399031-16-4

Basic information

• Product Name: Pyridine, 2-bromo-6-(phenoxymethyl)-
• Synonyms: Pyridine,2-bromo-6-(phenoxymethyl)
• CAS NO: 399031-16-4
• Molecular Formula: C12H10BrNO
• Molecular Weight: 264.11800
• Mol File: 399031-16-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Pyridine, 2-bromo-6-(phenoxymethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Pyridine, 2-bromo-6-(phenoxymethyl)-(399031-16-4)
• EPA Substance Registry System: Pyridine, 2-bromo-6-(phenoxymethyl)-(399031-16-4)

Safety Data

• Hazardous Substances Data: 399031-16-4(Hazardous Substances Data)

Upstream product

• 557789-12-5 (6-bromopyridin-2-yl)methyl methanesulfonate 
• 33674-96-3 2-bromo-6-(hydroxymethyl)pyridine 
• 496840-11-0 2-bromo-6-(iodomethyl)pyridine 
• 108-95-2 phenol 
• 139-02-6 sodium phenoxide 

Downstream Products

• 399031-19-7 1,2-bis[(6-phenoxymethyl-2-pyridyl)ethynyl]benzene 

Relevant articles and documents

Self-assembly and substituent effect of copper(I) complexes with 1,2-bis(2-pyridylethynyl)benzene ligands

The reaction of 1,2-bis(2-pyridylethynyl)benzenes (L1-L5) with copper(I) ions proceeded smoothly to afford mononuclear copper(I) chelate complexes CL1-CL3 or dinuclear copper(I) molecular rectangular boxes, CL4 and CL5, in excellent yields, depending on the size of the substituent. If a ligand with a small substituent was used, the self-assembly of a mononuclear copper(I) chelate complex was achieved. If a ligand with a bulky substituent was used, the self-assembly of dinuclear copper(I) molecular rectangular boxes was achieved. The equilibrium between these two copper(I) complexes was also observed in solution.