76-14-2Relevant articles and documents
Zitter et al.
, p. 2578 (1975)
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Iwasaki
, p. 1071 (1958)
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PROCESS FOR PREPARING FLUORINE-CONTAINING PROPANE
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Page/Page column 9-10, (2010/12/17)
The present invention provides a process for preparing a fluorine-containing propane represented by the formula: CF2XCF2CH3 wherein X is F or Cl, the process including reacting tetrafluoroethylene and methyl chloride in the presence of an antimony halide represented by the formula: SbFxC5-x wherein x is a value of 0 to 5. According to the present invention, the fluorine-containing propane represented by the formula: CF2XCF2CH3 wherein X is F or Cl, which is useful as a starting material of 2,3,3,3-tetrafluoropropene (1234yf), can be obtained by a simple process, using relatively inexpensive starting materials.
PHOTOCHLORINATION AND FLUORINATION PROCESS FOR PREPARATION OF FLUORINE-CONTAINING HYDROCARBONS
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Page/Page column 12, (2008/06/13)
A process is disclosed for increasing the fluorine content of at least one compound selected from halohydrocarbons and hydrocarbons. The process involves (a) directing light from a light source through the wall of a reactor to interact with reactants comprising chlorine and said at least one compound in said reactor, thereby producing a halogenated hydrocarbon having increased chlorine content by photochlorination, and (b) reacting said halogenated hydrocarbon produced by the photochlorination in (a) with HF; and is characterized by the light directed through the reactor wall being directed through a poly(perhaloolefin) polymer.