4472-81-5

Basic information

• Product Name: DITHIOLAN-2-IMINE
• Synonyms: DITHIOLAN-2-IMINE
• CAS NO: 4472-81-5
• Molecular Formula: C₃H₅NS₂
• Molecular Weight: 119.21
• Mol File: 4472-81-5.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: DITHIOLAN-2-IMINE(CAS DataBase Reference)
• NIST Chemistry Reference: DITHIOLAN-2-IMINE(4472-81-5)
• EPA Substance Registry System: DITHIOLAN-2-IMINE(4472-81-5)

Safety Data

• Hazardous Substances Data: 4472-81-5(Hazardous Substances Data)

Usage

Uses

Used in Agricultural Industry:
DITHIOLAN-2-IMINE is used as a metabolite in the insecticide Cyolane for its effectiveness in controlling larvae of all stages. The insecticide is known for its persistence over a long period of time, making it a valuable tool in pest management.
Used in Toxicology Research:
DITHIOLAN-2-IMINE is used as a subject of study in toxicology research due to its association with Cyolane, which is known to be toxic and cause asthmatic inflammatory reactions in the lungs of juvenile rats. Understanding the effects of this compound can help in developing safer alternatives or methods to mitigate its harmful effects.

Upstream product

• 420-12-2 thirane 
• 333-20-0 potassium thioacyanate 
• 64-19-7 acetic acid 
• 629-17-4 1,2-bis(thiocyanato)ethane 
• 540-63-6 ethane-1,2-dithiol 
• 68927-87-7 pentacarbonyl(trichloromethyl isocyanide)chromium 

Downstream Products

• 110-04-3 ethane-1,2-disulphonic acid 
• 1940-01-8 [1,2,5,6]tetrathiocane 
• 540-63-6 ethane-1,2-dithiol 
• 15719-64-9 methylammonium carbonate 
• 86674-05-7 N-5[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrobenzoyl-2-imino-1,3-dithiolane 

Relevant articles and documents

Reaktionen am koordinierten Trichlormethylisocyanid. II. Cyclische Dithio- und Diaminocarbene

Cr(CO)5CNCCl3 (1) and 1,2-dithioles in the presence of triethylamine react with cleavage of the CN triple bond to give the 1,3-dithiolane-2-ylidene complexes (R=H (2a), Me (2b)); the other fragment, NCCl3 has been found in the by-products 2-imino-1,3-dithiolane (3) and triethylammonium chloride.The diamines H2NCH2CHRNH2 (R=H, Me), H2NCH2CH2NHMe, and H2N(CH2)3NH2, by analogy, give cyclic diaminocarbene species, while functional isocyanides in the form of Cr(CO)5CN(CH2)4NH2 (6) (main product) and (OC)5CrCN(CH2)4NCCr(CO)5 (7) result from the reaction of 1 with 1,4-diaminobutane.As a deviant from this reaction scheme, N,N'-dimethyldiaminoethane adds across both electrophilic C-centers in 1 to give carbenoid sevenmembered triazepane ring system of which the crystal structure is reported.In the reaction of 2a with triphenylphosphine CO-substitution occurs with formation of (11), amines, such as H2NCH2CH2OH or H2NCH2CH2OMe, on the other hand, attack the cyclic dithiocarbene ligand in 2a and 11 to give Cr(CO)5CNCH2CH2OH (10) and cis-Cr(CO)4(CNCH2CH2OMe)PPh3 (12), respectively.