Relevant articles and documents
All total 4 Articles be found
Sawton, E. A.,Weber, J. Q.
, p. 4755 (1959)
Some chemistry of difluoraminocarbonyl chloride. A new route to perfluorourea
Wright, Kenneth J.,Shreeve, Jean'ne M.
, p. 77 - 80 (2007/10/12)
Improved yields of NF2C(O)Cl are obtained by short-term (4-6 hr) photolysis of N2F4 with oxalyl chloride. Reactions of NF2C(O)Cl with AgCN, AgNCS, AgNCO, Hg(SCF3)2 and Hg(ON(CF3)2)2 give the new difluoraminocarbonyl pseudohalides NF2C(O)CN, NF2C(O)NCS, NF2C(O)NCO, NF2C(O)SCF3, and NF2C(O)ON(CF3)2. With excess of either Ag2O at 0° or HgO at -78°, NF2C(O)Cl is converted to (NF2)2CO and CO2 in nearly quantitative yield. Chlorocarbonyl fluorosulfate results when NF2C(O)Cl is mixed with S2O6F2 or BrOSO2F.
Some chemistry of difluoraminocarbonyl fluoride, NF2CFO. The preparation of perfluorourea, (NF2)2CO, and difluoraminocarbonyl chloride, NF2C(O)Cl. New preparations for NF2OCF3 and NF2<
Fraser, George W.,Shreeve, Jean'ne M.
, p. 1711 - 1715 (2008/10/08)
Reactions of NF2CFO with CF3OF or with Al2Cl6 and HCl yield NF2OCF3 or NF2C(O)Cl, respectively. The reactions of NF2CFO with KF and CsF to give KOCF2NF