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7-Bromo-2-iodo-9,9-dimethyl-9H-fluorene is a complex organic compound that is a derivative of fluorene, a polycyclic aromatic hydrocarbon. It features two methyl groups at the 9th carbon atom, a bromine atom at the 7th position, and an iodine atom at the 2nd position on the fluorene structure. The presence of these halogen atoms and methyl groups significantly alters the properties of the fluorene molecule, making it a versatile compound for various applications.

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  • 319906-45-1 Structure
  • Basic information

    1. Product Name: 7-Bromo-2-iodo-9,9-dimethyl-9H-fluorene
    2. Synonyms: 2-Bromo-7-iodo-9,9-dimethyl-9H-fluorene;2-Bromo-7-iodo-9,9-dimethylfluorene;7-Bromo-2-iodo-9,9-dimethyl-9H-fluorene;2-Bromo-7-iodo-9,9-d;2-Bromo-7-iodo-9,9-dimethyl-fluoren
    3. CAS NO:319906-45-1
    4. Molecular Formula: C15H12BrI
    5. Molecular Weight: 399.06
    6. EINECS: 1312995-182-4
    7. Product Categories: N/A
    8. Mol File: 319906-45-1.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 424.2 °C at 760 mmHg
    3. Flash Point: 210.4 °C
    4. Appearance: /
    5. Density: 1.773
    6. Vapor Pressure: 5.19E-07mmHg at 25°C
    7. Refractive Index: 1.666
    8. Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
    9. Solubility: N/A
    10. CAS DataBase Reference: 7-Bromo-2-iodo-9,9-dimethyl-9H-fluorene(CAS DataBase Reference)
    11. NIST Chemistry Reference: 7-Bromo-2-iodo-9,9-dimethyl-9H-fluorene(319906-45-1)
    12. EPA Substance Registry System: 7-Bromo-2-iodo-9,9-dimethyl-9H-fluorene(319906-45-1)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 319906-45-1(Hazardous Substances Data)

319906-45-1 Usage

Uses

Used in Organic Synthesis:
7-Bromo-2-iodo-9,9-dimethyl-9H-fluorene is used as a synthetic intermediate for the preparation of other complex organic molecules. Its bromine and iodine atoms can be utilized to drive specific reactions, making it a valuable compound in the field of organic chemistry.
Used in Research Labs:
Due to its complex and specialized chemical nature, 7-Bromo-2-iodo-9,9-dimethyl-9H-fluorene is often used in research settings. It serves as a subject of study for understanding the effects of halogen substitution on the properties of fluorene and related compounds.
Used in Advanced Material Synthesis:
7-Bromo-2-iodo-9,9-dimethyl-9H-fluorene is used as a building block in the synthesis of advanced materials. Its unique structure and properties contribute to the development of new materials with potential applications in various industries.
Used in Pharmaceutical Synthesis:
7-Bromo-2-iodo-9,9-dimethyl-9H-fluorene is used as a key component in the synthesis of pharmaceuticals. Its structure and reactivity make it a promising candidate for the development of new drugs and therapeutic agents.
It is important to handle 7-Bromo-2-iodo-9,9-dimethyl-9H-fluorene with care due to its reactivity, and it is typically used in controlled environments such as laboratories.

Check Digit Verification of cas no

The CAS Registry Mumber 319906-45-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 3,1,9,9,0 and 6 respectively; the second part has 2 digits, 4 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 319906-45:
(8*3)+(7*1)+(6*9)+(5*9)+(4*0)+(3*6)+(2*4)+(1*5)=161
161 % 10 = 1
So 319906-45-1 is a valid CAS Registry Number.
InChI:InChI=1/C15H12BrI/c1-15(2)13-7-9(16)3-5-11(13)12-6-4-10(17)8-14(12)15/h3-8H,1-2H3

319906-45-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-bromo-7-iodo-9,9-dimethylfluorene

1.2 Other means of identification

Product number -
Other names 7-Bromo-2-Iodo-9,9-Dimethyl-9H-Fluorene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:319906-45-1 SDS

319906-45-1Relevant articles and documents

Vinyl-Fluorene Molecular Wires for Voltage Imaging with Enhanced Sensitivity and Reduced Phototoxicity

Boggess, Steven C.,Gandhi, Shivaani S.,Benlian, Brittany R.,Miller, Evan W.

supporting information, p. 11903 - 11907 (2021/08/20)

Fluorescent voltage indicators are an attractive alternative for studying the electrical activity of excitable cells; however, the development of indicators that are both highly sensitive and low in toxicity over long-term experiments remains a challenge.

Covalent Assembly and Characterization of Nonsymmetrical Single-Molecule Nodes

Nacci, Christophe,Viertel, Andreas,Hecht, Stefan,Grill, Leonhard

supporting information, p. 13724 - 13728 (2016/10/26)

The covalent linking of molecular building blocks on surfaces enables the construction of specific molecular nanostructures of well-defined shape. Molecular nodes linked to various entities play a key role in such networks, but represent a particular chal

NITROGENATED AROMATIC HETEROCYCLIC DERIVATIVE, AND ORGANIC ELECTROLUMINESCENT ELEMENT USING SAME

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Paragraph 0153-0154, (2014/06/24)

A nitrogen-containing aromatic heterocyclic derivative in which a nitrogen atom of an indenocarbazole skeleton optionally having a hetero atom or an indenoindole skeleton optionally having a hetero atom is bonded to a dibenzofuran or a dibenzothiophene directly or indirectly. The derivative realizes an organic EL device with a high emission efficiency and a long lifetime.

AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE ELEMENT USING SAME

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Paragraph 0179; 0180, (2014/08/19)

An aromatic amine derivative represented by formula (1): wherein L1, L2, Ar1, Ar2, R1, R2, a, b, and Q are as defined in the specification. An organic electroluminescence device having at least one organic thin film layer which includes the aromatic amine derivative has high emission efficiency and long lifetime.

AROMATIC AMINE DERIVATIVE, ORGANIC ELECTROLUMINESCENT ELEMENT AND ELECTRONIC DEVICE

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Paragraph 0194; 0195; 0196, (2015/01/18)

An organic EL device that has a high efficiency and a long service life, an electronic apparatus containing the organic EL device, and a compound capable of providing the organic EL device. The compound is specifically represented by the following general

BIS-CARBAZOLE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT ELEMENT USING SAME

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Paragraph 0134, (2014/02/15)

A biscarbazole derivative represented by formula (1): wherein A1, A2, L1, L2, R1 to R4, and a to d are as defined in the specification, is useful as a material for forming organic EL devices and the organic EL devices including the derivative is capable of driving at a low voltage and has a long lifetime.

AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT ELEMENT USING SAME

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Paragraph 0066, (2013/12/03)

To provide an organic EL element material that is capable of enhancing the light emission efficiency and the lifetime of the element as compared to an ordinary organic EL element material, and an organic EL element using the same. Specifically, to provide

AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT ELEMENT USING SAME

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Page/Page column 31, (2012/02/15)

There are provided an aromatic monoamine derivative having a fluorene structure-containing organic group and an aromatic hydrocarbon group-containing organic group, and an organic electroluminescent element containing an organic thin film layer composed of a single layer or plural layers while including at least a light emitting layer, the organic thin film layer being between a cathode and an anode, wherein at least one layer of the organic thin film layer, particularly a hole transport layer, contains the aromatic amine derivative alone or as a component of a mixture. An organic electroluminescent element which maintains high luminous efficiency even if exposed to a high temperature environment, and has a low driving voltage and a long emission lifetime, and an aromatic amine derivative capable of realizing the organic electroluminescent element are provided.

AROMATIC AMINE DERIVATIVES AND ORGANIC ELECTROLUMINESCENT ELEMENTS USING SAME

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Page/Page column 119, (2012/07/03)

Provided are an organic EL device material capable of reducing the driving voltage of an organic EL device and increasing the lifetime of the device as compared with a conventional organic EL device material, specifically an aromatic amine derivative represented by N(Ara)(Arb)(Arc), and an organic EL device using the material. [Ara is represented by the formula (II). (In the formula (II): La represents a single bond or an arylene group; R1 to R4 each represent an alkyl group, an aryl group, or the like, and R3's or R4's, or R3 and R4 may be bonded to each other to form a ring; and o represents 0 to 3 and p represents 0 to 4.) Arb is represented by the formula (III). (in the formula (III), X represents NRa, O, or S, and Ra and R5 to R7 each represent an alkyl group, an aryl group, or the like, and R5's, R6's, or R7's adjacent to each other, or R5 and R6 may be bonded to each other to form a ring; n represents 2 to 4 when X represents NRa, and represents 0 to 4 when X represents O or S; and q represents 0 to 3, r and s each independently represent 0 to 4.) Arc represents an aryl group, or is represented by the formula (III).]

AROMATIC AMINE DERIVATIVE, AND ORGANIC ELECTROLUMINESCENT ELEMENT

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Page/Page column 62, (2012/08/14)

Provided are: an aromatic amine derivative including a substituent A and a substituent B each represented by the formula (1) or (2) and having an arylene group bound to a carbazole structure, in which the substituent A and the substituent B include groups different from each other in the position at which the arylene group is bonded to the carbazole structure, and the substituent A and the substituent B are bonded to the same nitrogen atom or different nitrogen atoms in the molecule; an organic electroluminescent device including an organic thin-film layer formed of one or more layers including at least a light emitting layer, the organic thin-film layer being interposed between a cathode and a anode, in which at least one layer of the organic thin-film layer contains the aromatic amine derivative, and the molecules are rarely crystallized, the yield upon production of the organic electroluminescent device is improved, the driving voltage for the organic electroluminescent device is low, and the lifetime of the organic electroluminescent device is long; and an aromatic amine derivative which can realize the organic electroluminescent device. (In the formulae, each substituent is as described in claim 1.)

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