108167-42-6

Basic information

• Product Name: 3-Pentafluorophenyl-oxaziridine-2-sulfonic acid benzyl-((S)-1-phenyl-ethyl)-amide
• CAS NO: 108167-42-6
• Molecular Weight: 484.447
• Mol File: 108167-42-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3-Pentafluorophenyl-oxaziridine-2-sulfonic acid benzyl-((S)-1-phenyl-ethyl)-amide(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Pentafluorophenyl-oxaziridine-2-sulfonic acid benzyl-((S)-1-phenyl-ethyl)-amide(108167-42-6)
• EPA Substance Registry System: 3-Pentafluorophenyl-oxaziridine-2-sulfonic acid benzyl-((S)-1-phenyl-ethyl)-amide(108167-42-6)

Safety Data

• Hazardous Substances Data: 108167-42-6(Hazardous Substances Data)

Upstream product

• 108167-35-7 (S)-N-(pentafluorobenzylidene)-N'-(α-methylbenzyl)-N'-benzylsulfamide 
• 653-37-2 perfluorobenzaldehyde 
• 100-52-7 benzaldehyde 
• 89556-73-0 (-)(S)-N-(α-methylbenzyl-N-benzylamine)sulfamide 
• 3129-98-4 (S)-N-benzylidene(1-phenylethylamine) 
• 17480-69-2 (S)-N-benzyl-1-phenylethylamine 
• 2627-86-3 (S)-1-phenyl-ethylamine 

Downstream Products

• 1439-07-2 (R,R)-trans-stilbene epoxide 
• 1439-07-2 (S,S)-trans-stilbene oxide 
• 4518-66-5 (1S,2S)-(-)-1-phenyl-1-propene oxide 
• 14212-54-5 (+)-(R,R)-β-methylstyrene oxide 
• 20780-53-4 (R)-Styrene oxide 
• 20780-54-5 (S)-styrene oxide 

Relevant articles and documents

ASYMMETRIC EPOXIDATION OF NONFUNCTIONALIZED ALKENES WITH HIGH ENANTIOSELECTIVITY USING CHIRAL SULFAMYLOXAZIRIDINES

High enantioselectivities (19-65percent ee) are reported for the asymmetric epoxidation of a series of nonfunctionalized alkenes using chiral sulfamyloxaziridines (1b/2b).

Chemistry of Oxaziridines. 8. Asymmetric Oxidation of Nonfunctionalized Sulfides to Sulfoxides with High Enantioselectivity by 2-Sulfamyloxaziridines. The Influence of the Oxaziridine C-Aryl Group on the Asymmetric Induction

Chiral sulfamyloxaziridines 6 and 7, prepared by biphasic oxidation of the corresponding sulfamylimines 5, afford high asymmetric induction for the oxidation of a series of nonfunctionalized sulfides to sulfoxides (53-91percent ee).The enantioselectivitie