3-Cyclohexenyltrichlorosilane

Base Information

• Chemical Name: 3-Cyclohexenyltrichlorosilane
• CAS No.: 10137-69-6
• Molecular Formula: C6H9 Cl3 Si
• Molecular Weight: 215.582
• Hs Code.: 2931900090
• European Community (EC) Number: 233-377-7
• UN Number: 1762
• UNII: WQR6C3507A
• DSSTox Substance ID: DTXSID60884449
• Nikkaji Number: J36.471A
• Wikidata: Q27292776
• Mol file: 10137-69-6.mol

Synonyms:3-Cyclohexenyltrichlorosilane;10137-69-6;Cyclohexene, 4-(trichlorosilyl)-;Cyclohexenyl trichlorosilane;Trichloro-3-cyclohexenylsilane;trichloro(cyclohex-3-en-1-yl)silane;Silane, trichloro-3-cyclohexen-1-yl-;Trichloro-3-cyclohexen-1-ylsilane;UN1762;Silane, (3-cyclohexenyl)trichloro-;EINECS 233-377-7;BRN 2935909;UNII-WQR6C3507A;WQR6C3507A;CYCLOHEXENYLTRICHLOROSILANE;HSDB 7795;Silane, 3-cyclohexenyltrichloro-;(3,4-cyclohexenyl)trichlorosilane;4-16-00-01554 (Beilstein Handbook Reference);C6H9Cl3Si;Cyclohexnyltrichlorosilane;trichlorosilyl-3-cyclohexene;C6-H9-Cl3-Si;SCHEMBL983841;trichloro(cyclohex-3-enyl)silane;DTXSID60884449;4-(TRICHLOROSILYL)CYCLOHEXENE;MFCD00054173;NA1762;Trichloro(3-cyclohexen-1-yl)silane #;UN 1762;CYCLOHEXENYLTRICHLOROSILANE [HSDB];1-(TRICHLOROSILYL)-3-CYCLOHEXENE;LS-145162;Cyclohexenyltrichlorosilane [UN1762] [Corrosive];Cyclohexenyltrichlorosilane [UN1762] [Corrosive];Q27292776

Chemical Property of 3-Cyclohexenyltrichlorosilane

Chemical Property:

• Appearance/Colour: colourless fuming liquid
• Vapor Pressure: 0.418mmHg at 25°C
• Melting Point: <0°C
• Refractive Index: 1.4905
• Boiling Point: 87-88°C 16mm
• Flash Point: 90°C
• PSA: 0.00000
• Density: 1,25 g/cm3
• LogP: 3.75200
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 213.953910
• Heavy Atom Count: 10
• Complexity: 138
• Transport DOT Label: Corrosive

Purity/Quality:

98% ^*data from raw suppliers

3-CYCLOHEXENYLTRICHLOROSILANE 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 34
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CC(CC=C1)[Si](Cl)(Cl)Cl

Technology Process of 3-Cyclohexenyltrichlorosilane

There total 7 articles about 3-Cyclohexenyltrichlorosilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

cyclohexa-1,4-diene (1165952-92-0) → 4,5-bis(trichlorosilyl)cyclohexene (620987-06-6) + trichloro(cyclohex-3-en-1-yl)silane (10137-69-6)

Guidance literature:

With trichlorosilane; tetra-n-butylphosphonium chloride; at 180 ℃; for 4h;

Reference yield:

cyclohexa-1,4-diene (1165952-92-0) → trichloro(cyclohex-3-en-1-yl)silane (10137-69-6) + (+/-)-3-trichlorosilylcyclohexene (18139-74-7) + cyclohexene (110-83-8) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1)

Guidance literature:

With trichlorosilane; In dodecane; at 230 ℃; for 4h; Temperature; Time; Inert atmosphere;

DOI:10.1016/j.jorganchem.2012.10.015

Reference yield:

cyclohexa-1,3-diene (1165952-91-9) → cyclohexa-1,4-diene (1165952-92-0) + trichloro(cyclohex-3-en-1-yl)silane (10137-69-6) + (+/-)-3-trichlorosilylcyclohexene (18139-74-7) + cyclohexene (110-83-8) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1)

Guidance literature:

With trichlorosilane; In dodecane; at 230 ℃; for 4h; Temperature; Time; Inert atmosphere;

DOI:10.1016/j.jorganchem.2012.10.015

upstream raw materials:

trichlorovinylsilane

buta-1,3-diene

cyclohexa-1,4-diene

cyclohexa-1,3-diene

Downstream raw materials:

trichloro-(3,4-dichloro-cyclohexyl)-silane

(3-cyclohexenyl)trimethylsilane

C₉H₁₈O₃Si

3-cyclohexenylsilane

Refernces

• 1、 Jung, Dong Eui,Han, Joon Soo,Yoo, Bok Ryul. "Thermal reaction of cyclic alkadiene with trichlorosilane. Preparative and mechanistic aspects". . p. 40 - 44. Retrieved 2013/03/13.
• 2、 -. "Trichlorosilyl groups containing organochlorosilanes and their preparation methods by the double-silylation of olefins with trichlorosilane". Page 5. . Retrieved 2008/06/13.