31928-39-9

Basic information

• Product Name: Hydrazine, 1-phenyl-1-(2-propenyl)-
• CAS NO: 31928-39-9
• Molecular Formula: C9H12N2
• Molecular Weight: 148.208
• Mol File: 31928-39-9.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Hydrazine, 1-phenyl-1-(2-propenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Hydrazine, 1-phenyl-1-(2-propenyl)-(31928-39-9)
• EPA Substance Registry System: Hydrazine, 1-phenyl-1-(2-propenyl)-(31928-39-9)

Safety Data

• Hazardous Substances Data: 31928-39-9(Hazardous Substances Data)

Upstream product

• 589-09-3 N-allyl-N-phenylamine 
• 64-17-5 ethanol 
• 106-95-6 allyl bromide 
• 100-63-0 phenylhydrazine 
• 556-56-9 allyl iodid 
• 27843-96-5 (1E)-1-(2-phenylhydrazin-1-ylidene)propan-2-one 

Downstream Products

• 110213-00-8 propanal phenylallylhydrazone 
• 132127-03-8 mesoxalaldehyde-1-(allyl-phenyl-hydrazone)-2-phenylhydrazone 
• 951781-04-7 C₁₈H₁₇ClF₃N₃O₂S 
• 589-09-3 N-allyl-N-phenylamine 
• 1450812-65-3 C₁₁H₁₄N₂O 
• 1450812-70-0 C₂₂H₂₁NO₂ 
• 110213-04-2 3-phenylazo-5-hexene 
• 110213-02-0 N-Allyl-N'-[1-methyl-prop-(E)-ylidene]-N-phenyl-hydrazine 
• 110213-01-9 N-Allyl-N'-isopropylidene-N-phenyl-hydrazine 
• 110213-13-3 N-Allyl-N'-eth-(E)-ylidene-N-phenyl-hydrazine 
• 61908-60-9 benzaldehyde-(allyl-phenyl-hydrazone) 
• 66255-61-6 N-Allyl-N'-methylene-N-phenyl-hydrazine 

Relevant articles and documents

Preparation of Hexahydrocarbazole Derivatives by Reductive Indolization

The reductive indolization is a two-step protocol performed in one flask: First, the acid-mediated Fischer indolization of a cyclic ketone with phenylhydrazine forms an iminium ion which is subsequently reduced by a hydrido borate reagent to the indoline as the final product. We utilized this new strategy for the preparation of hexahydrocarbazole derivatives with a side chain in the quaternary C4a-position. Starting materials were several N1- and aryl-substituted phenylhydrazines and a cyclic ketone with propanoic ester moiety, which is the product of the conjugated addition of cyclohexanone to ethyl acrylate. Furthermore, benzannulated congeners as well as a pyrido[4,3-b]indole derivative were accessed. The hexahydrocarbazole defines a molecular scaffold with two points of diversification. Therefore, several derivatives at N9 and at the C4a-side chain were prepared.

Formation of enehydrazine intermediates through coupling of phenylhydrazines with vinyl halides: Entry into the Fischer indole synthesis

Cut to the chase: Direct formation of an enehydrazine, an intermediate in the classic Fischer indole synthesis, solves the regioselectivity problem associated with indolization. This approach not only achieves selective synthesis of indoles through proper selection of the vinyl halide, but also leads to quick construction of desoxyeseroline and esermethole, as well as the key structural motif in the Akuammiline alkaloid vincorine. Copyright

Investigation of the Potential of Molybdenum(VI) Hydrazido(2-) Complexes as Sources of Nitrenium Ions: Cleavage of the N-N Bond and Incorporation of the β-Nitrogen Group into Solvent Molecules

Photolyis or thermolysis of bis(N,N-dimethyldithiocarbamato)bismolybdenum(VI) complexes in 1,1,2,2-tetrachloroethane results predominantly in transfer of the hydrazido group to the solvent with formation of dichloroacetohydrazides.A small amount of the corresponding dichloroacetamides are produced by N-N cleavage and N(R)Ph transfer.In contrast, the latter process dominates the reaction of dichlorobis(N,N-dimethyldithiocarbamato)mono-molybdenum(VI) complexes with silver nitrate in alcohols occuring concomitantly with ring methoxylation and nitration and N-nitrosation.Neither transfer of N(R)Ph appears to involve free nitrenium ions.