279-23-2Relevant articles and documents
Traynham
, p. 833,834 (1960)
Norbornane: An investigation into its valence electronic structure using electron momentum spectroscopy, and density functional and Green's function theories
Knippenberg,Nixon,Brunger,Maddern,Campbell,Trout,Wang,Newell,Deleuze,Francois,Winkler
, p. 10525 - 10541 (2004)
We report on the results of an exhaustive study of the valence electronic structure of norbornane (C7H12), up to binding energies of 29 eV. Experimental electron momentum spectroscopy and theoretical Green's function and density functional theory approaches were all utilized in this investigation. A stringent comparison between the electron momentum spectroscopy and theoretical orbital momentum distributions found that, among all the tested models, the combination of the Becke-Perdew functional and a polarized valence basis set of triple-ζ quality provides the best representation of the electron momentum distributions for all of the 20 valence orbitals of norbornane. This experimentally validated quantum chemistry model was then used to extract some chemically important properties of norbornane. When these calculated properties are compared to corresponding results from other independent measurements, generally good agreement is found. Green's function calculations with the aid of the third-order algebraic diagrammatic construction scheme indicate that the orbital picture of ionization breaks down at binding energies larger than 22.5 eV. Despite this complication, they enable insights within 0.2 eV accuracy into the available ultraviolet photoemission and newly presented (e,2e) ionization spectra, except for the band associated with the 1a2-1 one-hole state, which is probably subject to rather significant vibronic coupling effects, and a band at ~25 eV characterized by a momentum distribution of "s-type" symmetry, which Green's function calculations fail to reproduce. We note the vicinity of the vertical double ionization threshold at ~26 eV.
Boryl-metal bonds facilitate cobalt/nickel-catalyzed olefin hydrogenation
Lin, Tzu-Pin,Peters, Jonas C.
, p. 13672 - 13683 (2014)
New approaches toward the generation of late first-row metal catalysts that efficiently facilitate two-electron reductive transformations (e.g., hydrogenation) more typical of noble-metal catalysts is an important goal. Herein we describe the synthesis of a structurally unusual S = 1 bimetallic Co complex, [(CyPBP)CoH]2(1), supported by bis(phosphino)boryl and bis(phosphino)hydridoborane ligands. This complex reacts reversibly with a second equivalent of H2(1 atm) and serves as an olefin hydrogenation catalyst under mild conditions (room temperature, 1 atm H2). A bimetallic Co species is invoked in the rate-determining step of the catalysis according to kinetic studies. A structurally related NiINiIdimer, [(PhPBP)Ni]2(3), has also been prepared. Like Co catalyst 1, Ni complex 3 displays reversible reactivity toward H2, affording the bimetallic complex [(PhPBHP)NiH]2(4). This reversible behavior is unprecedented for NiIspecies and is attributed to the presence of a boryl-Ni bond. Lastly, a series of monomeric (tBuPBP)NiX complexes (X = Cl (5), OTf (6), H (7), OC(H)O (8)) have been prepared. The complex (tBuPBP)NiH (7) shows enhanced catalytic olefin hydrogenation activity when directly compared with its isoelectronic/isostructural analogues where the boryl unit is substituted by a phenyl or amine donor, a phenomenon that we posit is related to the strong trans influence exerted by the boryl ligand.
Hydrogenation via photochemically generated diimide
Squillacote,De Felippis,Lai
, p. 4137 - 4140 (1993)
Diimide is a well-known reagent for hydrogenating multiple bonds with very high stereospecificity. However, all of the methods for generating diimide require somewhat rigorous conditions. We show here that 1-thia-3,4-diazolidine-2,5-dione (TDADH) can be used to photochemically produce diimide at room temperature under neutral conditions. The diimide thus produced can hydrogenate multiple bonds in high yields.
-
Bower, B. K.,Tennent, H. G.
, p. 2512 - 2514 (1972)
-
Moore et al.
, p. 2019 (1961)
Comparison of alkene hydrogenation in carbon nanoreactors of different diameters: Probing the effects of nanoscale confinement on ruthenium nanoparticle catalysis
Aygün, Mehtap,Stoppiello, Craig T.,Lebedeva, Maria A.,Smith, Emily F.,Gimenez-Lopez, Maria Del Carmen,Khlobystov, Andrei N.,Chamberlain, Thomas W.
, p. 21467 - 21477 (2017)
The catalytic properties of ruthenium nanoparticles (RuNPs) supported in carbon nanoreactors of different diameters-single walled carbon nanotubes (SWNTs, width of cavity 1.5 nm) and hollow graphitised nanofibers (GNFs, width of cavity 50-70 nm)-were evaluated using exploratory alkene hydrogenation reactions and compared to RuNPs adsorbed on the surface of SWNT or deposited on carbon black in commercially available Ru/C. Supercritical CO2 is shown to be essential to enable efficient transport of reactants to the catalytic RuNPs, particularly for the very narrow RuNP@SWNT nanoreactors. Though the RuNPs in SWNT are observed to be highly active, they simultaneously reduce the accessible volume of very narrow SWNTs by 30-40% resulting in lower overall turnover numbers (TONs). In contrast, RuNPs confined in wider GNFs were completely accessible and demonstrated remarkable activity compared to unconfined RuNPs on the outer surface of SWNTs or carbon black. Control of the nanoscale environment around the catalytic RuNPs significantly enhances the stability of the catalyst and influences the local concentration of reactant molecules in close proximity to the RuNPs, illustrating the comparable importance of confinement to that of metal loading and size of NPs in the catalyst. Interestingly, extreme spatial confinement also appeared not to be the best strategy for controlling the selectivity of hydrogenations in a competitive reaction of norbornene and benzonorbornadiene, with wider RuNP@GNF nanoreactors displaying enhanced selectivity for the hydrogenation of the aromatic group containing alkene (benzonorbornadiene). This is attributed to the presence of nanoscale graphitic step-edges within the GNF making them an attractive alternative to the extremely narrow SWNT nanoreactors for preparative catalysis.
-
Wiberg,K.B. et al.
, p. 2711 - 2714 (1976)
-
Heterometallic Mg?Ba Hydride Clusters in Hydrogenation Catalysis
Wiesinger, Michael,Knüpfer, Christian,Elsen, Holger,Mai, Jonathan,Langer, Jens,Harder, Sjoerd
, p. 4567 - 4577 (2021/09/09)
Reaction of a MgN“2/BaN”2 mixture (N“=N(SiMe3)2) with PhSiH3 gave three unique heterometallic Mg/Ba hydride clusters: Mg5Ba4H11N”7 ? (benzene)2 (1), Mg4Ba7H13N“9 ? (toluene)2 (2) and Mg7Ba12H26N”12 (3). Product formation is controlled by the Mg/Ba ratio and temperature. Crystal structures are described. While 3 is fully insoluble, clusters 1 and 2 retain their structures in aromatic solvents. DFT calculations and AIM analyses indicate highly ionic bonding with Mg?H and Ba?H bond paths. Also unusual H????H? bond paths are observed. Catalytic hydrogenation with MgN“2, BaN”2 and the mixture MgN“2/BaN”2 has been studied. Whereas MgN“2 is only active in imine hydrogenation, alkene and alkyne hydrogenation needs the presence of Ba. The catalytic activity of the MgN”2/BaN“2 mixture lies in general between that of its individual components and strong cooperative effects are not evident.
Hydrolysis of B2pin2 over Pd/C Catalyst: High Efficiency, Mechanism, and in situ Tandem Reaction
Li, Ning,Shen, Jialu,Liu, Xiang
supporting information, p. 2797 - 2800 (2021/02/16)
A facile and effective synthesis of H2 or D2 from Pd/C catalyzed hydrolysis of B2pin2 has first been developed. Among them, B2pin2 is frequently used for borylation reaction, and has rarely been used for hydrogen evolution. The kinetic isotope effects (KIEs) and tandem reaction for diphenylacetylene and norbornene hydrogenation have confirmed both two H atoms of H2 gas are provided from H2O. This is contrary to other boron compounds hydrolysis (including NH3BH3, NaBH4), which generates H2 with only one H atom provided by water and the other one by boron compounds. Note that the hydrolysis of B2pin2 in D2O also provides an easy and useful synthesis of D2.
Boosting homogeneous chemoselective hydrogenation of olefins mediated by a bis(silylenyl)terphenyl-nickel(0) pre-catalyst
Lücke, Marcel-Philip,Yao, Shenglai,Driess, Matthias
, p. 2909 - 2915 (2021/03/14)
The isolable chelating bis(N-heterocyclic silylenyl)-substituted terphenyl ligand [SiII(Terp)SiII] as well as its bis(phosphine) analogue [PIII(Terp)PIII] have been synthesised and fully characterised. Their reaction with Ni(cod)2(cod = cycloocta-1,5-diene) affords the corresponding 16 VE nickel(0) complexes with an intramolecularη2-arene coordination of Ni, [E(Terp)E]Ni(η2-arene) (E = PIII, SiII; arene = phenylene spacer). Due to a strong cooperativity of the Si and Ni sites in H2activation and H atom transfer, [SiII(Terp)SiII]Ni(η2-arene) mediates very effectively and chemoselectively the homogeneously catalysed hydrogenation of olefins bearing functional groups at 1 bar H2pressure and room temperature; in contrast, the bis(phosphine) analogous complex shows only poor activity. Catalytic and stoichiometric experiments revealed the important role of the η2-coordination of the Ni(0) site by the intramolecular phenylene with respect to the hydrogenation activity of [SiII(Terp)SiII]Ni(η2-arene). The mechanism has been established by kinetic measurements, including kinetic isotope effect (KIE) and Hammet-plot correlation. With this system, the currently highest performance of a homogeneous nickel-based hydrogenation catalyst of olefins (TON = 9800, TOF = 6800 h?1) could be realised.