100847-87-8

Basic information

• Product Name: ETHYL 6-(4-METHYLPHENYL)-6-OXOHEXANOATE
• Synonyms: ETHYL 6-(4-METHYLPHENYL)-6-OXOHEXANOATE
• CAS NO: 100847-87-8
• Molecular Formula: C₁₅H₂₀O₃
• Molecular Weight: 248.32
• Mol File: 100847-87-8.mol

Chemical Properties

• Boiling Point: 360.4°C at 760 mmHg
• Flash Point: 156.8°C
• Appearance: /
• Density: 1.035g/cm³
• Vapor Pressure: 2.22E-05mmHg at 25°C
• Refractive Index: 1.501
• CAS DataBase Reference: ETHYL 6-(4-METHYLPHENYL)-6-OXOHEXANOATE(CAS DataBase Reference)
• NIST Chemistry Reference: ETHYL 6-(4-METHYLPHENYL)-6-OXOHEXANOATE(100847-87-8)
• EPA Substance Registry System: ETHYL 6-(4-METHYLPHENYL)-6-OXOHEXANOATE(100847-87-8)

Safety Data

• Hazardous Substances Data: 100847-87-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C15H20O3/c1-3-18-15(17)7-5-4-6-14(16)13-10-8-12(2)9-11-13/h8-11H,3-7H2,1-2H3

Upstream product

• 64-17-5 ethanol 
• 100847-96-9 5-(p-toluoyl)valeric acid 
• 1821-23-4 1-cyclohex-1-enyl-4-methylbenzene 
• 1821-24-5 1-(p-methylphenyl)cyclohexanol 
• 106-38-7 para-bromotoluene 
• 117421-36-0 6-oxo-6-(p-tolyl)hexanal 

Downstream Products

• 100847-88-9 ethyl 6-hydroxy-6-p-tolylheptanoate 
• 16982-00-6 1-(1,2,2-trimethylcyclopentyl)-4-methylbenzene 
• 51941-57-2 (1R^*,2S^*)-1,2-Dimethyl-2-(4-methylphenyl)cyclopentanemethanol 
• 51941-58-3 1,2-dimethyl-2-p-tolylcyclopentane-1-carbaldehyde 
• 100847-92-5 ethyl 5-methyl-p-tolylcyclopent-1-ene-1-carboxylate 
• 51941-56-1 ethyl cis-1,2-dimethyl-2-(4-methylphenyl)cyclopentanecarboxylate 
• 100847-89-0 ethyl 6-phenylthio-6-p-tolylheptanoate 
• 100847-91-4 2-Methyl-1-phenylsulfanyl-2-p-tolyl-cyclopentanecarboxylic acid ethyl ester 
• 100847-90-3 ethyl 2-diazo-6-phenylthio-6-p-tolylheptanoate 
• 211811-46-0 2-Methyl-2-p-tolyl-cyclopentanecarboxylic acid ethyl ester 
• 54750-40-2 1-(1,2-dimethylcyclopent-2-en-1-yl)-4-methylbenzene 
• 117421-41-7 1-hydroxymethyl-5-methyl-5-p-tolylcyclopent-1-ene 
• 117421-42-8 2-(4-methylcyclohexyl)cyclopentane-1-carboxylate 
• 117421-47-3 ethyl 6-p-tolyl-2,6-heptadienoate 

Relevant articles and documents

SYNTHESIS OF AROMATIC SESQUITERPENES, (+/-)-CUPARENE AND (+/-)-LAURENE BY MEANS OF AN INTRAMOLECULAR CARBENOID DISPLACEMENT (ICD) REACTION

The synthesis of (+/-)-cuparene and (+/-)-laurene was accomplished by means of an intramolecular carbenoid displacement (ICD) reaction of the benzyl sulphide (12) as a key reaction.

Synthesis of an Aromatic Sesquiterpene, (+/-)-Cuparene, via Construction of a Quaternary Carbon Centre by an Intramolecular Carbenoid Displacement Reaction

The synthesis of (+/-)-cuparene (11), which includes as the key step an intramolecular carbenoid displacement reaction at the benzylic position of a benzyl sulphide derivative, is described.