34177-25-8

Basic information

• Product Name: 4-iodo-1,1':3',1''-terphenyl
• Synonyms: 4-iodo-1,1':3',1''-terphenyl;4-Iodo-m-terphenyl
• CAS NO: 34177-25-8
• Molecular Formula: C₁₈H₁₃I
• Molecular Weight: 356.20029
• Mol File: 34177-25-8.mol

Chemical Properties

• Melting Point: 67℃
• Boiling Point: 432℃
• Flash Point: 196℃
• Appearance: /
• Density: 1.471
• CAS DataBase Reference: 4-iodo-1,1':3',1''-terphenyl(CAS DataBase Reference)
• NIST Chemistry Reference: 4-iodo-1,1':3',1''-terphenyl(34177-25-8)
• EPA Substance Registry System: 4-iodo-1,1':3',1''-terphenyl(34177-25-8)

Safety Data

• Hazardous Substances Data: 34177-25-8(Hazardous Substances Data)

Usage

Uses

Used in Organic Synthesis:
4-iodo-1,1':3',1''-terphenyl is utilized as a building block in organic synthesis for the creation of more complex organic molecules. Its presence of the iodine atom allows for further functionalization and modification, making it a valuable precursor in the synthesis of various organic compounds.
Used in Material Science:
In the field of material science, 4-iodo-1,1':3',1''-terphenyl is employed in the development of liquid crystals and organic electronic devices. Its unique structure and properties contribute to the performance and functionality of these advanced materials.
Used in Pharmaceutical Chemistry:
4-iodo-1,1':3',1''-terphenyl serves as a key intermediate in the synthesis of pharmaceutical compounds. Its reactivity and structural features make it a promising candidate for the development of new drugs and therapeutic agents.

Upstream product

• 92-06-8 1,3-diphenylbenzene 
• 5728-67-6 m-terphenyl-4-ylamine 

Downstream Products

• 34203-49-1 2,4,2',4'-tetraphenylbiphenyl 
• 3073-03-8 2-phenyltriphenylene 
• 897671-70-4 C₄₃H₃₁NO 
• 87666-86-2 5′-iodo-1,1:3′,1″-terphenyl 

Relevant articles and documents

PtI2-catalyzed cyclization of 3-acyloxy-1,5-enynes with the elimination of HOAc and a benzyl shift: Synthesis of unsymmetrical m-terphenyls

A novel cyclization of 3-acyloxy-1,5-enynes is developed in the presence of PtI2 for the synthesis of substituted unsymmetrical m-terphenyls in good to excellent yields. Two unique steps are involved in this transformation, which includes the elimination of HOAc and benzyl group migration. DFT calculations indicated that the rate-determining step is the migration of the benzylic carbocation to form a zwitterionic intermediate followed by the elimination of HOAc. The subsequent cyclopropanation of the zwitterionic intermediate is the regioselectivity-determining step.

AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT ELEMENT USING SAME

There are provided an aromatic monoamine derivative having a fluorene structure-containing organic group and an aromatic hydrocarbon group-containing organic group, and an organic electroluminescent element containing an organic thin film layer composed of a single layer or plural layers while including at least a light emitting layer, the organic thin film layer being between a cathode and an anode, wherein at least one layer of the organic thin film layer, particularly a hole transport layer, contains the aromatic amine derivative alone or as a component of a mixture. An organic electroluminescent element which maintains high luminous efficiency even if exposed to a high temperature environment, and has a low driving voltage and a long emission lifetime, and an aromatic amine derivative capable of realizing the organic electroluminescent element are provided.

AROMATIC AMINE DERIVATIVES AND ORGANIC ELECTROLUMINESCENT ELEMENTS USING SAME

Provided are an organic EL device material capable of reducing the driving voltage of an organic EL device and increasing the lifetime of the device as compared with a conventional organic EL device material, specifically an aromatic amine derivative represented by N(Ara)(Arb)(Arc), and an organic EL device using the material. [Ara is represented by the formula (II). (In the formula (II): La represents a single bond or an arylene group; R1 to R4 each represent an alkyl group, an aryl group, or the like, and R3's or R4's, or R3 and R4 may be bonded to each other to form a ring; and o represents 0 to 3 and p represents 0 to 4.) Arb is represented by the formula (III). (in the formula (III), X represents NRa, O, or S, and Ra and R5 to R7 each represent an alkyl group, an aryl group, or the like, and R5's, R6's, or R7's adjacent to each other, or R5 and R6 may be bonded to each other to form a ring; n represents 2 to 4 when X represents NRa, and represents 0 to 4 when X represents O or S; and q represents 0 to 3, r and s each independently represent 0 to 4.) Arc represents an aryl group, or is represented by the formula (III).]

AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME

Disclosed is a long-life organic EL device having high luminous efficiency even after storage at high temperatures. Also disclosed is an aromatic amine derivative which enables to realize such an organic EL device. The aromatic amine derivative is represented by the following general formula (1). (In the formula (1), Ar1 is represented by the general formula (2) below, and Ar2 is represented by the general formula (3) below.)

AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME

Disclosed is a long-life organic EL device having high luminous efficiency even after storage at high temperatures. Also disclosed is an aromatic amine derivative which enables to realize such an organic EL device. The aromatic amine derivative is represented by the following general formula (1). (In the formula (1), Ar1 is represented by the general formula (2) below, and Ar2 is represented by the general formula (3) below.)

AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME

An aromatic amine derivative having a specific structure. An organic electroluminescence device which is composed of one or more organic thin film layers sandwiched between a cathode and an anode, wherein at least one of the organic thin film layers especially a hole transporting layer, contains the aromatic amine derivative. The aromatic amine derivative has at least one substituted or unsubstituted dibenzofuran skeleton and at least one substituted or unsubstituted terphenylene skeleton. Because the molecules in the aromatic amine derivative hardly crystallize, organic electroluminescence devices improving their production yield and having prolonged lifetime are provided.

AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT ELEMENT EMPLOYING THE SAME

An aromatic amine derivative having a specific structure having m-terphenyl group and an organic electroluminescence device comprising a cathode, an anode and an organic thin film layer which is disposed between the cathode and the anode and comprises at least one layer comprising at least a light emitting layer, wherein at least one layer in the organic thin film layer comprises the aromatic amine derivative singly or as a component of a mixture. The organic electroluminescence device has a long life.

AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT DEVICE USING SAME

Disclosed is an organic electroluminescent device wherein an organic thin film which is composed of one or more layers including at least a light-emitting layer is interposed between a cathode and an anode. Since at least one layer of the organic thin film contains a novel aromatic amine derivative, which has an asymmetric structure wherein two different amine units are bonded through a linking group, by itself or as a component of a mixture, molecules are hardly crystallized, thereby improving the production yield of the organic electroluminescent device. This organic electroluminescent device has a long life.

AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT DEVICE USING SAME

Disclosed is a novel aromatic amine derivative having an asymmetric structure. Also disclosed is an organic electroluminescent device wherein an organic thin film composed of one or more layers including at least a light-emitting layer is interposed between a cathode and an anode. Since at least one layer of the organic thin film contains the aromatic amine derivative by itself or as a component of a mixture, molecules are hardly crystallized, thereby improving the production yield of the organic electroluminescent device. This organic electroluminescent device has a long life.