1118-39-4 Usage
Occurrence
Has apparently not been reported to occur in nature
Preparation
By cold acetylation of myrcenol (Arctander, 1969).
Flammability and Explosibility
Nonflammable
Safety Profile
Mildly toxic by ingestion. A skinirritant. When heated to decomposition itemits acrid smoke and irritating fumes.
Check Digit Verification of cas no
The CAS Registry Mumber 1118-39-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,1,1 and 8 respectively; the second part has 2 digits, 3 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 1118-39:
(6*1)+(5*1)+(4*1)+(3*8)+(2*3)+(1*9)=54
54 % 10 = 4
So 1118-39-4 is a valid CAS Registry Number.
InChI:InChI=1/C12H20O2/c1-6-10(2)8-7-9-12(4,5)14-11(3)13/h6H,1-2,7-9H2,3-5H3
1118-39-4Relevant articles and documents
Ruthenium-Catalyzed Cross Metathesis of β-Myrcene and its Derivatives with Methyl Acrylate
Behr, Arno,Johnen, Leif,Wintzer, Andreas,Gümü? ?etin, Arzu,Neubert, Peter,Domke, Lutz
, p. 515 - 522 (2016)
The reaction of β-myrcene with methyl acrylate produces 3-methylenecyclopent-1-ene in the presence of the Ru catalyst Neolyst M2 by ring-closing metathesis in the first step. In the second step, the generated methylidene unit reacts with methyl acrylate to give the corresponding unsaturated cyclic ester by cross metathesis. Under the optimized reaction conditions (80 °C, Neolyst M2, 16 equivalents of methyl acrylate), derivatives of β-myrcene, myrcenol, myrcenyl acetate, and β-ocimene, react to yield functionalized acyclic esters.
