10137-69-6 Usage
Uses
Used in Chemical Industry:
3-CYCLOHEXENYLTRICHLOROSILANE is used as a key intermediate for the synthesis of silicon-containing compounds, which find applications in various industries such as electronics, pharmaceuticals, and materials science. Its ability to form stable bonds with silicon makes it a valuable component in the development of new materials and products.
Used in Electronics Industry:
In the electronics industry, 3-CYCLOHEXENYLTRICHLOROSILANE is used as a precursor for the production of silicon-based materials, which are essential in the manufacturing of semiconductors, solar cells, and other electronic components. Its role in creating these materials contributes to the advancement of technology and the development of more efficient electronic devices.
Used in Pharmaceutical Industry:
3-CYCLOHEXENYLTRICHLOROSILANE is used as a building block for the synthesis of silicon-containing drugs and drug delivery systems. Its unique properties allow for the development of novel therapeutic agents and targeted drug delivery systems, which can improve the efficacy and safety of various pharmaceutical treatments.
Used in Materials Science:
In the field of materials science, 3-CYCLOHEXENYLTRICHLOROSILANE is used as a component in the development of advanced materials with specific properties, such as high temperature resistance, chemical stability, and enhanced mechanical strength. These materials can be utilized in various applications, including aerospace, automotive, and construction industries.
Air & Water Reactions
Reacts violently with water, steam, moist air, alcohols, acetone, light metals with generation of heat and combustible (H2) and corrosive (HCl) gases. on contact with air 3-CYCLOHEXENYLTRICHLOROSILANE gives off HCl gas. REF [Handling Chemicals Safely, 1980 p. 924].
Reactivity Profile
Chlorosilanes, such as 3-CYCLOHEXENYLTRICHLOROSILANE, are compounds in which silicon is bonded to from one to four chlorine atoms with other bonds to hydrogen and/or alkyl groups. Chlorosilanes react with water, moist air, or steam to produce heat and toxic, corrosive fumes of hydrogen chloride. They may also produce flammable gaseous H2. They can serve as chlorination agents. Chlorosilanes react vigorously with both organic and inorganic acids and with bases to generate toxic or flammable gases. Special Hazards of Combustion Products: Irritating, toxic hydrogen chloride and phosgene may be generated in a fire.
Health Hazard
Inhalation causes irritation of mucous membrane. Contact with eyes or skin causes severe burns. Ingestion causes severe burns of mouth and stomach.
Safety Profile
Moderately toxic by
ingestion and skin contact. An eye and
severe skin irritant. A corrosive material. It
fumes in moist air, releasing HCl.
Combustible when exposed to heat or
flame. When heated to decomposition itemits toxic fumes of Cl-. See also
CHLOROSILANES.
Potential Exposure
This material is used to make silicone
polymers.
Shipping
UN1762 Cyclohexenyl trichlorosilane, Hazard
class: 8; Labels: 8-Corrosive material.
Incompatibilities
Incompatible with oxidizers (chlorates,
nitrates, peroxides, permanganates, perchlorates, chlorine,
bromine, fluorine, etc.); contact may cause fires or explo-
sions. Keep away from alkaline materials, strong bases,
strong acids, oxoacids, epoxides. Chlorosilanes react vigor-
ously with bases and both organic and inorganic acids gen-
erating toxic and/or flammable gases. Chlorosilanes react
with water, moist air, or steam releasing heat and toxic,
corrosive fumes of hydrogen chloride. The reaction may
also release flammable hydrogen fumes. Attacks metals in
the presence of moisture. Some chlorosilanes are pyro-
phoric; self-ignite in air. Contact with ammonia can cause
a self-igniting compound.
Check Digit Verification of cas no
The CAS Registry Mumber 10137-69-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,1,3 and 7 respectively; the second part has 2 digits, 6 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 10137-69:
(7*1)+(6*0)+(5*1)+(4*3)+(3*7)+(2*6)+(1*9)=66
66 % 10 = 6
So 10137-69-6 is a valid CAS Registry Number.
InChI:InChI=1/C6H9Cl3Si/c7-10(8,9)6-4-2-1-3-5-6/h1-2,6H,3-5H2
10137-69-6Relevant articles and documents
Thermal reaction of cyclic alkadiene with trichlorosilane. Preparative and mechanistic aspects
Jung, Dong Eui,Han, Joon Soo,Yoo, Bok Ryul
, p. 40 - 44 (2013/03/13)
The thermal reactions of trichlorosilane (1a) with cyclic alkadienes such as cyclopentadiene (2a), 1,3-cyclohexadiene (2b), and 1,4-cyclohexadiene (2c) were studied at temperatures ranging from 170 °C to 250 °C. In this reaction, the hydrosilylation rate increased as the reaction temperature was raised using an equimolar ratio of 1a to 2a. The reaction of 2a with 1a at 250 °C afforded 2-cyclopentenyltrichlorosilane (3a) as the major hydrosilylation product within 1 h in good yield (82%). This reaction also works when dicyclopentadiene (2a′) was used as a reactant instead of 2a. In a large scale preparation under the same conditions, 3a was obtained in 82% isolated yield. It is significant to note that 2a′ can be used for the hydrosilylation, with no requirement of a cracking step under our thermal conditions. While the reaction of cyclohexadienes with 1a under the same conditions gave a mixture of three hydrosilylation products such as 2-cyclohexenyltrichlorosilane (3b), 3-cyclohexenyltrichlorosilane (3c) and cyclohexyltrichlorosilane (5) in moderate yields, along with other unsaturated C6 components, such as benzene and cyclohexene. In the thermal reaction of cycloalkadienes with 1a, the five-membered-ring diene 2a undergoes both a hydrosilylation reaction with 1a as well as a [4 + 2] cycloaddition reaction, leading to the hydrosilylation product 3a in good yield. While the six-membered ring dienes, 2b and 2c, undergo four different types of reactions, including hydrosilylation, [4 + 2] cycloaddition, dehydrogenation, and hydrogenation in competition to give the hydrosilylation products, hexane, and benzene, respectively. The reaction rates of cyclic alkadienes under our thermal conditions increase in the following order: 2c 2b 2a.
Cyclohexadien-2,4-ylsilane and its derivatives, synthesis of the same, and the pyrolysis of the same to silane
-
Page/Page column 5, (2008/06/13)
Silane gas precursor compounds having the formula (I): wherein R1, R2, and R3 each can independently be hydrogen or halogen and wherein the cyclohexadiene ring can have one or more substituents selected from the group consisting of a saturated or unsaturated, straight chain or branched alkyl group, a halogen, NO2, and C≡N are disclosed. In one form, the silane gas precursor compound is cyclohexadien-2,4-ylsilane, an air-stable liquid, that can be thermolyzed in a pyrolysis process to efficiently generate high purity silane gas. The compounds of the present invention can thus serve as a “point-of-use” precursor for silane gas.
Trichlorosilyl groups containing organochlorosilanes and their preparation methods by the double-silylation of olefins with trichlorosilane
-
Page 5, (2008/06/13)
The present invention provides organosilicon compounds containing two trichlorosilyl groups and their preparation methods. Organosilicon compounds of formula II are prepared by reacting linear chain or cyclic olefins of formula I with trichlorosilane in the presence of quaternary organophosphonium salt as a catalyst.R1—HC=CH—R2??(I) 1In formulas I and II, R1 and R2 may be identical or different and represent a hydrogen atom, a linear or a cyclic C1-C8 alkyl, a linear or a cyclic C1-C8 alkenyl, benzyl, phenyl, a C1-C8 alkyl substituted phenyl group, two functional groups between R1 and R2 may be covalently bonded to form a C4-C8 ring with or without a carbon-carbon double bond.
