2351-43-1

Basic information

• Product Name: DIETHYLENE GLYCOL MONO-METHACRYLATE
• Synonyms: DIETHYLENE GLYCOL MONO-METHACRYLATE;2-Propenoic acid, 2-methyl-, 2-(2-hydroxyethoxy)ethyl ester
• CAS NO: 2351-43-1
• Molecular Formula: C₈H₁₄O₄
• Molecular Weight: 174.19
• Product Categories: monomer
• Mol File: 2351-43-1.mol

Chemical Properties

• Boiling Point: 270.5oC at 760 mmHg
• Flash Point: 103.3oC
• Appearance: /
• Density: 1.069g/cm3
• Vapor Pressure: 0.0009mmHg at 25°C
• Refractive Index: 1.449
• Storage Temp.: Sealed in dry,Room Temperature
• PKA: 14.32±0.10(Predicted)
• CAS DataBase Reference: DIETHYLENE GLYCOL MONO-METHACRYLATE(CAS DataBase Reference)
• NIST Chemistry Reference: DIETHYLENE GLYCOL MONO-METHACRYLATE(2351-43-1)
• EPA Substance Registry System: DIETHYLENE GLYCOL MONO-METHACRYLATE(2351-43-1)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36
• Hazardous Substances Data: 2351-43-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C8H14O4/c1-7(2)8(10)12-6-5-11-4-3-9/h9H,1,3-6H2,2H3

Upstream product

• 80-62-6 methacrylic acid methyl ester 
• 111-46-6 diethylene glycol 
• 107-21-1 ethylene glycol 
• 920-46-7 Methacryloyl chloride 
• 92-84-2 10H-phenothiazine 
• 79-41-4 poly(methacrylic acid) 
• 75-21-8 oxirane 

Downstream Products

• 42040-46-0 2-Methyl-acrylic acid 2-(2-benzenesulfonyloxy-ethoxy)-ethyl ester 
• 42040-48-2 2-Methyl-acrylic acid 2-[2-(toluene-4-sulfonyloxy)-ethoxy]-ethyl ester 

Relevant articles and documents

Phosphate cross-linking agent and preparation method thereof, phosphate-based cross-linked gel polymer electrolyte and preparation method and application thereof

According to the invention, the safety of the battery can be improved based on introduction of phosphate into the gel polymer electrolyte, , the adjustable flexibility is improved by introduction of aPEO chain segment, and the stability and the polymerization capability are improved by introduction of acrylate; thus, further research is carried out on the basis of the prior art, the polyfunctional phosphate cross-linking agent is obtained and is applied to the preparation of the phosphate-based cross-linked gel polymer electrolyte, so the cross linking agent can be copolymerized with other functional monomers to synthesize gel polymer electrolyte; the gel polymer electrolyte has the advantages of simple and convenient preparation method, high ionic conductivity, high thermal stability andgood electrochemical stability, the assembled sodium ion battery has good cycling stability and high-temperature performance, and the phosphate-based gel polymer electrolyte with high safety is provided for quasi-solid sodium/lithium ion batteries.

Efficient synthesis of polymer prodrug by thiol-acrylate michael addition reaction and fabrication of Ph-responsive prodrug nanoparticles

In this study, an efficient method is proposed for the synthesis of polymer prodrug with acid-liable linkage via thiol-acrylate Michael addition reaction of the camptothecin with tethering acrylate group and polymer scaffold containing multiple thiol grou

A new high-capacity metal ion-complexing gel containing cyclen ligands

We describe a new polymeric hydrogel that binds divalent metal ions with large binding constants and capacity. A new acrylate monomer with the pendant cyclen, tri-tert-butyl-10-(2-(2-(2-(methacryloyloxy)ethoxy)ethoxy)-2-oxoethyl)-1,4,7,10-tetraazacyclododecane-1,4,7-tricarboxylate, was polymerised by RAFT to a roughly spherical 5-9 unit oligomer bearing a carboxylate-functionalised end-group. This was de-protected and coupled to an amine dendrimer then crosslinked into a nylon-type hydrogel capable of absorbing more than 10 wt% copper ions.

METHOD FOR PRODUCING IRON CARBONATE

The purpose of the present invention is to provide a method for producing an iron carbonate, whereby it becomes possible to prevent the generation of hydrogen during the production of the iron carbonate by the reaction of a carboxylic acid with metal iron. An embodiment of the present invention is a method for producing an iron carbonate by reacting metal iron with a carboxylic acid in a reaction solution, wherein a compound of trivalent iron is added to the reaction solution, the reaction solution contains a compound of trivalent iron at the time of the start of the reaction, the reaction solution contains a non-iron metal having a standard electrode potential of -2.5 to 0.1 inclusive or a metal compound containing the metal, or the reaction solution contains at least one metal selected from the group consisting of Ag, Bi and Pd or a metal compound containing the metal.

Unique associative properties of copolymers of sodium acrylate and oligo(ethylene oxide) alkyl ether methacrylates in water

A series of random copolymers of sodium acrylate and oligo(ethylene oxide) alkyl ether methacrylates (CnEmMA) with different lengths of ethylene oxide (EO) and alkyl groups were prepared by free-radical copolymerization at varying copolymer compositions. The lengths of the EO units (the number of EO units) (m) and the numbers of carbon atoms in the alkyl groups (n) ranged fro'm 0 to 8.7 and 1 to 6, respectively. The copolymers with n = 1 and m = 1-8.7 exhibited a marked increase in solution viscosity at polymer concentrations (Cp) higher than their overlap concentrations (C*) when the CnEmMA contents (x) in the copolymers were in a certain limited range. Namely, there was an optimum x value that yielded the highest viscosity as a consequence of the competition between inter- and intrapolymer associations; the maximum viscosities occurred around x ≈ 25, 15, 10, 7, and 3 mol % for m = 1, 2, 3, 4.2, and 8.7, respectively. The maximum viscosity decreased significantly as n was increased on going from 1 to 6, and for the copolymers with n = 6, no increase in the viscosity occurred, a trend opposite to what is expected to interpolymer hydrophobic associations. When Cp > C*, steady-shear viscosity depended on the nature of countercations; the viscosities were found to be higher in the order Li + > Na+ ? NH4+, whereas reduced viscosity in dilute regime (Cp C*) was independent of the species of the cations. Rheological properties were found to be typical of transient networks formed through very weak interpolymer associations. Thus, the large increase in solution viscosity was explained by simultaneous interactions of countercations with EO units via coordination and with the polyanion via counterion condensation.

Production process for hydroxyalkyl (meth) acrylate

There is disclosed a novel production process for a hydroxyalkyl (meth)acrylate in which: the diffusion of harmful substances due to disposal of catalysts can be reduced; and also the amount of the catalyst as used can be greatly saved in the entire production process. This production process comprises the step of carrying out a reaction between (meth)acrylic acid and an alkylene oxide in the presence of a catalyst in order to produce the hydroxyalkyl (meth)acrylate; with the production process being characterized by further comprising the step of recovering the catalyst as has been used for the reaction.

Process for the preparation of hydroxyalkyl(meth)acrylate

The present invention provides: a high-quality hydroxyalkyl (meth)acrylate of which the alkylene glycol di(meth)acrylate content and the acid component content are both low; and its novel production process. The hydroxyalkyl (meth)acrylate, which has a content, in terms of an alkylene glycol di(meth)acrylate as an impurity, of not more than 0.1 weight % and an acid component content of not more than 0.1 weight %, is obtained by a process comprising the step of carrying out a batch reaction between (meth)acrylic acid and an alkylene oxide in the presence of a catalyst in order to produce the hydroxyalkyl (meth)acrylate; with the process making an adjustment as to charging of both raw materials in such a manner that, for, of a time as needed for supplying both raw materials, a supplying time of not less than 40 % of a total supplying time when the raw materials as supplied have a temperature of not lower than 40 °C, the molar ratio of the integrated amount of the alkylene oxide to the integrated amount of the (meth)acrylic acid that have been added to a reactor by then can be more than 1.0.

Chromene compound

A photochromic compound featuring a large fading rate to prevent a change in the color tone at the time of fading, exhibiting little color after aged, and exhibiting good durability in the photochromic property. The photochromic compound is a novel chromene compound having a substituted phenyl group at the second position of the naphthopyrane ring and an alkyl group at the fifth position thereof, and is represented by, for example, the following formula, wherein R1 is an alkyl group, R2 and R3 are substituted phenyl groups, and R4 and R5 are substituents.

Reaction kinetics of acyl chlorides with glycols

The reaction rates of crotonyl and methacryloyl chlorides with mono-, di-, and triethylene glycols obey the second order equations. No isokinetic relation was observed.

Adhesive composition

An adhesive composition comprises 100 parts by weight of a polymerizable monomer comprising (a) 1.5 to 100 parts by weight of a compound represented by general formula I or II: STR1 where R1 and R1 ' each stand for hydrogen or a methyl group, R2 stands for a divalent organic residue having 4 to 40 carbon atoms, X1 and X2 each stand for --O--, --S-- or --NH--, a is 0 or 1, and R3 stands for a group of the formula STR2 having 6 to 40 carbon atoms, where R4 and R4 ' each stand for a hydrocarbon group having 1 to 29 carbon atoms, and optionally replaced by a halogen atom, or a hydroxyl, amino or carboxyl group, b is an integer of 0 to 3, and Z stands for --O--, --COO-- or --NH--, a plurality of R4 ' (when b is 2 or 3) being the same or different, at least one of R4 and R4 ' having at least three carbon atoms, and (b) 0 to 98.5 parts by weight of a vinyl monomer copolymerizable with the above compound; and 0.01 to 20 parts by weight of a curing agent. It shows a superior adhesive strength on any of hard tissues in a living body, such as teeth and bones, metals, organic polymers and ceramics. It maintains a high adhesive strength for a long time even if it is exposed to moisture, or immersed in water. It is particularly effective for use in dentistry, though it is useful for a variety of other purposes, too.