2549-51-1Relevant articles and documents
Sandler
, p. 503 (1969)
Version: 1.0
Creation Date: Aug 11, 2017
Revision Date: Aug 11, 2017
Product name | Vinyl chloroacetate |
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Product number | - |
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Other names | chloroacetoxy-ethene |
Identified uses | For industry use only. |
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Uses advised against | no data available |
Emergency phone number | - |
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Service hours | Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). |
More Details:2549-51-1 SDS
Conditions | Yield |
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With mercury(II) diacetate; boric acid at 10 - 20℃; | |
With hydroquinone; mercury(II) oxide at 60℃; dann bei 40-50grad; | |
With mercury(II) oxide |
Conditions | Yield |
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for 1h; Ambient temperature; |
chloroacetyl chloride
2-chloromercurio-acetaldehyde
vinyl chloroacetate
Conditions | Yield |
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With benzene |
Conditions | Yield |
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With Cp*2Sm(THF)2 In toluene Ambient temperature; further reagent: SmI2; | 99% |
With 1,3-dichlorotetrabutyldistannoxane at 50℃; for 17h; | 96% |
With 1,3-dichlorotetrabutyldistannoxane at 50℃; for 17h; | 96% |
vinyl chloroacetate
1-phenyl-2-cyclohex-2-en-1-ol
Conditions | Yield |
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With Candida antartica lipase B (CAL-B) immobilized on a support (commercial name: Chirazyme L-2 C4); V-MPS4 In acetonitrile at 35℃; for 24h; Inert atmosphere; | 99% |
Conditions | Yield |
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With Candida antarctica lipase B In 2,2,4-trimethylpentane; acetone at 55℃; for 1h; Enzymatic reaction; regioselective reaction; | 99% |
vinyl chloroacetate
thexyldimethylsilyl 6-O-acetyl-β-D-galactopyranosyl-(1->3)-6-O-acetyl-2-azido-2-deoxy-β-D-glucopyranoside
Conditions | Yield |
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With Candida antarctica lipase In acetonitrile at 40℃; for 12h; Acylation; | 91% |
vinyl chloroacetate
thexyldimethylsilyl 6-O-acetyl-β-D-galactopyranosyl-(1->3)-2-azido-2-deoxy-β-D-glucopyranoside
Conditions | Yield |
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With Candida antarctica lipase In acetonitrile at 28℃; for 4h; Acylation; | 90% |
vinyl chloroacetate
(3S,5S)-1-ethynyl-3,5-dihydroxy-2-methylcyclohex-1-ene
Conditions | Yield |
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In tetrahydrofuran for 23h; Ambient temperature; Chromobacterium viscosum lipase; | A 86% B 7 % Spectr. |
vinyl chloroacetate
(3R,5R)-1-ethynyl-3,5-dihydroxy-2-methylcyclohex-1-ene
Conditions | Yield |
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In tetrahydrofuran for 92h; Ambient temperature; Chromobacterium viscosum lipase; | A 6.5% B 2.5% C 85% |
2-Hydroxy-1,4-naphthoquinone
vinyl chloroacetate
tert-butylisonitrile
Conditions | Yield |
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With 1,4-diaza-bicyclo[2.2.2]octane In isopropyl alcohol at 120℃; for 0.166667h; Microwave irradiation; | 85% |
vinyl chloroacetate
vinyl iodoacetate
Conditions | Yield |
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With sodium iodide In acetone at 20℃; for 1h; | 85% |
6-Monoacetylated D-glucal
vinyl chloroacetate
6-O-acetyl-3-O-chloroacetyl-glucal
Conditions | Yield |
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With lipase from Pseudomonas fluorescens In 1,2-dimethoxyethane for 3h; Ambient temperature; | 83% |
vinyl chloroacetate
tert-butylisonitrile
4-hydroxy-2H-pyran-2-one
Conditions | Yield |
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With 1,4-diaza-bicyclo[2.2.2]octane In isopropyl alcohol at 120℃; for 0.166667h; Microwave irradiation; | 83% |
vinyl chloroacetate
6-O-Benzoyl-D-glucal
6-O-benzoyl-3-O-chloroacetyl-glucal
Conditions | Yield |
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With lipase from Pseudomonas fluorescens In 1,2-dimethoxyethane for 2h; Ambient temperature; | 82% |
Lipase P
6-Monoacetylated D-glucal
vinyl chloroacetate
6-O-acetyl-3-O-chloroacetyl-glucal
Conditions | Yield |
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In 1,2-dimethoxyethane | 80% |
Lipase P
vinyl chloroacetate
1-O-acetyl-2,6-anhydro-5-deoxy-D-arabino-hex-5-enitol
6-O-acetyl-3-O-chloroacetyl-galactal
Conditions | Yield |
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In 1,2-dimethoxyethane | 80% |
benzyl 4-O-β-D-galactopyranosyl-β-D-glucopyranoside
vinyl chloroacetate
benzyl (6-O-chloroacetyl-β-D-galactopyranosyl)-(1->4)-β-D-glucopyranoside
Conditions | Yield |
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With lipase from Candida antarctica In tetrahydrofuran at 20℃; for 48h; Acylation; Enzymatic reaction; | 78% |
With immobilized Candida antarctica lipase In tetrahydrofuran at 40℃; for 48h; | 78% |
Conditions | Yield |
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With tert-butyl methyl ether; 4 A molecular sieve; Novo Lipozyme IM-20 for 160h; Ambient temperature; | 74.7% |
vinyl chloroacetate
(3R,5S)-1-ethynyl-3,5-dihydroxy-2-methylcyclohex-1-ene
Conditions | Yield |
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In tetrahydrofuran for 21h; Ambient temperature; Chromobacterium viscosum lipase; Yields of byproduct given; | A 71% B n/a |
In tetrahydrofuran for 21h; Ambient temperature; Chromobacterium viscosum lipase; Yield given; | A 71% B n/a |
vinyl chloroacetate
(3S,5R)-1-ethynyl-3,5-dihydroxy-2-methylcyclohex-1-ene
Conditions | Yield |
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In tetrahydrofuran at 45℃; for 45h; Chromobacterium viscosum lipase; Yields of byproduct given; | A 70% B n/a |
In tetrahydrofuran at 45℃; for 45h; Chromobacterium viscosum lipase; Yield given; | A 70% B n/a |
vinyl chloroacetate
thexyldimethylsilyl 6-O-acetyl-β-D-galactopyranosyl-(1->3)-2-azido-2-deoxy-β-D-glucopyranoside
Conditions | Yield |
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With Candida antarctica lipase In acetonitrile at 35℃; for 1h; Acylation; | A 67% B 29% |
Conditions | Yield |
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In diethyl ether at 20℃; for 22.5h; Schlenk technique; | 63% |
In benzene |
vinyl chloroacetate
benzyl (6-O-acetyl-β-D-galactopyranosyl)-(1->4)-β-D-glucopyranoside
Conditions | Yield |
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With immobilized Candida antarctica lipase In acetonitrile at 45℃; for 120h; | 62% |
vinyl chloroacetate
2-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-cyclopent-3-enol
A
(1S,2R)-2-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-cyclopent-3-enol
Conditions | Yield |
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With Lipase PS In di-isopropyl ether at 30℃; for 1h; | A 50% B 46% |
vinyl chloroacetate
Conditions | Yield |
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With Porcine pancreas lipase type II In 1,4-dioxane at 20℃; for 24h; Enzymatic reaction; | 50% |
vinyl chloroacetate
(4-hydroxy-3,4-dihydroquinolin-1(2H)-yl)(phenyl)methanone
Conditions | Yield |
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With Novozyme 435 lipase In tert-butyl methyl ether at 30℃; for 8h; Enzymatic reaction; enantioselective reaction; | A 49% B 34% |
vinyl chloroacetate
Conditions | Yield |
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With Novozyme 435 lipase In tert-butyl methyl ether at 30℃; for 8h; Enzymatic reaction; enantioselective reaction; | A 42% B 48% |
vinyl chloroacetate
Conditions | Yield |
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With Novozyme 435 lipase In tert-butyl methyl ether at 30℃; for 8h; Enzymatic reaction; enantioselective reaction; | A 47% B 29% |
vinyl chloroacetate
phenyl 4-hydroxy-3,4-dihydroquinoline-1(2H)-carboxylate
Conditions | Yield |
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With Novozyme 435 lipase In tert-butyl methyl ether at 30℃; for 8h; Enzymatic reaction; enantioselective reaction; | A 43% B 46% |