100340-47-4

Basic information

• Product Name: methyl (E)-2-phenyl-2-octenoate
• Synonyms: methyl (E)-2-phenyl-2-octenoate
• CAS NO: 100340-47-4
• Molecular Weight: 232.323
• Mol File: 100340-47-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: methyl (E)-2-phenyl-2-octenoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (E)-2-phenyl-2-octenoate(100340-47-4)
• EPA Substance Registry System: methyl (E)-2-phenyl-2-octenoate(100340-47-4)

Safety Data

• Hazardous Substances Data: 100340-47-4(Hazardous Substances Data)

Upstream product

• 93-89-0 benzoic acid ethyl ester 
• 100340-43-0 tert-Butyl-((E)-1-methoxy-hept-1-enyloxy)-dimethyl-silane 
• 78935-63-4 Z-methoxy-1 trimethylsiloxy-1 heptene-1 
• 86593-94-4 (E/Z)-1-methoxy-1-trimethylsilyloxy-1-heptene 
• 106-73-0 methyl heptanoate 
• 98-87-3 benzylidene dichloride 
• 144079-75-4 methyl (E)-2-tributylstannyl-2-octenoate 
• 67-56-1 methanol 
• 96845-72-6 triisopropyl((phenylethynyl)oxy)silane 
• 66-25-1 hexanal 
• 28557-00-8 phenylzinc chloride 
• 144079-78-7 methyl (E)-2-iodo-2-octenoate 
• 591-50-4 iodobenzene 

Relevant articles and documents

New and efficient procedures for the synthesis of stereodefined 2-(hetero) aryl and 2-methyl substituted alkyl 2-alkenoates having very high stereoisomeric purity

Stereodefined 2-(hetero)aryl and 2-methyl substituted alkyl 2-alkenoates of general formulai and2 have been synthesized with a high degree of stereoselectivity as well as in good overall yields starting from alkyl 2-alkynoates,4.

Trisubstituted Olefins via Ester-Derived (Silyloxy)acetylenes: A Highly Stereoselective Alternative to the Horner-Wadsworth-Emmons Reaction

Crude ((triisopropylsilyl)oxy)acetylenes 2, prepared in one step from common esters 1, react with aldehydes in 60-65 percent overall yield after methanol quench to afford α,β-unsaturated esters 3 with very high E/Z stereoselectivity.