35856-81-6

Basic information

• Product Name: Benzene, 1-methoxy-4-(3-phenyl-1-propenyl)-, (E)-
• CAS NO: 35856-81-6
• Molecular Formula: C16H16O
• Molecular Weight: 224.302
• Mol File: 35856-81-6.mol
• Article Data: 52

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methoxy-4-(3-phenyl-1-propenyl)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-4-(3-phenyl-1-propenyl)-, (E)-(35856-81-6)
• EPA Substance Registry System: Benzene, 1-methoxy-4-(3-phenyl-1-propenyl)-, (E)-(35856-81-6)

Safety Data

• Hazardous Substances Data: 35856-81-6(Hazardous Substances Data)

Upstream product

• 496789-06-1 (E)-p-methoxycinnamyl methyl carbonate 
• 20850-13-9 (E)-3-(4-methoxyphenyl)prop-2-en-1-amine 
• 98-80-6 phenylboronic acid 
• 1046826-12-3 C₁₇H₁₇NO₃S 
• 1403462-83-8 C₂₄H₂₅NO₅S₂ 
• 28557-00-8 phenylzinc chloride 
• 1000979-69-0 4-methyl-N-[(2E)-3-(4-methoxyphenyl)-2-propenyl]benzenesulfonamide 
• 943-89-5 (E)-3-(4-methoxyphenyl)acrylic acid 
• 122-78-1 phenylacetaldehyde 
• 24680-50-0 4-methoxy-trans-cinnamaldehyde 
• 53484-50-7 (E)-p-methoxy-cinnamyl alcohol 
• 30277-63-5 3-methoxy-3-(4-methoxyphenyl)propene 
• 300-57-2 allylbenzene 
• 5720-07-0 4-methoxyphenylboronic acid 

Downstream Products

• 35856-80-5 4-(3-phenylallyl)anisole 
• 122-78-1 phenylacetaldehyde 
• 123-11-5 4-methoxy-benzaldehyde 
• 100-09-4 4-methoxybenzoic acid 
• 40715-68-2 1‐methoxy‐4‐(3‐phenylpropyl)benzene 
• 20442-74-4 1-Methoxy-4-((E)-3-phenyl-propenyl)-benzene 
• 93010-65-2 4-(1,2-dibromo-3-phenyl-propyl)-anisole 
• 102560-35-0 1-benzoyloxy-1-(4-methoxy-phenyl)-3-phenyl-propan-2-ol 

Relevant articles and documents

Observation of Stable and Transient Intermediates in Palladium Complex-catalysed Cross-coupling Reactions

Complexes of 1,1'-bis(diphenylphosphino)ferrocene corresponding to the separate steps of cross-coupling have been identified and related to the catalytic cycle.

Visible-Light-Promoted Cross-Coupling of N-Alkylpyridinium Salts and Nitrostyrenes

A stereoselective, denitrative cross-coupling of β-nitrostyrenes with N-alkylpyridinium salts for the preparation of functionalized styrenes has been developed. The visible-light-induced reaction proceeds without any catalyst at ambient temperature. Broad in scope and tolerant to multiple functional groups, the moderately yielding transformation is orthogonal to several traditional metal-catalyzed cross-couplings.

Palladium-catalyzed reaction of γ-silylated allyl acetates proceeding through 1,2-shift of a substituent on silicon

The palladium-catalyzed reaction of γ-silylated allyl acetates with water in the presence of CsF induces a previously unprecedented 1,2-shift of a substituent on silicon to produce allylsilanes in situ. The catalytic activity of the palladium increased when using an electron-poor phosphine ligand possessing fluorinated substituents. Further investigation of the reaction revealed that the approximate order of the migratory aptitude of groups from silicon was PhC≡C, allyl > Bn > Ph, vinyl > alkyl (Me, Et). A density functional theory study was employed to explore the reaction mechanism. Finally, the Hosomi–Sakurai-type allylation of aldehydes with in situ-generated α,γ-disubstituted allylsilanes was also investigated.