20063-92-7Relevant articles and documents
SELECTIVITY IN ALLYLIC SUBSTITUTIONS WITH ORGANOMETALLICS THROUGH NEIGHBOURING COORDINATION. SYNTHESIS AND REACTIONS OF COPPER(I) ?-COMPLEXES WITH 2-ALLYLLOXYBENZOTHIAZOLES
Calo, Vincenzo,Lopez, Luigi,Pesce, Giannangelo
, p. 179 - 184 (1982)
2-Allylloxybenzothiazoles react with CuBr to give stable CuI ?-complexes.These complexes undergo nucleophilic attack by organomagnesium compounds to give olefins with very high regio- and stereo-specificity.
Highly enantioselective Cu-catalysed allylic substitutions with Grignard reagents
Lopez, Fernando,Van Zijl, Anthoni W.,Minnaard, Adriaan J.,Feringa, Ben L.
, p. 409 - 411 (2008/02/05)
A catalyst system able to perform highly enantioselective Cu-catalysed allylic alkylations with Grignard reagents is described. The Royal Society of Chemistry 2006.
Zirconium porphyrins as novel active catalysts for highly regio- And stereoselective ethylalumination of alkynes
Shibata, Kenji,Aida, Takuzo,Inoue, Shohei
, p. 1077 - 1080 (2007/10/02)
Zirconium(IV) complexes of 5, 10, 15, 20-tetraphenylporphyrin ((TPP)ZrX2) catalyze highly regioand stereo-selective ethylalumination of terminal alkynes with satisfactorily high turnover numbers.