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ANILAZINE, also known as dichlorotriazene with an o-chloroanilino group, is a member of the triazene class. It is characterized by its white to tan crystalline or powder form and has a melting point of 159°C. ANILAZINE is moderately soluble in organic solvents but is insoluble in water. It was formerly used as a fungicide to control leaf spots and downy mildew.

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  • 101-05-3 Structure
  • Basic information

    1. Product Name: ANILAZINE
    2. Synonyms: 4,6-dichloro-n-(2-chlorophenyl)-1,3,5-triazin-2-amine;5-triazin-2-amine,4,6-dichloro-n-(2-chlorophenyl)-3;Anilazin;Aniyaline;Bortrysan;Dairene;Dairin;Direz
    3. CAS NO:101-05-3
    4. Molecular Formula: C9H5Cl3N4
    5. Molecular Weight: 275.52
    6. EINECS: 202-910-5
    7. Product Categories: Agro-Products;Aromatics;FUNGICIDE
    8. Mol File: 101-05-3.mol
  • Chemical Properties

    1. Melting Point: 159-160℃
    2. Boiling Point: 425.99°C (rough estimate)
    3. Flash Point: 232.2 °C
    4. Appearance: white to light brown crystals or powder
    5. Density: 1.611
    6. Vapor Pressure: 1.17E-08mmHg at 25°C
    7. Refractive Index: 1.6000 (estimate)
    8. Storage Temp.: 0-6°C
    9. Solubility: N/A
    10. PKA: 0.43±0.10(Predicted)
    11. Water Solubility: 10mg/L(temperature not stated)
    12. Stability: Stable. Incompatible with oils and alkalies. May corrode some types of metal and alloy.
    13. Merck: 13,659
    14. BRN: 223133
    15. CAS DataBase Reference: ANILAZINE(CAS DataBase Reference)
    16. NIST Chemistry Reference: ANILAZINE(101-05-3)
    17. EPA Substance Registry System: ANILAZINE(101-05-3)
  • Safety Data

    1. Hazard Codes: Xi,N
    2. Statements: 36/38-50/53
    3. Safety Statements: 22-60-61
    4. RIDADR: UN3077 9/PG 3
    5. WGK Germany: 3
    6. RTECS: XY7175000
    7. HazardClass: N/A
    8. PackingGroup: N/A
    9. Hazardous Substances Data: 101-05-3(Hazardous Substances Data)

101-05-3 Usage

Uses

Used in Agricultural Industry:
ANILAZINE is used as a pesticide for controlling fungus diseases in lawns and turf.
Used in Fungicide Applications:
ANILAZINE is used as a fungicide to protect plants from fungal infections.
Used in Crop Protection:
ANILAZINE is used as a nonsystemic, foliar fungicide in potatoes, tomatoes, wheat, barley, and ornamentals to prevent and treat fungal diseases.
Note: ANILAZINE is no longer approved for use within the European Union due to safety concerns.

Air & Water Reactions

Insoluble in water. Stable in neutral and slightly acidic aqueous media but hydrolyzes on heating with alkali.

Reactivity Profile

ANILAZINE is incompatible with oils and alkalis. ANILAZINE is slightly corrosive to metals.

Fire Hazard

Flash point data for ANILAZINE are not available; however, ANILAZINE is probably combustible.

Environmental Fate

Soil. Anilazine is readily degraded by soil bacteria (Harris et al., 1968). The reported half-life of anilazine in soil is approximately 12 hours (Hartley and Kidd, 1987)Plant. In plants, one or both of the chlorine atoms on the triazine ring may be replaced by thio or amino groups (Hartley and Kidd, 1987)Chemical/Physical. Anilazine is subject to hydrolysis (Windholz et al., 1983) releasing chlorine gas (Hartley and Kidd, 1987)

Check Digit Verification of cas no

The CAS Registry Mumber 101-05-3 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,0 and 1 respectively; the second part has 2 digits, 0 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 101-05:
(5*1)+(4*0)+(3*1)+(2*0)+(1*5)=13
13 % 10 = 3
So 101-05-3 is a valid CAS Registry Number.
InChI:InChI=1/C9H5Cl3N4/c10-5-3-1-2-4-6(5)13-9-15-7(11)14-8(12)16-9/h1-4H,(H,13,14,15,16)

101-05-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name anilazine

1.2 Other means of identification

Product number -
Other names 2,4-dichloro-6-(o-chloro-anilino)-s-triazine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Fungicide
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:101-05-3 SDS

101-05-3Downstream Products

101-05-3Related news

Normal coordinate analysis and fungicidal activity study on ANILAZINE (cas 101-05-3) and its related compound using spectroscopic techniques07/19/2019

The FTIR and FT-Raman spectra of anilazine have been recorded in the range 400–4000 cm−1 and 50–3500 cm−1 respectively. The optimized geometrical parameters of the compound were calculated using B3LYP method with 6-311G(d,p) basis set. The distribution of the vibrational bands were carried out...detailed

101-05-3Relevant articles and documents

Design, synthesis, and cytotoxicity of novel 2,4,6-trisubstituted 1,3,5-triazines bearing aryl hydrazone moiety as potent antitumor agent

Wang, Limei,Zhao, Sijia,Bao, Guanglong,Zhang, Yu,Xi, Shuancheng,Zhou, Guolin,Zhai, Xin,Gong, Ping

, p. 621 - 630 (2016/10/18)

A novel series of 2,4,6-trisubstituted 1,3,5-triazine derivatives bearing aryl hydrazone moiety were designed and synthesized under the guidance of scaffold hopping and bioisosterism from the autophagy inhibitor VLX600. The target compounds were evaluated for cytotoxicity against HT-29 by MTT assay with VLX600 as positive control. Then, ten potent target compounds (5c-5f, 5i-5r, 5s, 5t) were further evaluated against two cancer cell lines H460 and A549 and one normal cell line WI-38. Most of them exhibited significant cytotoxicity against one or more cell lines. Particularly, a promising compound 5f was identified, which exhibited the most potent cytotoxicity against HT-29, H460 and A549 cancer cell lines with IC50 values of 0.047 μM, 0.071 μM and 0.071 μM, respectively, which was 10-to 62-folds more potent than VLX600 (IC50 = 0.47 μM, 4.1 μM, 4.4 μM). The preliminary structure-activity relationships (SARs) of the compounds were also discussed.

HEXAHYDROTRIAZINES, SYNTHESIS AND USE

-

Page/Page column, (2013/05/22)

Methods for making asymmetrical triazines are provided. The methods comprise first forming a mixture of at least two primary amines then reacting the mixture with an aldehyde. Methods for removing sulfides from hydrocarbon streams are also provided. The triazines may be added to the hydrocarbon stream in a molar ratio of triazine:H2S of about 10:1 to about 1:2.

Targeting the hydrophobic region of Hsp90's ATP binding pocket with novel 1,3,5-triazines

Lee, Taeho,Seo, Young Ho

supporting information, p. 6427 - 6431 (2013/11/19)

Heat shock protein 90 (Hsp90) is a molecular chaperone that plays an important role in regulating the maturation and stabilization of many oncogenic proteins. In an attempt to discover a new class of Hsp90 inhibitors, a series of 1,3,5-triazine compounds were rationally designed, synthesized, and their biological activities were evaluated. Compound 3b was found to degrade Hsp90's client proteins of Her2, Met and Akt and to induce the expression level of Hsp70. The binding mode of 3b in the ATP-binding site of Hsp90 was predicted by the molecular docking.

Dyes and their use in ink-jet printing

-

, (2008/12/07)

A compound of Formula (1) or a salt thereof: wherein: A is optionally substituted aryl or optionally substituted heterocyclyl; and R1 and R2 are independently H or a substituent. Also metal chelates, compositions, inks, printing processes, printed material and ink-jet cartridges.

N4-Phenyl modifications of N2-(2-hydroxyl)ethyl-6-(pyrrolidin-1-yl)-1,3,5-triazine-2,4-d iamines enhance glucocerebrosidase inhibition by small molecules with potential as chemical chaperones for Gaucher disease

Huang, Wenwei,Zheng, Wei,Urban, Daniel J.,Inglese, James,Sidransky, Ellen,Austin, Christopher P.,Thomas, Craig J.

, p. 5783 - 5789 (2008/02/13)

A series of 1,3,5-triazine-2,4,6-triamines were prepared and analyzed as inhibitors of glucocerebrosidase. Synthesis, structure activity relationships and the selectivity of chosen analogues against related sugar hydrolases enzymes are described.

Photochemical Crosslinkers for Polymer Coatings and Substrate Tie-Layer

-

, (2008/06/13)

The invention describes novel crosslinking compounds that include photoactivatable moieties. Several families of compounds are disclosed that can include one or more hydrophilic moieties that help to solubilize the compounds in aqueous environments.

Triazine library with linkers

-

, (2008/06/13)

Triazine linkers can be used as universal small molecule chips for functional proteomics and sensors. These compounds are prepared by making a first building block by adding a first amine by reductive amination of triazine, making a second building block by adding a second amine to cyanuric chloride, and combining the first and second building blocks by aminating the first building block onto one of the chloride positions of the second building block.

Inhibitors of protein kinase for the treatment of disease

-

, (2008/06/13)

The present invention is directed in part towards methods of modulating the function of protein kinases with phenol- and hydroxynaphthalene-based compounds. The methods incorporate cells that express a protein kinase. In addition, the invention describes methods of preventing and treating protein kinase-related abnormal conditions in organisms with a compound identified by the invention. Furthermore, the invention pertains to phenol- and hydroxynaphthalene-based compounds and pharmaceutical compositions comprising these compounds.

Organic electroluminescent (EL) devices

-

, (2008/06/13)

A new class of conjugated organic polymers or copolymers comprising a triazine group. This class of polymers or copolymers may be used in organic electroluminescent (EL) devices.

Sodium channel drugs and uses

-

, (2008/06/13)

The compounds of this invention comprise 2-10 ligands covalently connected, each of the ligands being capable of binding to a ligand binding site in a Na+channel, thereby modulating the biological activities thereof.

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