255-55-0Relevant articles and documents
Mizuno et al.
, p. 1484 (1976)
Selective Metalations of 1,4-Dithiins and Condensed Analogues Using TMP-Magnesium and -Zinc Bases
Castelló-Micó, Alicia,Nafe, Julia,Higashida, Kosuke,Karaghiosoff, Konstantin,Gingras, Marc,Knochel, Paul
, p. 360 - 363 (2017)
TMPMgCl·LiCl and TMPZnCl·LiCl allow facile magnesiation and zincation, respectively, of the 1,4-dithiin scaffold, producing polyfunctionalized 1,4-dithiins. A subsequent metalation of these S-heterocycles can also be achieved with the same TMP bases, lead
An expedient, cost effective large scale synthesis of tetrathiafulvalene
Meline, Ronald L.,Elsenbaumer, Ronald L.
, p. 2467 - 2469 (2007/10/03)
TTF is synthesized (85% yield) in two steps from 4,5-bis(benzoylthio)-1,3-dithiole-2-thione and isolated in high purity without the use of chromatography.