henrique C.,Dos Santos, Alex P.A.,Rosenbach, Nilton,Walkimar Carneiro, Jose,Mota, Claudio J.A.
, p. 4480 - 4482 (2013)
The mobility and rearrangement of the C4H7 + system over Chabazite were studied using ab initio molecular dynamics. The results indicated the high mobility of the cations, which can rearrange within picosecond time interva
REACTIONS OF DIAZOALKANES WITH UNSATURATED COMPOUNDS. 8. CATALYTIC CYCLOPROPANATION OF ALLYL ALCOHOLS AND ALLYLAMINES WITH DIAZOMETHANE
Tomilov, Yu. V.,Kostitsyn, A. B.,Dokichev, V. A.,Dzhemilev, U. M.,Nefedov, O. M.
, p. 2518 - 2521 (2007/10/02)
Allyl alcohols and allylamines have been cyclopropanated directly with diazomethane in the presence of palladium compounds to give 60-88percent of cyclopropylmethanols and cyclopropylmethylamines, respectively, almost free from the products of formal insertion of methylene into the heteroatom-hydrogen bond.
