466686-17-9

Basic information

• Product Name: (E)-4-oxo-1-phenylbut-2-en-1-yl acetate
• Synonyms: (E)-4-oxo-1-phenylbut-2-en-1-yl acetate
• CAS NO: 466686-17-9
• Molecular Weight: 204.225
• Mol File: 466686-17-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-4-oxo-1-phenylbut-2-en-1-yl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-4-oxo-1-phenylbut-2-en-1-yl acetate(466686-17-9)
• EPA Substance Registry System: (E)-4-oxo-1-phenylbut-2-en-1-yl acetate(466686-17-9)

Safety Data

• Hazardous Substances Data: 466686-17-9(Hazardous Substances Data)

Upstream product

• 108-24-7 acetic anhydride 
• 100-59-4 phenylmagnesium chloride 
• 51801-01-5 (E)-1-acetoxy-1-phenyl-2-butene 

Downstream Products

• 466686-19-1 (2E,4E)-6-acetoxy-6-phenylhexa-2,4-dienal 
• 1403749-16-5 (2R,3E)-methyl 2-fluoro-4-phenylbut-3-enoate 
• 466686-24-8 (1E,3E,5E)-7-acetoxy-N-isopropyl-7-phenyl-1-azahepta-1,3,5-triene 
• 127392-19-2 <2-methyl-5-(1E)-phenylethenyl>-furan 
• 1202-49-9 (E)-2-styrylfuran 
• 40025-25-0 (E)-5-phenyl-2-(2-phenylvinyl)furan 
• 17113-33-6 2-phenylfuran 
• 466686-22-6 (1E,3E)-5-acetoxy-N-isopropyl-5-phenyl-1-azapenta-1,3-diene 
• 466686-20-4 (2E,4E)-6-acetoxy-1,6-diphenylhexa-2,4-dien-1-one 
• 466686-21-5 (3E,5E)-7-acetoxy-7-phenylhepta-3,5-dien-2-one 

Relevant articles and documents

Enantioselective synthesis of β,γ-unsaturated α-fluoroesters catalyzed by N-heterocyclic carbenes

NHC meets F: NHC-bound enolates undergo a catalytic asymmetric fluorination reaction to β,γ-unsaturated α-fluoroesters, which are obtained with good efficiency and stereoselectivity (see scheme, NFSI=N- fluorobenzenesulfonimide). The strategy overcomes possible challenges, such as fluorination in the γ position and difluorination. Experimental evidence combined with DFT calculations provides insight into the reaction mechanism. Copyright