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Cas Database

101-05-3

101-05-3

Identification

  • Product Name:ANILAZINE

  • CAS Number: 101-05-3

  • EINECS:202-910-5

  • Molecular Weight:275.524

  • Molecular Formula: C9H5 Cl3 N4

  • HS Code:2933699015

  • Mol File:101-05-3.mol

Synonyms:s-Triazine,2,4-dichloro-6-(o-chloroanilino)- (8CI);2,4-Dichloro-6-(2-chloranilino)-s-triazine; 2,4-Dichloro-6-(2-chloroanilino)-1,3,5-triazine;2,4-Dichloro-6-(o-chloroanilino)-1,3,5-triazine;2,4-Dichloro-6-(o-chloroanilino)-s-triazine;2,4-Dichloro-6-(o-chlorophenyl)amino-s-triazine;2,4-Dichloro-6-o-chloranilino-s-triazine; 2-(2-Chloroanilino)-4,6-dichloro-s-triazine;2-(2'-Chloroanilino)-4,6-dichloro-s-triazine;2-(o-Chloroanilino)-4,6-dichloro-1,3,5-triazine; Anilazin; Anilazine;Aniyaline; B 622; Bortrysan; Dyrene; Dyrene 50W; Dyrene Flussig; Kemate; NSC3851; Triazin; Triazine; Triazine (pesticide); Zinochlor

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Safety information and MSDS view more

  • Pictogram(s):IrritantXiDangerousN

  • Hazard Codes:Xi,N

  • Signal Word:Warning

  • Hazard Statement:H315 Causes skin irritationH319 Causes serious eye irritation H410 Very toxic to aquatic life with long lasting effects

  • First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. SYMPTOMS: Symptoms of exposure to this compound may include irritation of the gastrointestinal tract and the respiratory tract. Severe eye irritation may occur. Prolonged skin contact may cause irritation. ACUTE/CHRONIC HAZARDS: This compound is a severe eye irritant. Prolonged skin contact may cause irritation. When heated to decomposition it emits toxic fumes of chlorine and nitrogen oxides. Absorption, Distribution and ExcretionElimination is quick; almost 98% is excreted within 72 hr in the urine & feces.

  • Fire-fighting measures: Suitable extinguishing media If material on fire or involved in fire: Extinguish fire using agent suitable for type of surrounding fire. (Material itself does not burn or burns with difficulty.) Use water in flooding quantities as fog. Use "alcohol" foam, dry chemical or carbon dioxide. /Triazine pesticide, solid, NOS/ Flash point data for this chemical are not available; however, it is probably combustible. Wear self-contained breathing apparatus for firefighting if necessary.

  • Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  • Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

  • Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

Supplier and reference price view more

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  • Manufacture/Brand:TRC
  • Product Description:Anilazine
  • Packaging:1g
  • Price:$ 1230
  • Delivery:In stock
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  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Anilazine PESTANAL?, analytical standard
  • Packaging:50mg
  • Price:$ 87.1
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  • Manufacture/Brand:Biosynth Carbosynth
  • Product Description:Anilazine
  • Packaging:25 mg
  • Price:$ 550
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  • Product Description:Anilazine
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  • Price:$ 425
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  • Manufacture/Brand:Biosynth Carbosynth
  • Product Description:Anilazine
  • Packaging:5 mg
  • Price:$ 275
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  • Manufacture/Brand:Biosynth Carbosynth
  • Product Description:Anilazine
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  • Product Description:Anilazine
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  • Manufacture/Brand:American Custom Chemicals Corporation
  • Product Description:ANILAZINE 95.00%
  • Packaging:1G
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  • Manufacture/Brand:American Custom Chemicals Corporation
  • Product Description:ANILAZINE 95.00%
  • Packaging:100MG
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  • Manufacture/Brand:AHH
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Relevant articles and documentsAll total 38 Articles be found

Design, synthesis, and cytotoxicity of novel 2,4,6-trisubstituted 1,3,5-triazines bearing aryl hydrazone moiety as potent antitumor agent

Wang, Limei,Zhao, Sijia,Bao, Guanglong,Zhang, Yu,Xi, Shuancheng,Zhou, Guolin,Zhai, Xin,Gong, Ping

, p. 621 - 630 (2016/10/18)

A novel series of 2,4,6-trisubstituted 1,3,5-triazine derivatives bearing aryl hydrazone moiety were designed and synthesized under the guidance of scaffold hopping and bioisosterism from the autophagy inhibitor VLX600. The target compounds were evaluated for cytotoxicity against HT-29 by MTT assay with VLX600 as positive control. Then, ten potent target compounds (5c-5f, 5i-5r, 5s, 5t) were further evaluated against two cancer cell lines H460 and A549 and one normal cell line WI-38. Most of them exhibited significant cytotoxicity against one or more cell lines. Particularly, a promising compound 5f was identified, which exhibited the most potent cytotoxicity against HT-29, H460 and A549 cancer cell lines with IC50 values of 0.047 μM, 0.071 μM and 0.071 μM, respectively, which was 10-to 62-folds more potent than VLX600 (IC50 = 0.47 μM, 4.1 μM, 4.4 μM). The preliminary structure-activity relationships (SARs) of the compounds were also discussed.

Targeting the hydrophobic region of Hsp90's ATP binding pocket with novel 1,3,5-triazines

Lee, Taeho,Seo, Young Ho

supporting information, p. 6427 - 6431 (2013/11/19)

Heat shock protein 90 (Hsp90) is a molecular chaperone that plays an important role in regulating the maturation and stabilization of many oncogenic proteins. In an attempt to discover a new class of Hsp90 inhibitors, a series of 1,3,5-triazine compounds were rationally designed, synthesized, and their biological activities were evaluated. Compound 3b was found to degrade Hsp90's client proteins of Her2, Met and Akt and to induce the expression level of Hsp70. The binding mode of 3b in the ATP-binding site of Hsp90 was predicted by the molecular docking.

Photochemical Crosslinkers for Polymer Coatings and Substrate Tie-Layer

-

, (2008/06/13)

The invention describes novel crosslinking compounds that include photoactivatable moieties. Several families of compounds are disclosed that can include one or more hydrophilic moieties that help to solubilize the compounds in aqueous environments.

Process route upstream and downstream products

Process route

1,3,5-trichloro-2,4,6-triazine
108-77-0

1,3,5-trichloro-2,4,6-triazine

o-chloroaniline
95-51-2

o-chloroaniline

anilazine
101-05-3

anilazine

Conditions
Conditions Yield
With sodium hydroxide; In acetone; at 0 - 5 ℃; for 3h;
75%
In acetonitrile; at 20 ℃; for 4h;
In sodium hydroxide; water; toluene;
With 2,6-dimethylpyridine; In acetone; at 20 ℃; for 12h; Inert atmosphere;
1,3,5-trichloro-2,4,6-triazine; With sodium carbonate; In acetone; at 10 ℃; for 0.5h;
o-chloroaniline; In acetone; for 0.5h;
4-Hydroxybenzophenone
1137-42-4

4-Hydroxybenzophenone

anilazine
101-05-3

anilazine

Conditions
Conditions Yield
With triphenylphosphine; In chloroform;
70%
1,3,5-trichloro-2,4,6-triazine
108-77-0

1,3,5-trichloro-2,4,6-triazine

ethanolamine
141-43-5

ethanolamine

anilazine
101-05-3

anilazine

Conditions
Conditions Yield
In acetone;
64%
6-chloro-1-hexanol
2009-83-8

6-chloro-1-hexanol

PEG 400

PEG 400

2-(2,4-dihydroxyphenyl)-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine
1668-53-7

2-(2,4-dihydroxyphenyl)-4,6-bis(2,4-dimethylphenyl)-1,3,5-triazine

2,4-di-(2,4-dimethylphenyl)-6-[2-hydroxy-4-(6-hydroxy-1-hexyloxy)phenyl]-1,3,5-triazine

2,4-di-(2,4-dimethylphenyl)-6-[2-hydroxy-4-(6-hydroxy-1-hexyloxy)phenyl]-1,3,5-triazine

anilazine
101-05-3

anilazine

Conditions
Conditions Yield
With sodium hydroxide; potassium iodide; In water; 4-methyl-2-pentanone; acetone;
trichloroacetonitrile
545-06-2

trichloroacetonitrile

cyclopropropanecarbonitrile
5500-21-0

cyclopropropanecarbonitrile

4-cyclopropyl-2,6-bis(trichloromethyl)-1,3,5-triazine

4-cyclopropyl-2,6-bis(trichloromethyl)-1,3,5-triazine

anilazine
101-05-3

anilazine

Conditions
Conditions Yield
With hydrogenchloride; In hexane;
1-[2-(2-chloroethoxy)ethoxy]hexane
72510-64-6

1-[2-(2-chloroethoxy)ethoxy]hexane

anilazine
101-05-3

anilazine

Conditions
Conditions Yield
In 6-chloro-1-hexanol; n-heptane;
2,6-Dichloro-4-piperidine-1,3,5-triazine

2,6-Dichloro-4-piperidine-1,3,5-triazine

bis(3-aminophenyl)(methyl)phosphine oxide
783-81-3

bis(3-aminophenyl)(methyl)phosphine oxide

anilazine
101-05-3

anilazine

Conditions
Conditions Yield
In N,N-dimethyl-formamide;
2,6-Dichloro-4-pyrrolidine-1,3,5-triazine

2,6-Dichloro-4-pyrrolidine-1,3,5-triazine

bis(3-aminophenyl)(methyl)phosphine oxide
783-81-3

bis(3-aminophenyl)(methyl)phosphine oxide

anilazine
101-05-3

anilazine

Conditions
Conditions Yield
In N,N-dimethyl-formamide;
3-Amino-1,2-propanediol
616-30-8,13552-31-3,98923-21-8

3-Amino-1,2-propanediol

benzenediazonium hexafluorophosphate
369-58-4

benzenediazonium hexafluorophosphate

anilazine
101-05-3

anilazine

Conditions
Conditions Yield
In hexane; N,N-dimethyl-formamide;
tetrakis(triphenylphosphine) palladium<sup>(0)</sup>
14221-01-3

tetrakis(triphenylphosphine) palladium(0)

bromobenzene
108-86-1,52753-63-6

bromobenzene

9,9-di-n-octyl-2,7-bis(4,4,5,5-tetramethyl-1,2,3-dioxaborolan-2-yl)fluorene

9,9-di-n-octyl-2,7-bis(4,4,5,5-tetramethyl-1,2,3-dioxaborolan-2-yl)fluorene

sodium carbonate
497-19-8

sodium carbonate

2,7-dibromo-9-octyl-9H-fluorene
496879-77-7

2,7-dibromo-9-octyl-9H-fluorene

anilazine
101-05-3

anilazine

Conditions
Conditions Yield
In methanol; 2,4-bis(4-bromophenyl)-6-phenyl-1,3,5-triazine; toluene;

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