1611-56-9Relevant articles and documents
Synthesis of Terminally Substituted 9-Alkylidene-10-methyl Acridans
Varveri, Fannie S.,Nikokavouras, John,Mantaka-Marketou, Anastasia E.,Micha-Screttas, Maria
, p. 967 - 972 (1989)
ω-Substituted undecanals 1 and 2 reacted with acridine derivatives 3 and 5 to give the terminally substituted 9-alkylidene-10-methylacridans 6.The compounds prepared were highly fluorescent and exhibited chemiluminescent activity. - Keywords: Acridans; Chemiluminescence.
(Z,Z)-5,27-tritriacontadiene: Major sex pheromone of Drosophila pallidosa (Diptera; Drosophilidae)
Nemoto,Doi,Oshio,Matsubayashi,Oguma,Suzuki,Kuwahara
, p. 3029 - 3037 (1994)
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Rosen,Hybl
, p. 610,615 (1972)
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Me3SI-promoted chemoselective deacetylation: a general and mild protocol
Gurawa, Aakanksha,Kashyap, Sudhir,Kumar, Manoj
, p. 19310 - 19315 (2021/06/03)
A Me3SI-mediated simple and efficient protocol for the chemoselective deprotection of acetyl groups has been developedviaemploying KMnO4as an additive. This chemoselective deacetylation is amenable to a wide range of substrates, tolerating diverse and sensitive functional groups in carbohydrates, amino acids, natural products, heterocycles, and general scaffolds. The protocol is attractive because it uses an environmentally benign reagent system to perform quantitative and clean transformations under ambient conditions.
Highly Chemoselective Deprotection of the 2,2,2-Trichloroethoxycarbonyl (Troc) Protecting Group
Trost, Barry M.,Kalnmals, Christopher A.,Tracy, Jacob S.,Bai, Wen-Ju
supporting information, p. 8043 - 8046 (2019/01/04)
Nonreducing, pH-neutral conditions for the selective cleavage of the 2,2,2-trichloroethoxycarbonyl (Troc) protecting group are reported. Using trimethyltin hydroxide in 1,2-dichloroethane, Troc-protected alcohols, thiols, and amines can be selectively unmasked in the presence of various functionalities that are incompatible with the reducing conditions traditionally used to remove the Troc group. This mild deprotection protocol tolerates a variety of other hydrolytically sensitive and acid/base-sensitive moieties as well.