20069-66-3

Basic information

• Product Name: ALPHA-NAPHTHYL ACRYLATE
• Synonyms: ALPHA-NAPHTHYL ACRYLATE;2-Propenoicacid,1-naphthalenylester;1-Naphthyl acrylate;1-Naphthyl propenoate;Acrylic acid 1-naphthyl ester
• CAS NO: 20069-66-3
• Molecular Formula: C₁₃H₁₀O₂
• Molecular Weight: 198.22
• Product Categories: monomer
• Mol File: 20069-66-3.mol

Chemical Properties

• Flash Point: >110°C
• Appearance: /
• Density: 1.147
• CAS DataBase Reference: ALPHA-NAPHTHYL ACRYLATE(CAS DataBase Reference)
• NIST Chemistry Reference: ALPHA-NAPHTHYL ACRYLATE(20069-66-3)
• EPA Substance Registry System: ALPHA-NAPHTHYL ACRYLATE(20069-66-3)

Safety Data

• Statements: 36
• Safety Statements: 26
• Hazardous Substances Data: 20069-66-3(Hazardous Substances Data)

Usage

Uses

Used in Polymer Production:
ALPHA-NAPHTHYL ACRYLATE is used as a monomer for its ability to polymerize easily, contributing to the creation of various polymers that serve different purposes in the chemical industry.
Used in Coatings Industry:
ALPHA-NAPHTHYL ACRYLATE is used as a key ingredient in the formulation of UV-curable coatings, valued for its capacity to rapidly cure under ultraviolet light, thus enhancing the efficiency of coating processes.
Used in Adhesives Industry:
In the adhesives industry, ALPHA-NAPHTHYL ACRYLATE is used as a component in the development of high-performance adhesives, leveraging its reactive nature to create strong bonds in various applications.
Used in Inks Industry:
ALPHA-NAPHTHYL ACRYLATE is utilized as a constituent in ink formulations, particularly for UV-curable inks, due to its quick curing properties which are beneficial in printing processes.

Upstream product

• 90-15-3 α-naphthol 
• 79-10-7 acrylic acid 
• 814-68-6 acryloyl chloride 
• 1033462-77-9 tert-butyl acryloyl carbonate 

Downstream Products

• 17324-17-3 trans-3-methyl-1,4-diphenylazetidin-2-one 

Relevant articles and documents

Clay anti-swelling agent for acidifying acid in high-temperature oil field

The invention relates to the technical field of oilfield development, in particular to a clay anti-swelling agent for high temperature oilfield acidification. The clay anti-swelling agent is preparedby: reacting 1-naphthol with acrylic acid to generate na

CARBOXYLIC ACID ESTER PRODUCTION METHOD

Provided is a production method whereby corresponding carboxylic acid esters can be obtained from a variety of carboxylic acids at a high yield, even under conditions using a simple reaction operation and little catalyst and even if the amount of substrate used is theoretical. A production method for carboxylic acid ester, whereby a prescribed diester dicarbonate, carboxylic acid, and alcohol are reacted in the presence of at least one type of magnesium compound and at least one type of alkali metal compound.

METHOD FOR PRODUCING (METH) ACRYLATE

PROBLEM TO BE SOLVED: To provide a production method for obtaining (meth) acrylate in high yields, by preventing a large amount of waste from produced from by-products, like the conventional art. SOLUTION: A method for producing (meth) acrylate includes the reaction between a compound represented by the following formula (I) and an aryl alcohol. Preferably, the reaction occurs in the presence of a catalyst of at least one metal compound selected from first Group metal compounds and second Group metal compounds. SELECTED DRAWING: None COPYRIGHT: (C)2019,JPOandINPIT

METHOD FOR PRODUCING CARBOXYLIC ACID ANHYDRIDE AND METHOD FOR PRODUCING CARBOXYLIC ACID ESTER

Provided is a production method whereby corresponding carboxylic acid anhydrides and carboxylic acid esters can be obtained at high yield from various carboxylic acids even without a solvent and near room temperature. A method for producing a carboxylic acid anhydride represented by formula (II), the method comprising reacting a compound represented by formula (I) and a carboxylic acid in the presence of a Group II metal compound having an ionic ligand containing an oxygen atom. A method for producing a carboxylic acid ester, the method comprising reacting a carboxylic acid anhydride produced by the aforementioned method and an alcohol. In formula (I), R1 represents a C1-20 hydrocarbon group. In formula (II), R2 represents a C1-20 hydrocarbon group.

(Meth) acrylic acid ester naphthylacetic

PROBLEM TO BE SOLVED: To provide a method for producing less discolored (meth)acrylic naphthyl ester at a high yield by reacting (meth)acrylic anhydride with naphthol, and to provide a method for producing (meth)acrylic naphthyl ester achieving high polymerization rate. SOLUTION: There is provided a method for producing (meth)acrylic naphthyl ester by reacting naphthol and (meth)acrylic anhydride, wherein, the production method of (meth)acrylic naphthyl ester is characterized in making a carbonate salt present in the reaction system of the naphthol and the (meth)acrylic anhydride. COPYRIGHT: (C)2010,JPOandINPIT

1,4-Diazabicyclo[2.2.2]octane-Promoted Aminotrifluoromethylthiolation of α,β-Unsaturated Carbonyl Compounds: N-Trifluoromethylthio-4-nitrophthalimide Acts as Both the Nitrogen and SCF3 Sources

A novel difunctionalization reaction is described. It uses N-trifluoromethylthio-4-nitrophthalimide as the reagent, which serves as both the nitrogen and SCF3 sources. In the presence of DABCO (1,4-diazabicyclo[2.2.2]octane), the nitrogen and SCF3 groups can be incorporated into α,β-unsaturated carbonyl compounds easily and give versatile β-amino ketones and esters in good yields. This difunctionalization reaction features mild reaction conditions, high atom-economy, and efficient access to α-SCF3 amino acids.

A bifunctional β-isocupreidine derivative as catalyst for the enantioselective morita-baylis-hillman reaction and a mechanistic rationale for enantioselectivity

Starting from β-isocupreidine (β-ICD), a series of difunctional catalysts were synthesized to ascertain their usefulness in the asymmetric Morita-Baylis-Hillman (MBH) reaction. The trichloroacetylcarbamate derivative was found to give the (R)-MBH adducts in excellent optical purities (90-99% ee) and moderate to good yields (43-83%), in some cases, better than β-ICD. A number of acrylates were also tested and 2,6-dimethyl-4-nitrophenyl acrylate was identified as a suitable alternative to the popular hexafluoroisopropyl acrylate, with both the β-ICD and trichloroacetylcarbamate derivatives. The mechanism of the rate- and selectivity-determining step was ascertained by means of experimental observations and a computational investigation aimed at clarifying the transition state structures is reported. These studies have clarified the reasons for the effectiveness of these structurally related catalysts in the asymmetric MBH reaction between acrylates and aldehydes. β-Isocupreidine derivatives were used tocatalyze the asymmetric Morita-Baylis-Hillman (MBH) reaction, giving the (R)-MBH adducts in excellent optical purities and moderate to good yields. Both 2,6-dimethyl-4-nitrophenyl and hexafluoroisopropyl acrylate could be used. The rate- and selectivity-determining step was identified and the structures of the preferred transition states were computed.

Enantioselective organocatalytic Michael additions to acrylic acid derivatives: Generation of all-carbon quaternary stereocentres

Acrylic esters, thioesters and N-acryloyl pyrrole have been identified as effective electrophiles in the enantioselective Michael addition reaction with β-keto ester pro-nucleophiles catalysed by a cinchona alkaloid derived bifunctional organocatalyst; enantiomeric excesses of up to 98% and yields of up to 96% can be obtained for a range of Michael acceptors and pro-nucleophiles. The Royal Society of Chemistry.