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10388-19-9

10388-19-9

Identification

  • Product Name:Benzamide, 3-iodo-

  • CAS Number: 10388-19-9

  • EINECS:

  • Molecular Weight:247.035

  • Molecular Formula: C7H6INO

  • HS Code:2924299090

  • Mol File:10388-19-9.mol

Synonyms:Benzamide,m-iodo- (7CI,8CI);3-Iodobenzamide;m-Iodobenzamide;

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Safety information and MSDS view more

  • Signal Word:no data available

  • Hazard Statement:no data available

  • First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

  • Fire-fighting measures: Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.

  • Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  • Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

  • Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

Supplier and reference price

  • Manufacture/Brand
  • Product Description
  • Packaging
  • Price
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  • Manufacture/Brand:TRC
  • Product Description:3-Iodobenzamide
  • Packaging:25mg
  • Price:$ 45
  • Delivery:In stock
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  • Manufacture/Brand:TRC
  • Product Description:3-Iodobenzamide
  • Packaging:50mg
  • Price:$ 60
  • Delivery:In stock
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  • Manufacture/Brand:TCI Chemical
  • Product Description:3-Iodobenzamide
  • Packaging:5G
  • Price:$ 199
  • Delivery:In stock
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  • Manufacture/Brand:TCI Chemical
  • Product Description:3-Iodobenzamide
  • Packaging:1G
  • Price:$ 57
  • Delivery:In stock
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  • Manufacture/Brand:Oakwood
  • Product Description:3-Iodobenzamide 98%
  • Packaging:1g
  • Price:$ 45
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  • Manufacture/Brand:Oakwood
  • Product Description:3-Iodobenzamide 98%
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  • Manufacture/Brand:Matrix Scientific
  • Product Description:3-Iodobenzamide 95+%
  • Packaging:25g
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  • Manufacture/Brand:Matrix Scientific
  • Product Description:3-Iodobenzamide 95+%
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  • Manufacture/Brand:Crysdot
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  • Manufacture/Brand:Crysdot
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Relevant articles and documentsAll total 27 Articles be found

Efficient nitriding reagent and application thereof

-

Paragraph 0514-0516, (2021/03/31)

The invention discloses an efficient nitriding reagent and application thereof, wherein the nitriding reagent comprises nitrogen oxide, an active agent, a reducing agent and an organic solvent. By applying the nitriding reagent, nitrogen-containing compounds such as amide, nitrile and the like can be produced, and the method is simple in condition, low in waste discharge amount and simple in reaction equipment.

Visible light-mediated synthesis of amides from carboxylic acids and amine-boranes

Chen, Xuenian,Kang, Jia-Xin,Ma, Yan-Na,Miao, Yu-Qi

supporting information, p. 3595 - 3599 (2021/06/06)

Here, a photocatalytic deoxygenative amidation protocol using readily available amine-boranes and carboxylic acids is described. This approach features mild conditions, moderate-to-good yields, easy scale-up, and up to 62 examples of functionalized amides with diverse substituents. The synthetic robustness of this method was also demonstrated by its application in the late-stage functionalization of several pharmaceutical molecules.

Nitromethane as a nitrogen donor in Schmidt-type formation of amides and nitriles

Jiao, Ning,Liu, Jianzhong,Qiu, Xu,Song, Song,Wei, Jialiang,Wen, Xiaojin,Zhang, Cheng,Zhang, Ziyao

supporting information, p. 281 - 285 (2020/01/28)

The Schmidt reaction has been an efficient and widely used synthetic approach to amides and nitriles since its discovery in 1923. However, its application often entails the use of volatile, potentially explosive, and highly toxic azide reagents. Here, we report a sequence whereby triflic anhydride and formic and acetic acids activate the bulk chemical nitromethane to serve as a nitrogen donor in place of azides in Schmidt-like reactions. This protocol further expands the substrate scope to alkynes and simple alkyl benzenes for the preparation of amides and nitriles.

Transamidation for the Synthesis of Primary Amides at Room Temperature

Chen, Jiajia,Lee, Sunwoo,Xia, Yuanzhi

supporting information, (2020/05/05)

Various primary amides have been synthesized using the transamidation of various tertiary amides under metal-free and mild reaction conditions. When (NH4)2CO3 reacts with a tertiary amide bearing an N-electron-withdrawing substituent, such as sulfonyl and diacyl, in DMSO at 25 °C, the desired primary amide product is formed in good yield with good funcctional group tolerance. In addition, N-tosylated lactam derivatives afforded their corresponding N-tosylamido alkyl amide products via a ring opening reaction.

Base promoted peroxide systems for the efficient synthesis of nitroarenes and benzamides

Gupta, Sampa,Ansari, Alisha,Sashidhara, Koneni V.

supporting information, (2019/09/07)

A useful and efficient approach for the synthesis of nitroarenes from several aromatic amines (including heterocycles) using peroxide and base has been developed. This oxidative reaction is very easy to handle and afforded the products in good yields. Formation of benzamides from benzylamine was also successfully carried out with this metal-free catalytic system in good to excellent yields.

Process route upstream and downstream products

Process route

3-Iodobenzoic acid
618-51-9

3-Iodobenzoic acid

m-iodobenzamide
10388-19-9

m-iodobenzamide

Conditions
Conditions Yield
3-Iodobenzoic acid; With oxalyl dichloride; N,N-dimethyl-formamide; In tetrahydrofuran; for 2h;
With ammonia; In tetrahydrofuran; water; for 1.5h;
99%
3-Iodobenzoic acid; With oxalyl dichloride; In tetrahydrofuran; N,N-dimethyl-formamide; for 2h;
With ammonia; In tetrahydrofuran; water; for 1h;
99%
With ammonium hydroxide; oxalyl dichloride; In dichloromethane; at 23 ℃; for 2h;
90%
3-Iodobenzoic acid; With Rink amide linker attached to polystyrene resin; benzotriazol-1-yloxyl-tris-(pyrrolidino)-phosphonium hexafluorophosphate; N-ethyl-N,N-diisopropylamine; In N,N-dimethyl-formamide; at 110 ℃; for 0.333333h; microwave irradiation;
With trifluoroacetic acid; at 70 ℃; for 0.333333h; microwave irradiation;
62%
With tris[2-phenylpyridinato-C2,N]iridium(III); dipotassium hydrogenphosphate; borane-ammonia complex; di-tert-butyl dicarbonate; magnesium chloride; In acetonitrile; at 20 ℃; for 36h; Schlenk technique; Irradiation; Green chemistry;
47%
Multi-step reaction with 2 steps
1: SOCl2 / 3 h / Heating
2: 19.2 g / ammonia / tetrahydrofuran / 15 h / -78 - -40 °C
With thionyl chloride; ammonia; In tetrahydrofuran;
Multi-step reaction with 2 steps
1: (COCl)2; DMF / CH2Cl2 / 2 h
2: 18percent aq. NH4OH / 0.25 h / 0 °C
With oxalyl dichloride; N,N-dimethyl-formamide; In dichloromethane; 1: Chlorination / 2: Substitution;
3-Iodobenzoic acid; With 1,1'-carbonyldiimidazole; In dichloromethane; at 20 ℃; for 0.333333h; Inert atmosphere;
With ammonium hydroxide; In dichloromethane; at 20 ℃; for 3h; Inert atmosphere;
m-iodobenzaldehyde
696-41-3

m-iodobenzaldehyde

m-iodobenzamide
10388-19-9

m-iodobenzamide

Conditions
Conditions Yield
With hydroxylamine hydrochloride; caesium carbonate; In water; dimethyl sulfoxide; at 125 ℃; for 48h;
66%
3-Iodotoluene
625-95-6

3-Iodotoluene

m-iodobenzamide
10388-19-9

m-iodobenzamide

Conditions
Conditions Yield
3-Iodotoluene; With N-hydroxyphthalimide; 1,1,1,3',3',3'-hexafluoro-propanol; oxygen; cobalt(II) diacetate tetrahydrate; at 25 ℃; for 12h;
With nitromethane; trifluoromethylsulfonic anhydride; In formic acid; at 80 - 120 ℃;
40%
3-Iodotoluene; With N-hydroxyphthalimide; 1,1,1,3',3',3'-hexafluoro-propanol; oxygen; cobalt(II) diacetate tetrahydrate; at 20 ℃; for 12h; under 760.051 Torr;
With formic acid; nitromethane; trifluoromethylsulfonic anhydride; In acetic acid; at 100 ℃; for 12h;
40%
m-iodobenzamide
10388-19-9

m-iodobenzamide

Conditions
Conditions Yield
With chromium(VI) oxide; sulfuric acid; iodine; In acetic anhydride; acetic acid; at 20 - 45 ℃; for 5h;
88%
With sulfuric acid; triiodoisocyanuric acid; acetic acid; at 20 ℃; for 144h; regioselective reaction; Darkness;
88%
With sodium iodate; iodine; In sulfuric acid; at 25 - 30 ℃; for 1h;
74%
With sodium periodate; sulfuric acid; iodine; at 23 ℃;
72%
With manganese(IV) oxide; sulfuric acid; iodine; In acetic anhydride; acetic acid; at 70 ℃; for 3h;
70%
With sodium periodate; sulfuric acid; potassium iodide; at 25 - 30 ℃; for 1h;
70%
With manganese(IV) oxide; sulfuric acid; iodine; acetic anhydride; In acetic acid; 1.) room temperature, 2 h, 2.) 45-55 deg C, 2 h, 3.) room temperature, overnight;
63%
With sodium periodate; acetic anhydride; acetic acid; sulfuric acid; Heating;
61%
With tetramethylammonium hydrogen sulfate; at 20 ℃; for 0.25h;
56%
With sulfuric acid; sulfur trioxide; iodine;
3-iodo-N-phenyl-N-tosylbenzamide

3-iodo-N-phenyl-N-tosylbenzamide

m-iodobenzamide
10388-19-9

m-iodobenzamide

Conditions
Conditions Yield
With ammonium carbonate; In dimethyl sulfoxide; at 25 ℃; for 6h;
86%
oxalyl dichloride
79-37-8

oxalyl dichloride

3-Iodobenzoic acid
618-51-9

3-Iodobenzoic acid

m-iodobenzamide
10388-19-9

m-iodobenzamide

Conditions
Conditions Yield
With ammonia; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide;
3.5 g (87%)
diethyl ether
60-29-7,927820-24-4

diethyl ether

3-Iodobenzoic acid
618-51-9

3-Iodobenzoic acid

m-iodobenzamide
10388-19-9

m-iodobenzamide

Conditions
Conditions Yield
With thionyl chloride; ammonia; In benzene;
3-Aminobenzamide
3544-24-9

3-Aminobenzamide

m-iodobenzamide
10388-19-9

m-iodobenzamide

Conditions
Conditions Yield
With N-iodo-succinimide; sodium nitrite; In N,N-dimethyl-formamide; at 20 ℃; for 4h;
77%
3-iodobenzoyl chloride
1711-10-0

3-iodobenzoyl chloride

m-iodobenzamide
10388-19-9

m-iodobenzamide

Conditions
Conditions Yield
With ammonium hydroxide; diethyl ether;
With ammonia; In tetrahydrofuran; at -78 - -40 ℃; for 15h;
19.2 g
With 18percent aq. NH4OH; at 0 ℃; for 0.25h;
benzonitrile
100-47-0

benzonitrile

m-iodobenzamide
10388-19-9

m-iodobenzamide

Conditions
Conditions Yield
With sodium periodate; acetic anhydride; acetic acid; sulfuric acid; Heating;
59%

Global suppliers and manufacturers

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  • Amadis Chemical Co., Ltd.
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  • Win-Win chemical Co.Ltd
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  • Hangzhou Dingyan Chem Co., Ltd
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  • Finetech Industry Limited
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