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3-Bromo-9-phenylcarbazole is an organic compound characterized by its off-white powder form. It is a derivative of carbazole, with a bromine atom at the 3-position and a phenyl group at the 9-position. This unique structure endows it with specific chemical properties that make it suitable for various applications.

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  • 1153-85-1 Structure
  • Basic information

    1. Product Name: 3-Bromo-9-phenylcarbazole
    2. Synonyms: 3-Bromo-9-phenylcarbazole;3-bromo-9-phenyl-9H-carbazole;3-Bromo-N-phenylcarbazole;3-bromo-N-phenyl-9H-carbazole;N-Phenyl-3-broMocarbazole;3-BroMo-N-phenylcarbazol;9H-Carbazole, 3-broMo-9-phenyl- Carbazole, 3-broMo-9-phenyl- (8CI);3-broMo-9-phenyl-9H-carbazole (3BPC)
    3. CAS NO:1153-85-1
    4. Molecular Formula: C18H12BrN
    5. Molecular Weight: 322.2
    6. EINECS: 1312995-182-4
    7. Product Categories: organic chemicals and derivatives/others;OLED;carbazol;OLED materials,pharm chemical,electronic
    8. Mol File: 1153-85-1.mol
  • Chemical Properties

    1. Melting Point: 98 ºC
    2. Boiling Point: 461.7 °C at 760 mmHg
    3. Flash Point: 233 °C
    4. Appearance: /Solid
    5. Density: 1.39
    6. Vapor Pressure: 1.05E-08mmHg at 25°C
    7. Refractive Index: 1.672
    8. Storage Temp.: Sealed in dry,Room Temperature
    9. Solubility: N/A
    10. Water Solubility: Slightly soluble in water.
    11. CAS DataBase Reference: 3-Bromo-9-phenylcarbazole(CAS DataBase Reference)
    12. NIST Chemistry Reference: 3-Bromo-9-phenylcarbazole(1153-85-1)
    13. EPA Substance Registry System: 3-Bromo-9-phenylcarbazole(1153-85-1)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1153-85-1(Hazardous Substances Data)

1153-85-1 Usage

Uses

Used in the Manufacturing of OLED Materials:
3-Bromo-9-phenylcarbazole is used as a key component in the production of organic light-emitting diode (OLED) materials. Its electronic and photophysical properties contribute to the efficient performance and emission characteristics of OLED devices, making it an essential material for the development of advanced display and lighting technologies.
Used as an Intermediate in Pharmaceutical Synthesis:
3-Bromo-9-phenylcarbazole also serves as an intermediate in the synthesis of various pharmaceutical compounds. Its unique structure allows for further chemical modifications and functionalization, enabling the development of new drugs with potential therapeutic applications in the medical field.

Check Digit Verification of cas no

The CAS Registry Mumber 1153-85-1 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,1,5 and 3 respectively; the second part has 2 digits, 8 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 1153-85:
(6*1)+(5*1)+(4*5)+(3*3)+(2*8)+(1*5)=61
61 % 10 = 1
So 1153-85-1 is a valid CAS Registry Number.
InChI:InChI=1/C18H12BrN/c19-13-10-11-18-16(12-13)15-8-4-5-9-17(15)20(18)14-6-2-1-3-7-14/h1-12H

1153-85-1 Well-known Company Product Price

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  • (Code)Product description
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  • Alfa Aesar

  • (H64212)  3-Bromo-9-phenylcarbazole, 98%   

  • 1153-85-1

  • 5g

  • 382.0CNY

  • Detail
  • Alfa Aesar

  • (H64212)  3-Bromo-9-phenylcarbazole, 98%   

  • 1153-85-1

  • 25g

  • 1529.0CNY

  • Detail
  • Alfa Aesar

  • (H64212)  3-Bromo-9-phenylcarbazole, 98%   

  • 1153-85-1

  • 100g

  • 6115.0CNY

  • Detail

1153-85-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-Bromo-9-phenylcarbazole

1.2 Other means of identification

Product number -
Other names 3-bromanyl-9-phenyl-carbazole

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1153-85-1 SDS

1153-85-1Relevant articles and documents

Pyridyl Pyrrolide Boron Complexes: The Facile Generation of Thermally Activated Delayed Fluorescence and Preparation of Organic Light-Emitting Diodes

Shiu, Yi-Jiun,Cheng, Yung-Chen,Tsai, Wei-Lung,Wu, Chung-Chih,Chao, Chun-Tien,Lu, Chin-Wei,Chi, Yun,Chen, Yi-Ting,Liu, Shih-Hung,Chou, Pi-Tai

, p. 3017 - 3021 (2016)

The electron positive boron atom usually does not contribute to the frontier orbitals for several lower-lying electronic transitions, and thus is ideal to serve as a hub for the spiro linker of light-emitting molecules, such that the electron donor (HOMO)

Novel bifluorene based conjugated systems: Synthesis and properties

Grisorio, Roberto,Dell'Aquila, Antonio,Romanazzi, Giuseppe,Suranna, Gian Paolo,Mastrorilli, Piero,Cosma, Pynalisa,Acierno, Domenico,Amendola, Eugenio,Ciccarella, Giuseppe,Nobile, Cosimo Francesco

, p. 627 - 634 (2006)

A series of novel bifluorene based systems was synthesised by a convergent approach by means of a Suzuki cross-coupling between 7,7′-bis-(4,4,5,5- tetramethyl-[1,3,2]dioxaborolan-2-yl)-9,9,9′,9′-tetraoctyl-2, 2′-bifluorene and suitable aryl-bromides. All

Efficient thermally activated delayed fluorescence of functional phenylpyridinato boron complexes and high performance organic light-emitting diodes

Shiu, Yi-Jiun,Chen, Yi-Ting,Lee, Wei-Kai,Wu, Chung-Chih,Lin, Tzu-Chieh,Liu, Shih-Hung,Chou, Pi-Tai,Lu, Chin-Wei,Cheng, I-Chen,Lien, Yi-Jyun,Chi, Yun

, p. 1452 - 1462 (2017)

A new series of functional phenylpyridinato boron complexes possessing thermally activated delayed fluorescence (TADF) has been strategically designed and synthesized. These boron complexes utilize phenylpyridine as the electron acceptor (A) that links to carbazole or triphenyl amine as the electron donor (D) via a core boron atom, forming four-coordinate neutral boron complexes. The selection of boron to spatially separate the donor and acceptor takes advantage of facile functionalization. The TADF properties of the resulting D-A functional materials in various solvents have been investigated via their emission spectra and associated relaxation dynamics. The results show that the operation of TADF is strongly solvent polarity dependent in fluid states, and several underlying mechanisms are discussed. OLEDs fabricated by fppyBTPA and dfppyBTPA show EL efficiencies of up to (20.2%, 63.9 cd A?1, 66.9 lm W?1) and (26.6%, 88.2 cd A?1, 81.5 lm W?1), respectively, in which a nearly 27% EQE for the dfppyBTPA device is among the most efficient TADF OLEDs so far.

Imidazolyl-Phenylcarbazole-Based Host Materials and Their Use for Co-host Designs in Phosphorescent OLEDs

Yi, Rong-Huei,Lei, Ya-Chun,Tseng, Yeh-Hsiang,Lin, Yi-Fan,Cheng, Yen-Chia,Fang, Yu-Chuan,Ho, Cheng-Yung,Tsai, Wei-Wen,Chang, Chih-Hao,Lu, Chin-Wei

, (2021/12/06)

In recent years, owing to the demand for high-efficiency phosphorescent organic light-emitting devices (PhOLEDs), many studies have been conducted on the development of bipolar host materials. A series of imidazolyl-phenylcarbazole-based host materials, i

Method for synthesizing high-purity 3-bromine-N-phenylcarbazole

-

Paragraph 0049-0084, (2021/01/24)

The invention discloses a method for synthesizing high-purity 3-bromo-N-phenylcarbazole, and belongs to the technical field of chemistry. The method comprises the following steps: dissolving N-phenylcarbazole in a solvent, sequentially adding a brominatin

Amine-based compound and organic light emitting diode comprising the same

-

Paragraph 0223; 0229-0230, (2021/03/16)

Disclosed are an amine-based compound and an organic light emitting device including the same. The amine-based compound is represented by chemical formula 1A.

Organic compound, and organic electroluminescent device and electronic device using the same

-

Paragraph 0129-0131; 0132; 0135, (2021/11/10)

The present invention relates to an organic compound and an organic electroluminescent device and an electronic device using the same, wherein the organic compound has a structure formed by combining an indole carbazole-based planar conjugated group in a fused manner and a dibenzofuran substituted with an aryl group. The structure has higher hole mobility and higher energy transfer efficiency, and is suitable for being used as a light-emitting host material in an organic electroluminescent device. When the organic compound is used as a light emitting host material in an organic electroluminescent device, the light emitting efficiency and the service life of the device can be effectively improved, and the working voltage is reduced.

COMPOSITION, ORGANIC OPTOELECTRONIC DEVICE, AND DISPLAY DEVICE

-

Paragraph 0163; 0168-0169; 0280-0282, (2021/03/13)

A composition including a first compound represented by a combination of Chemical Formula 1 and Chemical Formula 2, and a second compound represented by Chemical Formula 3, an organic optoelectronic device, and a display device are related. In Chemical Formula 1 to Chemical Formula 3, each substituent is the same as described in the specification.

Thiophene ethylene malononitrile structural compound and preparation method thereof

-

Paragraph 0069-0071, (2021/04/28)

The invention discloses a thiophene ethylene malononitrile structural compound and a preparation method thereof. The structural formula is shown in the specification. The thiophene ethylene malononitrile structural compound is obtained through multi-step

Preparation method of 3 - bromo - N - phenyl carbazole

-

Paragraph 0024; 0032-0038; 0039; 0047-0053, (2021/10/11)

The invention relates to a preparation method of 3 -bromo - N -phenyl carbazole, and belongs to the technical field of organic chemistry. To the invention, diphenylamine serves as a starting raw material, and 2 -bromophenylaniline is obtained through bromination reaction. Then, intramolecular cyclization is carried out to obtain carbazole. Then, 3 - bromocarbazole is obtained by bromination reaction. Finally, a substituted 3 - bromo - N -phenyl carbazole is obtained. By controlling the concentration and reaction environment of the reactants, the selectivity of the reaction site is effectively improved, the used raw materials are simple and easy to obtain, the preparation period is relatively short, and the reaction process is simple and easy to control.

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