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16310-13-7

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16310-13-7 Usage

Chemical Properties

white powder

Uses

rac-2-?Thiazolidinecarboxyl?ic Acid is a derivative of thiazolidyne-?4-?carboxylic acid (thiaproline) (T344205) and can be used as a colouring agent. Futhermore, it may be a physiological substrate for D-?amino acid oxidase.

Check Digit Verification of cas no

The CAS Registry Mumber 16310-13-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,6,3,1 and 0 respectively; the second part has 2 digits, 1 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 16310-13:
(7*1)+(6*6)+(5*3)+(4*1)+(3*0)+(2*1)+(1*3)=67
67 % 10 = 7
So 16310-13-7 is a valid CAS Registry Number.
InChI:InChI=1/C4H7NO2S/c6-4(7)3-5-1-2-8-3/h3,5H,1-2H2,(H,6,7)/t3-/m1/s1

16310-13-7 Well-known Company Product Price

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  • Alfa Aesar

  • (A11564)  Thiazolidine-2-carboxylic acid, 97%   

  • 16310-13-7

  • 5g

  • 763.0CNY

  • Detail
  • Alfa Aesar

  • (A11564)  Thiazolidine-2-carboxylic acid, 97%   

  • 16310-13-7

  • 25g

  • 3226.0CNY

  • Detail
  • Alfa Aesar

  • (A11564)  Thiazolidine-2-carboxylic acid, 97%   

  • 16310-13-7

  • 100g

  • 10611.0CNY

  • Detail

16310-13-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name Thiazolidine-2-carboxylic acid

1.2 Other means of identification

Product number -
Other names THIAZOLIDINE-2-CARBOXYLIC ACID

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:16310-13-7 SDS

16310-13-7Relevant articles and documents

Identification and quantitation of key aroma compounds formed in Maillard-type reactions of fructose with cysteamine or isothiaproline (1,3-thiazolidine-2-carboxylic acid)

Engel, Wolfgang,Schieberle, Peter

, p. 5394 - 5399 (2002)

Fructose was reacted in the presence of either cysteamine (model A) or isothiaproline (model B) in aqueous buffer at 145 °C and pH 7.0. Application of an aroma extract dilution analysis on the bulk of the volatile compounds formed in model A revealed 5-acetyl-3,4-dihydro-2H-1,4-thiazine (19), N-(2- mercaptoethyl)-1,3-thiazolidine (16), 4-hydroxy-2,5-dimethyl-3(2H)-furanone (15), and 2-acetyl-2- thiazoline (11) as the key aroma compounds among the 10 odorants detected. A similar set of aroma compounds was formed when isothiaproline was reacted (model B), but the flavor dilution factors were generally lower. Substitution of the buffer by silica gel/water (9 + 1 w/w) in both models and application of 150 °C for 10 min also gave the same key odorants from both thio compounds; however, under these conditions isothiaproline was the better precursor of, in particular, 19 and 11. Quantitative measurements performed by means of stable isotope dilution assays revealed a significant effect of the pH on odorant formation. For example, in model A, formation of 19 as well as of 11 was suppressed at pH values 5.0. A clear maximum was, however, found for 19 at pH 7.0 (~1 mol % yield), whereas 11 increased with increasing pH from 7.0 to 9.0.

Preparation of optically active 2-thiazolidinecarboxylic acid by asymmetric transformation

Shiraiwa, Tadashi,Katayama, Takashi,Ishikawa, Joji,Asai, Takeshi,Kurokawa, Hidemoto

, p. 1180 - 1183 (1999)

Cysteamine was condensed with glyoxylic acid monohydrate in a mixture of acetic acid and ethanol in the presence of (2R,3R)- or (2S,3S)-tartaric acid [(R)- or (S)-TA], as the resolving agent, to give the salt of (-)-2- thiazolidinecarboxylic acid [(-)-2-THC] with (R)-TA or the salt of (+)-2-THC with (S)-TA. Treatment of these salts with triethylamine in methanol afforded (-)- and (+)-2-THC. The (-)- and (+)- 2-THC obtained were determined to be enantiopure forms by comparing their powder X-ray diffraction patterns with that of (RS)-2-THC. The absolute configurations of (-)- and (+)-2-THC were estimated based on molar rotations of (2R,4R)- and (2S,4R)-2,4- thiazolidinedicarboxylic acids, (R)-4-thiazolidinecarboxylic acid, and (-)- and (+)-2-THC. ()-2THC was determined to have the (R)-configuration, and (+)- 2-THC to have the (S)-configuration.

Palladium-unleashed proteins: Gentle aldehyde decaging for site-selective protein modification

Brabham, Robin L.,Spears, Richard J.,Walton, Julia,Tyagi, Swati,Lemke, Edward A.,Fascione, Martin A.

supporting information, p. 1501 - 1504 (2018/02/19)

Protein bioconjugation frequently makes use of aldehydes as reactive handles, with methods for their installation being highly valued. Here a new, powerful strategy to unmask a reactive protein aldehyde is presented. A genetically encoded caged glyoxyl aldehyde, situated in solvent-accessible locations, can be rapidly decaged through treatment with just one equivalent of allylpalladium(ii) chloride dimer at physiological pH. The protein aldehyde can undergo subsequent oxime ligation for site-selective protein modification. Quick yet mild conditions, orthogonality and powerful exposed reactivity make this strategy of great potential in protein modification.

Anti-heparin peptides

-

, (2008/06/13)

The invention concerns a compound exhibiting an anti-heparin activity, of formula Z Bm ! (AXA)x Bn ! (AXA)y Bo (AXA)z Bp, the diagnostic reagents comprising it and the use of said compound in an in vitro diagnostic test of a medicine for anti-heparin activity.

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