32812-89-8

Basic information

• Product Name: bis(benzenethiolato)lead(II)
• CAS NO: 32812-89-8
• Molecular Formula: C₆H₆S
• Molecular Weight: 425.543
• Mol File: 32812-89-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: bis(benzenethiolato)lead(II)(CAS DataBase Reference)
• NIST Chemistry Reference: bis(benzenethiolato)lead(II)(32812-89-8)
• EPA Substance Registry System: bis(benzenethiolato)lead(II)(32812-89-8)

Safety Data

• Hazardous Substances Data: 32812-89-8(Hazardous Substances Data)

Upstream product

• 6080-56-4 lead(II) acetate trihydrate 
• 108-98-5 thiophenol 
• 82737-35-7 diphenyldicyclopentadienylplumbane 
• 7439-92-1 lead 

Downstream Products

• 139-66-2 diphenyl sulfide 
• 137-06-4 2-thiocresol 
• 52548-11-5 Chloro-dimethyl-phenylsulfanyl-silane 
• 167076-37-1 [Pd2Me2(μ-SPh)2(PMe2Ph)2] 
• 166904-89-8 [Pd2Me2(μ-SPh)2(PBu3)2] 
• 45704-68-5 [PdCl(SC₆H₅)] 
• 166904-98-9 [Pd2(μ-SPh)2(η(3)-C3H5)2] 
• 172660-34-3 [Pd(η(3)-2-methallyl)(benzenethiolate)]2 
• 405139-54-0 C₃₈H₃₂P₂PtS₂ 
• 522653-94-7 Fe(C₅H₄P(C₆H₅)2)2Pt(C₆H₅S)2 
• 1353050-93-7 [Pd2Ph2(μ-SPh)2(PPhMe2)2] 
• 1251839-33-4 Pt2(μ-SPh)2(CH2CMe2PtBu2)2 
• 460989-88-2 [Pd2Cl2(μ-SPh)2(AsPr3)2] 
• 460989-89-3 [Pd2Cl2(μ-SPh)2(AsiPr3)2] 

Relevant articles and documents

Structural Tunability and Diversity of Two-Dimensional Lead Halide Benzenethiolate

Two-dimensional (2D) organic-inorganic hybrid materials are currently of great interest for applications in electronics and optoelectronics. Here, the synthesis and optical properties of a new type of halide-organothiolate-mixed 2D hybrid material, Pb2X(S-C6H5)3, are reported, in which X is a halide (I, Br, or Cl). Different from conventional lead-based 2D layered materials, these compounds feature unusual five-coordinated lead centers with a stereochemically active electron lone pair on the lead atoms and four-coordinated iodine atoms. The Pb2X(S-C6H5)3 materials feature an indirect bandgap, strongly emissive long-lived self-trap states, and an extremely large Stokes shift. Interestingly, the optical bandgap of the materials can be tuned through variation of the halides; however, the photoluminescence is less sensitive to the composition and is more likely dominated by lead-sulfur lattice interactions or the lead lone-pair electrons. Our results support that a halide–organothiolate mixed anion hybrid structure offers a unique platform for discovering new exciting 2D electronic materials.

Direct electrochemical synthesis of benzenethiolato complexes of tin(II), tin(IV), and lead(II). Molecular structure of the 2,2′-bipyridine adduct of Sn(SC6H5)4

The electrochemical oxidation of tin into solutions of RSH (R = C6H5 C6H4CH3) gives Sn(SR)2. When 2,2′-bipyridine (bpy) or 1,10-phenanthroline is added to the solution phase, the product is the tin(IV) species Sn(SR)4L. The electrochemical oxidation is shown to involve Sn(II) as the first product in each case. The crystal structure of Sn(SC6H5)4bpy is monoclinic, with a = 13.150 (5) ?, b = 17.438 (6) ?, c = 14.215 (6) ?, β = 93.49 (3)°, V = 3254 (2) ?3, Z = 4, and space group P21/n (C2h5, No. 14). The molecule has a distorted octahedral SnS4N2 kernel, with bond distances of 2.449 (Sn-S) and 2.331 ? (Sn-N). With a lead anode, the product is Pb(SC6H5)2; no lead(IV) species could be isolated.