20120-26-7

Basic information

• Product Name: methyl alpha-methyl-4-morpholinepropionate
• Synonyms: methyl alpha-methyl-4-morpholinepropionate;2-Methyl-3-morpholinopropanoic acid methyl ester;2-Methyl-3-morpholinopropionic acid methyl ester;3-Morpholino-2-methylpropanoic acid methyl ester;α-Methyl-4-morpholinepropanoic acid methyl ester;Einecs 243-527-3;Methyl 2-Methyl-3-Morpholinopropanoate
• CAS NO: 20120-26-7
• Molecular Formula: C₉H₁₇NO₃
• Molecular Weight: 187.23618
• EINECS: 243-527-3
• Mol File: 20120-26-7.mol
• Article Data: 13

Chemical Properties

• Boiling Point: 261.8°Cat760mmHg
• Flash Point: 112.1°C
• Appearance: /
• Density: 1.043g/cm³
• Vapor Pressure: 0.0113mmHg at 25°C
• Refractive Index: 1.453
• CAS DataBase Reference: methyl alpha-methyl-4-morpholinepropionate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl alpha-methyl-4-morpholinepropionate(20120-26-7)
• EPA Substance Registry System: methyl alpha-methyl-4-morpholinepropionate(20120-26-7)

Safety Data

• Hazardous Substances Data: 20120-26-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H17NO3/c1-8(9(11)12-2)7-10-3-5-13-6-4-10/h8H,3-7H2,1-2H3

Upstream product

• 110-91-8 morpholine 
• 814-78-8 3-Methyl-3-buten-2-one 
• 67-56-1 methanol 
• 80-62-6 methacrylic acid methyl ester 

Downstream Products

• 55716-11-5 perfluoro(N-ethylmorpholine) 
• 358-21-4 perfluorodiethyl ether 
• 382-28-5 2,2,3,3,5,5,6,6-Octafluoro-4-trifluoromethyl-morpholine 
• 122531-27-5 2-[difluoro-(2,2,3,3, 5,5,6,6-octafluoromorpholin-4-yl)methyl]-2,3,3,3-tetrafluoro-propanoyl fluoride 
• 1600-71-1 perfluoro(N-iso-propylmorpholine) 
• 1704-69-4 perfluoro(N-n-propylmorpholine) 

Relevant articles and documents

Bromodimethylsulfonium bromide mediated Michael addition of amines to electron deficient alkenes

Bromodimethylsulfonium bromide has been found to be an efficient catalyst for the Michael addition of a wide variety of amines to electron deficient alkenes at room temperature. The protocol is very simple and chemoselective. Aliphatic and benzylic amines undergo conjugate addition within a very short period under solvent-free conditions and provide excellent yields of products.

SEGREGATED FLUORINATED ESTERS

Segregated fluorinated esters are described that are useful as dielectric fluids in electrical devices and as heat transfer agents.

Guanidine-based task-specific ionic liquids as catalysts for aza-Michael addition under solvent-free conditions

An efficient and facile protocol for aza-Michael addition of aliphatic and aromatic amines to electron-deficit alkenes using [TMG][Lac] as catalyst under solvent-free conditions was established.