15086-10-9Relevant articles and documents
Influence of superfluidity on recombination reactions of H + T → HT and T + T → T2 in 3He-4He quantum media under saturated vapor pressure at 1.6 K
Aratono, Yasuyuki,Iguchi, Kazunari,Okuno, Kenji,Kumada, Takayuk
, p. 3741 - 3746 (2003)
An influence of superfluidity on chemical reaction has been studied in the recombination reactions of hydrogen (H) and tritium (T) atoms, H + T → HT and T + T → T2, in 3He-4He mixture solutions at 1.6 K. The reactive species, H and T atoms, were produced in the mixture through the nuclear reaction, 3He + n → p(H) + T. Experimental yield ratio of HT to T2 was 110 ± 17 in normal-fluid solution. However, in superfluid solution, the value decreased to 60 with a decrease in atomic fraction of 3He. A two-fluid model was applied to estimate the contribution of superfluidity. The calculated yield of HT to T2 in the superfluid component became almost a constant value of 56 ± 14 over the whole range of superfluid solution studied. On the basis of preferential formation of HT over T2 and a computer simulation of relative rate constants, formation of hydrogen isotope bubbles and their tunneling recombination were proposed.
Non-statistical formation of J=1 T2 (ortho- T2 ) in recombination reaction of T+T+M→T2+M in liquid helium at 1.42-2.50 K
Iguchi, Kazunari,Kumada, Takayuki,Okuno, Kenji,Aratono, Yasuyuki
, p. 421 - 425 (2008/10/08)
During the course of an investigation on chemical behaviors of hydrogen isotopes in quantum media, non-statistical formation of ortho-T2 was observed in recombination reaction of T+T+3,4He→T2+3,4He in liquid su
Chemical Erosion of Irradiated Graphite
Tsetskhladze, T. V.,Cherkezishvili, L. I.,Tsibakhashvili, N. Ya.
, p. 864 - 865 (2007/10/02)
We have studied the chemical processess occuring in graphite under the action of recoil tritium atoms.The reaction products have been identified and the dependence of their yields on the annealing temperature established.
