18737-40-1

Basic information

• Product Name: 4-Bromotetraphenylsilane
• Synonyms: 4-Bromotetraphenylsilane;Benzene, 1-broMo-4-(triphenylsilyl)- Silane, (4-broMophenyl)triphenyl- (9CI);(4-Bromophenyl)triphenylsilane;Benzene, 1-bromo-4-(triphenylsilyl)-
• CAS NO: 18737-40-1
• Molecular Formula: C₂₄H₁₉BrSi
• Molecular Weight: 415.4
• Product Categories: Si (Classes of Silicon Compounds);Si-(C)4 Compounds;Silanes
• Mol File: 18737-40-1.mol
• Article Data: 30

Chemical Properties

• Melting Point: 175 °C
• Boiling Point: 462.9 °C at 760 mmHg
• Flash Point: 359.1 °C
• Appearance: /
• Density: 1.3 g/cm³
• Vapor Pressure: 2.63E-08mmHg at 25°C
• Refractive Index: 1.659
• Storage Temp.: Inert atmosphere,Room Temperature
• CAS DataBase Reference: 4-Bromotetraphenylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Bromotetraphenylsilane(18737-40-1)
• EPA Substance Registry System: 4-Bromotetraphenylsilane(18737-40-1)

Safety Data

• Hazard Codes: Xn
• Statements: 22
• WGK Germany: 3
• Hazardous Substances Data: 18737-40-1(Hazardous Substances Data)

Usage

Description

4-Bromotetraphenylsilane is an organosilicon compound with the molecular formula C24H19BrSi. It is characterized by a strong aromatic odor and typically appears as a light yellow liquid. This chemical is water reactive, leading to moisture loss and compacted reactions due to its impure nature. It is also incompatible with strong bases and oxidizing agents, necessitating careful handling and operation. Despite its toxicity, 4-Bromotetraphenylsilane is widely used in various industrial applications, including as a chemical reagent and in the synthesis of new chemical products.

Uses

Used in Chemical Synthesis:
4-Bromotetraphenylsilane is used as a chemical reagent for the synthesis of new chemical products. Its unique properties make it a valuable component in the creation of various compounds, contributing to the development of novel materials and substances.
Used in Industrial Applications:
In the industrial sector, 4-Bromotetraphenylsilane is employed as a key component in the production of various products. Its versatility and reactivity with other chemicals allow for its use in a wide range of applications, from the creation of new materials to the improvement of existing ones.
Safety Measures:
Due to its toxicity, it is crucial to follow safety measures when handling and operating with 4-Bromotetraphenylsilane. This includes the use of appropriate personal protective equipment, such as gloves and goggles, as well as ensuring proper ventilation in the work area to minimize exposure to its strong aromatic odor and potential hazards. Additionally, it is essential to store the compound away from strong bases and oxidizing agents to prevent unwanted reactions and maintain its stability.

InChI:InChI=1/C24H19BrSi/c25-20-16-18-24(19-17-20)26(21-10-4-1-5-11-21,22-12-6-2-7-13-22)23-14-8-3-9-15-23/h1-19H

Upstream product

• 76-86-8 Triphenylsilyl chloride 
• 22480-64-4 4-bromophenyllithium 
• 589-87-7 1,4-bromoiodobenzene 
• 14311-00-3 (4-methoxyphenyl)triphenylsilane 
• 18840-19-2 (4-(N,N-dimethylaminophenyl))triphenylsilane 
• 591-51-5 phenyllithium 
• 106-37-6 1.4-dibromobenzene 
• 18164-08-4 (4-bromophenyl)trichlorosilane 

Downstream Products

• 18840-20-5 N,N-dimethyl-3-triphenylsilanyl-aniline; hydrochloride 
• 1032070-20-4 1-(4-triphenylsilanylphenyl)ethanone 

Relevant articles and documents

Silicon-containing dendritic tris-cyclometalated Ir(iii) complex and its electrophosphorescence in a polymer host

In this paper, we present the synthesis and characterization of a new highly phosphorescent cyclometalated Ir(iii) complex with a silane-based dendritic substituent. The Ir(iii) complex showed 74 ± 3% of absolute phosphorescence quantum efficiency in the film state. In addition, efficient electrophosphorescence (32.8 cd A-1) employing an Ir(iii) complex-poly(N-vinylcarbazole) system device is observed. Study of a series of electroluminescent, spectroscopic, and electrochemical data of the Ir(iii) complex and the reference Ir(ppy)3 reveals superior performance of the new Ir(iii) complex. The Royal Society of Chemistry.

Highly thermally-stable 4,4′-bis(4″-triphenylsilylphenyl)-1,1′- binaphthalene as the ultraviolet amplified spontaneous emitter, efficient host and deep-blue emitting material

We report herein the synthesis and characterization of an efficient versatile binaphthyl derivative, 4,4′-bis(4″-triphenylsilylphenyl)-1,1′-binaphthalene (SiBN) with a high glass transition temperature of 159.3 °C. Its role as a lasing dye was demonstrated by the amplified spontaneous emission, which exhibited an ultraviolet peak of 397 nm with a low threshold of 20 μJ/pulse. Meanwhile, the lasing film and blue electroluminescent device employing this novel binaphthyl derivative as the host showed superior performances to the reference based on the conventional host 4,4′-bis(carbazol-9-yl)biphenyl. Finally, extremely stable colour-tunable deep-blue (436 nm/472 nm) organic electroluminescent devices based on SiBN were demonstrated with very high brightness (>7521.2 cd/m2) and high external quantum efficiencies (1.90% for 436 nm and 4.66% for 472 nm emission). The development of such functional versatility materials will be an effective method for reducing the cost of organic photoelectric devices.

Silicon-containing substituted metal complex

The invention discloses a silicon-containing substituted metal complex. The novel silicon-containing substituted metal complex has a general formula of M (La) m (Lb) n (Lc) q, and the ligand La is a ligand with silicon group substitution and can be used as a luminescent material in an electroluminescent device. The novel metal complexes have the advantages of remarkably improving the quantum efficiency of the material, effectively controlling the light-emitting wavelength and the light-emitting color and reducing the driving voltage, and can provide better device performance. The invention also discloses an electroluminescent device and a compound formulation.

An organoelectro luminescent compounds and organoelectro luminescent device using the same

The present invention relates to an organic light emitting compound represented by Formula I or Formula III, and an organic electroluminescent device including the same. The organic light-emitting compound according to the present invention has excellent brightness and luminous efficiency, and can be driven at a low voltage and has improved power efficiency. A compound of the formula I: No.No. STRIII No.No. wherein X represents a hydrogen atom or a methyl group. (by machine translation)