41098-56-0

Basic information

• Product Name: Fluorescent Brightener 357
• Synonyms: Kaycoll PK;hexasodium 2,2'-[vinylenebis[(3-sulphonato-4,1-phenylene)imino[6-(diethylamino)-1,3,5-triazine-4,2-diyl]imino]]bis(benzene-1,4-disulphonate);Fluorescent Brightener 357;2,2'-(1,2-ethenediyl)bis[5-[[4-(diethylamino)-6-[(2,5-disulfophenyl)amino]-1,3,5-triazin-2-yl]amino]benzenesulfonic acid] hexasodium salt;Tinopal STP;tinopal scp;1,4-Benzenedisulfonic acid, 2,2-1,2-ethenediylbis(3-sulfo-4,1-phenylene)imino6-(diethylamino)-1,3,5-triazine-4,2-diyliminobis-, hexasodium salt;2,2'-[1,2-Ethenediylbis[(3-sulfo-4,1-phenylene)imino[6-(diethylamino)-1,3,5-triazine-4,2-diyl]imino]]bis(1,4-benzenedisulfonic acid)hexasodium salt
• CAS NO: 41098-56-0
• Molecular Formula: C₄₀H₃₈N₁₂O₂₂S₆*6Na
• Molecular Weight: 1305.13
• EINECS: 255-217-5
• Product Categories: Organics
• Mol File: 41098-56-0.mol

Chemical Properties

• Appearance: /
• Density: 1.64[at 20℃]
• Vapor Pressure: 0-0Pa at 25℃
• Water Solubility: 201.1g/L at 20℃
• CAS DataBase Reference: Fluorescent Brightener 357(CAS DataBase Reference)
• NIST Chemistry Reference: Fluorescent Brightener 357(41098-56-0)
• EPA Substance Registry System: Fluorescent Brightener 357(41098-56-0)

Safety Data

• Hazardous Substances Data: 41098-56-0(Hazardous Substances Data)

Usage

Uses

Used in Textile Industry:
Fluorescent Brightener 357 is used as a whitening agent for textiles to improve the brightness and whiteness of fabrics. It helps in enhancing the overall appearance of the textile products, making them more visually appealing to consumers.
Used in Paper Industry:
In the paper industry, Fluorescent Brightener 357 is used as an additive to improve the whiteness and brightness of paper products. It helps in producing high-quality paper with a more vibrant and eye-catching appearance.
Used in Detergent Industry:
Fluorescent Brightener 357 is used as a whitening agent in the detergent industry, particularly in laundry detergents and fabric softeners. It helps in brightening and whitening clothes, giving them a fresh and clean look after washing.
Used in Cosmetic Industry:
In the cosmetic industry, Fluorescent Brightener 357 is used in various products such as creams, lotions, and makeup to enhance their appearance and provide a brighter, more radiant finish.
Used in Microbial Insecticides:
Fluorescent Brightener 357 is used as a protective agent for baculoviruses in the agricultural industry. It helps in protecting the baculoviruses against deactivation by UV light, thereby enhancing their activity as microbial insecticides on hosts and semipermissive hosts. This improves the bioinsecticidal activity of Anticarsia gemmatalis nucleopolyhedrovirus, making it more effective in controlling insect pests.

InChI:InChI=1/C40H44N12O18S6.6Na/c1-5-51(6-2)39-47-35(45-37(49-39)43-29-21-27(71(53,54)55)15-17-31(29)73(59,60)61)41-25-13-11-23(33(19-25)75(65,66)67)9-10-24-12-14-26(20-34(24)76(68,69)70)42-36-46-38(50-40(48-36)52(7-3)8-4)44-30-22-28(72(56,57)58)16-18-32(30)74(62,63)64;;;;;;/h9-22H,5-8H2,1-4H3,(H,53,54,55)(H,56,57,58)(H,59,60,61)(H,62,63,64)(H,65,66,67)(H,68,69,70)(H2,41,43,45,47,49)(H2,42,44,46,48,50);;;;;;/q;6*+1/p-6/rC40H38N12Na6O18S6/c1-5-51(6-2)39-47-35(45-37(49-39)43-29-21-27(77(59,60)71-53)15-17-31(29)79(63,64)73-55)41-25-13-11-23(33(19-25)81(67,68)75-57)9-10-24-12-14-26(20-34(24)82(69,70)76-58)42-36-46-38(50-40(48-36)52(7-3)8-4)44-30-22-28(78(61,62)72-54)16-18-32(30)80(65,66)74-56/h9-22H,5-8H2,1-4H3,(H2,41,43,45,47,49)(H2,42,44,46,48,50)

Synthetic route

C32H18Cl2N10O18S6(6-)*6Na(1+) + 2,2'-iminobis[ethanol] (111-42-2) → 2,2'-(1,2-ethenediyl)bis[5-{(4-bis(2-hydroxyethyl)amino)-6-[(3,6-disulfophenyl)amino]-1,3,5-triazin-2-yl}amino]benzenesulfonic acid hexasidium salt (41098-56-0)

Conditions	Yield
With sodium carbonate at 98℃; for 3.5h; pH=9;	89%

L-Aspartic acid (56-84-8) + C32H18Cl2N10O18S6(6-)*6Na(1+) + 2,2'-iminobis[ethanol] (111-42-2) → C40H32N12O24S6(8-)*8Na(1+) + C40H26N12O26S6(10-)*10Na(1+) + 2,2'-(1,2-ethenediyl)bis[5-{(4-bis(2-hydroxyethyl)amino)-6-[(3,6-disulfophenyl)amino]-1,3,5-triazin-2-yl}amino]benzenesulfonic acid hexasidium salt (41098-56-0)

Conditions	Yield
With sodium hydroxide In water at 95 - 100℃; for 4h; pH=8 - 9;

3-(N,N-diethylamino)propionamide (3813-27-2) + 2,2'-(1,2-ethenediyl)bis[5-{(4-bis(2-hydroxyethyl)amino)-6-[(3,6-disulfophenyl)amino]-1,3,5-triazin-2-yl}amino]benzenesulfonic acid hexasidium salt (41098-56-0) → C40H38N12O22S6(6-)*3.6Na(1+)*2.4C7H16N2O*2.4H(1+)

Conditions	Yield
With sulfuric acid; sodium chloride In water at 25℃;	100 g

Upstream product

• 56-84-8 L-Aspartic acid 
• 111-42-2 2,2'-iminobis[ethanol] 

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