4208-57-5

Basic information

• Product Name: 1-(2-FURYL)BUTAN-1-ONE
• Synonyms: 1-(2-FURYL)BUTAN-1-ONE;2-BUTANOYLFURAN;FEMA 4083;FURYL-N-PROPYL KETONE;FURYL PROPYL KETONE;1-(2-Furyl)butan-1-one 97%;1-(2-Furanyl)-1-butanone;1-furan-2-ylbutan-1-one
• CAS NO: 4208-57-5
• Molecular Formula: C₈H₁₀O₂
• Molecular Weight: 138.16
• Mol File: 4208-57-5.mol
• Article Data: 7

Chemical Properties

• Melting Point: 10-12 °C
• Boiling Point: 205.6 °C at 760 mmHg
• Flash Point: 87.7 °C
• Appearance: /
• Density: 1.01 g/cm³
• Vapor Pressure: 0.248mmHg at 25°C
• Refractive Index: 1.465
• CAS DataBase Reference: 1-(2-FURYL)BUTAN-1-ONE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-FURYL)BUTAN-1-ONE(4208-57-5)
• EPA Substance Registry System: 1-(2-FURYL)BUTAN-1-ONE(4208-57-5)

Safety Data

• Hazardous Substances Data: 4208-57-5(Hazardous Substances Data)

Usage

Chemical Properties

Colorless liquid; balsamic aroma

InChI:InChI=1/C8H10O2/c1-2-4-7(9)8-5-3-6-10-8/h3,5-6H,2,4H2,1H3

Upstream product

• 98-01-1 furfural 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 110-00-9 furan 
• 107-92-6 butyric acid 
• 527-69-5 2-furancarbonyl chloride 
• 18257-69-7 n-C₃H₇HgI 
• 927-77-5 n-propylmagnesium bromide 
• 72667-24-4 Brenzschleimsaeurenitril 
• 100059-37-8 2-ethyl-3-[2]furyl-3-oxo-propionic acid ethyl ester 
• 32488-17-8 N,N-diethyl furan 2-carboxamide 
• 10557-57-0 propylmagnesium iodide 
• 4208-62-2 1-(2-furyl)butan-1-ol 
• 56-23-5 tetrachloromethane 
• 88-14-2 2-furanoic acid 

Downstream Products

• 83463-06-3 2-Ethyl-1,5-di-furan-2-yl-4-methyl-3-phenyl-pentane-1,5-dione 
• 88-14-2 2-furanoic acid 
• 4208-45-1 2-bromo-1-(furan-2-yl)butan-1-one 
• 1305253-09-1 1-[5-(4-nitrophenyl)furan-2-yl]butan-1-one 
• 1305253-07-9 1-[5-(4-acetylphenyl)furan-2-yl]butan-1-one 
• 1305253-13-7 1-[5-(3-formylphenyl)furan-2-yl]butan-1-one 
• 1209985-62-5 1-[5-(4-fluorophenyl)furan-2-yl]butan-1-one 
• 1209985-61-4 1-[5-(4-formylphenyl)furan-2-yl]butan-1-one 
• 1209985-60-3 1-[5-(4-trifluoromethylphenyl)furan-2-yl]butan-1-one 
• 1209985-65-8 1-[5-(2-cyanophenyl)furan-2-yl]butan-1-one 
• 1209985-59-0 1-[5-(4-cyanophenyl)furan-2-yl]butan-1-one 
• 1209985-63-6 1-[5-(4-methylphenyl)furan-2-yl]butan-1-one 
• 1209985-64-7 1-[5-(4-t-butylphenyl)furan-2-yl]butan-1-one 
• 64258-96-4 n-Propyl-2-(5-nitrofuryl)-keton 

Relevant articles and documents

Rh-Catalyzed Coupling of Aldehydes with Allylboronates Enables Facile Access to Ketones

We present herein a novel strategy for the preparation of ketones from aldehydes and allylic boronic esters. This reaction involves the allylation of aldehydes with allylic boronic esters and the Rh-catalyzed chain-walking of homoallylic alcohols. The key to this successful development is the protodeboronation of alkenyl borylether intermediate via a tetravalent borate anion species in the presence of KHF2 and MeOH. This approach features mild reaction conditions, broad substrate scope, and excellent functional group tolerance. Mechanistic studies also supported that the tandem allylation and chain-walking process were involved.

Unexpectedly high activity of Zn(OTf)2·6H2O in catalytic Friedel-Crafts acylation reaction

Zn(OTf)2·6H2O was used to promote Friedel-Crafts acylation of aromatics. The work describes the high activity and efficiency of Zn(OTf)2·6H2O in acylation of aromatics, and the catalyst has surpassed most metal triflates in dispensing when dried at high temperature under vacuum before use. Copyright Taylor & Francis Group, LLC.

Friedel-Crafts acylation of furan and thiophene using ytterbium(III) trifluoromethanesulfonate in [BPy][BF4] ionic liquid

Friedel-Crafts reactions of furan and thiophene have been catalyzed by ytterbium(III) trifluoromethanesulfonate in [BPy][BF4] (n-butylpyridinium tetrafluoroborate) ionic liquid to produce intermediates of pharmaceuticals with good yields. The catalyzing system [BPy][BF 4]/Yb(OTf)3 could be reused.