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2-ISOPROPYL-5-METHYLCYCLOHEXYL CHLOROACETATE is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 106916-72-7 Structure
  • Basic information

    1. Product Name: 2-ISOPROPYL-5-METHYLCYCLOHEXYL CHLOROACETATE
    2. Synonyms: CHLORO-ACETIC ACID 2-ISOPROPYL-5-METHYL-CYCLOHEXYL ESTER;2-ISOPROPYL-5-METHYLCYCLOHEXYL CHLOROACETATE;Chloroacetic acid menthyl ester;Chloroacetic acid p-menthan-3-yl ester
    3. CAS NO:106916-72-7
    4. Molecular Formula: C12H21ClO2
    5. Molecular Weight: 232.75
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 106916-72-7.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 2-ISOPROPYL-5-METHYLCYCLOHEXYL CHLOROACETATE(CAS DataBase Reference)
    10. NIST Chemistry Reference: 2-ISOPROPYL-5-METHYLCYCLOHEXYL CHLOROACETATE(106916-72-7)
    11. EPA Substance Registry System: 2-ISOPROPYL-5-METHYLCYCLOHEXYL CHLOROACETATE(106916-72-7)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 106916-72-7(Hazardous Substances Data)

106916-72-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 106916-72-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,6,9,1 and 6 respectively; the second part has 2 digits, 7 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 106916-72:
(8*1)+(7*0)+(6*6)+(5*9)+(4*1)+(3*6)+(2*7)+(1*2)=127
127 % 10 = 7
So 106916-72-7 is a valid CAS Registry Number.

106916-72-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name l-menthyl chloroacetate

1.2 Other means of identification

Product number -
Other names (-)-menthylchloroacetate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:106916-72-7 SDS

106916-72-7Relevant articles and documents

Novel ketoprofen–antioxidants mutual codrugs as safer nonsteroidal anti-inflammatory drugs: Synthesis, kinetic and pharmacological evaluation

Sehajpal, Shikha,Prasad, Deo Nandan,Singh, Rajesh K.

, (2019)

Ketoprofen belongs to one of the most common nonsteroidal anti-inflammatory drugs (NSAIDs) but its clinical usefulness has been restricted due to the high incidence of gastrointestinal complications. The release of reactive oxygen species (ROS) in NSAIDs

Synthesis, characterization and physicochemical properties of new chiral quinuclidinol quaternary ammonium salts

Li, Ruoheng,Li, Zicheng,Song, Hang,Wang, Zhixia,Xu, Qiwei,Yao, Shun

, (2020)

A new series of chiral quaternary ammonium salts (QASs) were successfully synthesized and characterized by FT-IR, NMR and MS. The thermal stability and melting point (mp) of the chiral QASs were measured. Moreover, basic physicochemical properties of the

Solvent- and base-free dicyclohexylcarbodiimide-promoted esterifications

Streinz,Koutek,?aman

, p. 809 - 811 (2001)

N,N'-Dicyclohexylcarbodiimide/base-promoted esterification of carboxylic acids containing α-halogen atom(s) gave low yields of products when performed in a solvent. This failure was found to be due to the low stability of appropriate intermediates under t

Using chiral ionic liquid additives to enhance asymmetric induction in a Diels-Alder reaction

Goodrich,Nimal Gunaratne,Hall,Wang,Jin,Muldoon,Ribeiro,Pombeiro,Parvulescu,Davey,Hardacre

, p. 1704 - 1713 (2017)

A bis-oxazoline ligand has been complexed using Cu(ii) and Zn(ii) trifluoromethanesulfonate and a range of chiral ionic liquid (CIL) additives based on natural products were used as a co-catalyst for a Diels-Alder reaction. The catalytic performance of th

Synthesis, characterization and applications of some novel DMAP-based chiral ionic liquids

Singh, Avtar,Chopra, Harish Kumar

, p. 106 - 111 (2018)

A convenient and efficient procedure for the synthesis of some novel chiral ionic liquids (CILs) from 4-dimethylaminopyridinium cation has been reported. The synthesis of the CILs includes the treatment of optically active (?)-menthyl ester with 4-dimethy

New benzimidazolium-based chiral ionic liquids: Synthesis and application in enantioselective sodium borohydride reductions in water

Singh, Avtar,Chopra, Harish Kumar

, p. 448 - 453 (2016)

New chiral ionic liquids based on benzimidazolium salts have been synthesized from the reaction of (-)-menthol or (-)-borneol, chloroacetic acid and 1-methylbenzimidazole. The structures of these chiral ionic liquids have been confirmed from 1H

SYNTHESIS AND STRUCTURE OF AMINO ESTERS OF MENTHOL

Raikova, T. S.,Kalechits, G. V.,Manukov, E. N.,Vyalimyae, T. K.,Makhach, S. A.

, p. 526 - 529 (1981)

The conditions for the acylation of (-)-menthol with monochloroacetyl chloride have been studied.Amino esters of (-)-menthol have been obtained by the nuclephilic replacement of the chlorine in (-)-menthol monochloroacetate by residues of secondary amines

S-Substituted-2-mercaptobenzthiazolium-based chiral ionic liquids: efficient organocatalysts for enantioselective sodium borohydride reductions of prochiral ketones

Singh, Avtar,Chopra, Harish Kumar

, p. 414 - 418 (2017)

Novel chiral ionic liquids having chirality in their cationic part have been synthesized for evaluation of their catalytic potential as organocatalysts in sodium borohydride reduction of prochiral ketones to yield optically active secondary alcohols. The chiral ionic liquids have been synthesized from the reaction of (?)-menthol or (?)-borneol, chloroacetic acid and S-methyl/benzyl-2-mercaptobenzthiazole. The synthesized chiral ionic liquids have been characterized by 1H, 13C NMR and Mass spectrometry. Moderate to excellent enantiomeric excess (ee?>?99%) has been obtained in asymmetric sodium borohydride reduction of prochiral ketones using these salts as chiral catalysts.

Characterization of Enantiomeric Pairs of Optically Active 10-P-5 Phosphoranes with Asymmetry Only at Phosphorus

Kojima, Satoshi,Kajiyama, Kazumasa,Akiba, Kin-Ya

, p. 1785 - 1798 (1995)

Diastereomeric phosphoranes (o-OC(CF3)2C6H4)2P*CH2CO2-(-)-menthyl (3-RP and 3-SP) of which absolute stereochemistry was determined were treated with LiAlH4 to give (o-OC(CF3)2C6H4)2P*CH2CH2OH (4-RP and 4-SP) as the first optically active pair of enantiomeric phosphoranes of rigid stereochemistry with asymmetry only upon the pentacoordinate phosphorus atom.The high enantiomeric purities of the alcohols were confirmed by converting them to their (+)-MTPA esters.Furthermore, when diastereomeric phosphoranes (o-OC(CF3)2C6H4)2P*CH2NHC*HCH3Ph (10-RP and 10-SP) of which absolute stereochemistry was also determined were treated with MeLi the first optically active pair of enantiomeric P-H phosphoranes (o-OC(CF3)2C6H4)2P*H (2-RP and 2-SP) with asymmetry only upon the pentacoordinate phosphorus atom could be obtained.The high enantiomeric purities of the P-H phosphoranes were confirmed by converting each of them to their corresponding (-)-menthyl esters 3-RP and 3-SP.

Stereoselective oxidation of methyl phenyl sulfide in the presence of chiral ionic liquids

Akopyan,Rakhmanov,Grigor'Ev,Ryzhov,Tarakanova,Anisimov

, p. 1302 - 1307 (2014)

Several ionic liquids containing a chiral center either in the cation or in the anion have been prepared. They have been applied as catalysts and solvents for stereoselective oxidation of methyl phenyl sulfide to obtain the respective sulfoxide.

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