16544-46-0Relevant articles and documents
Direct coupling of benzene with olefin catalyzed by Pd(OAc)2 combined with heteropolyoxometalate under dioxygen
Yokota, Takahiro,Tani, Masayuki,Sakaguchi, Satoshi,Ishii, Yasutaka
, p. 1476 - 1477 (2007/10/03)
The oxidative coupling reaction of benzenes with alkenes was successfully achieved by the Pd(OAc)2/molybdovanadophosphoric acid (HPMoV)/O2 system. For example, the reaction of benzene with ethyl acrylate by the above catalytic system in acetic acid afforded ethyl cinnamate as a major product in satisfactory yield. Copyright
Oligonucleotide analogs containing sulfur linkages
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, (2008/06/13)
Analogs of DNA containing sulfides, sulfoxides, and sulfones as linking groups between subunits capable of forming bonds with natural oligonucleotides are described. The analogs are lipophilic, stable to chemical degradation under a wide range of conditions and stable to enzymatic degradation in vivo.