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2-benzyl-N-methylaniline is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 51570-52-6 Structure
  • Basic information

    1. Product Name: 2-benzyl-N-methylaniline
    2. Synonyms: 2-benzyl-N-methylaniline
    3. CAS NO:51570-52-6
    4. Molecular Formula: C14H15N
    5. Molecular Weight: 197.2756
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 51570-52-6.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 329.8°Cat760mmHg
    3. Flash Point: 161°C
    4. Appearance: /
    5. Density: 1.047g/cm3
    6. Vapor Pressure: 0.000173mmHg at 25°C
    7. Refractive Index: 1.608
    8. Storage Temp.: N/A
    9. Solubility: N/A
    10. CAS DataBase Reference: 2-benzyl-N-methylaniline(CAS DataBase Reference)
    11. NIST Chemistry Reference: 2-benzyl-N-methylaniline(51570-52-6)
    12. EPA Substance Registry System: 2-benzyl-N-methylaniline(51570-52-6)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 51570-52-6(Hazardous Substances Data)

51570-52-6 Usage

Synthesis Reference(s)

Synthetic Communications, 18, p. 1035, 1988 DOI: 10.1080/00397918808060888

Check Digit Verification of cas no

The CAS Registry Mumber 51570-52-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,1,5,7 and 0 respectively; the second part has 2 digits, 5 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 51570-52:
(7*5)+(6*1)+(5*5)+(4*7)+(3*0)+(2*5)+(1*2)=106
106 % 10 = 6
So 51570-52-6 is a valid CAS Registry Number.
InChI:InChI=1/C14H15N/c1-15-14-10-6-5-9-13(14)11-12-7-3-2-4-8-12/h2-10,15H,11H2,1H3

51570-52-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-benzyl-N-methylaniline

1.2 Other means of identification

Product number -
Other names 2-benzyl-N-methyl-aniline

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:51570-52-6 SDS

51570-52-6Relevant articles and documents

Radical and ionic mechanisms in rearrangements of o-tolyl aryl ethers and amines initiated by the Grubbs-stoltz reagent, et3SiH/KOtbu

Kolodziejczak, Krystian,Murphy, John A.,Stewart, Alexander J.,Tuttle, Tell

, (2021/12/04)

Rearrangements of o-tolyl aryl ethers, amines, and sulfides with the Grubbs-Stoltz reagent (Et3SiH + KOtBu) were recently announced, in which the ethers were converted to o-hydroxydiarylmethanes, while the (o-tol)(Ar)NH amines were transformed into dihydroacridines. Radical mechanisms were proposed, based on prior evidence for triethylsilyl radicals in this reagent system. A detailed computational investigation of the rearrangements of the aryl tolyl ethers now instead supports an anionic Truce-Smiles rearrangement, where the initial benzyl anion can be formed by either of two pathways: (i) direct deprotonation of the tolyl methyl group under basic conditions or (ii) electron transfer to an initially formed benzyl radical. By contrast, the rearrangements of o-tolyl aryl amines depend on the nature of the amine. Secondary amines undergo deprotonation of the N-H followed by a radical rearrangement, to form dihydroacridines, while tertiary amines form both dihydroacridines and diarylmethanes through radical and/or anionic pathways. Overall, this study highlights the competition between the reactive intermediates formed by the Et3SiH/KOtBu system.

Thermal reactions of N-Alkyl-2-benzylaniline and N-Alkyl-N′-phenyl-o- phenylenediamine: An unusual route to 2-phenylindole and 2-phenylbenzimidazole

Creencia, Evelyn Cuevas,Taguchi, Kei,Horaguchi, Takaaki

, p. 837 - 843 (2008/09/21)

(Chemical Equation Presented) Thermal cyclization reactions of N-alkyl-2-benzylaniline 1a-d and N-alkyl-N′-phenyl-o-phenylenediamine 2a-b were carried out expecting to get seven-membered heterocyclic compounds. However, the results show that aside from th

A SYNTHETIC EQUIVALENT FOR ORTHO-LITHIO-N-METHYLANILINE

Sisko, Joseph,Weinreb, Steven M.

, p. 1035 - 1042 (2007/10/02)

o-Bromo-N-methyl-N-n-propoxyaniline undergoes halogen-metal exchange with butyllithium and the resulting lithio species reacts cleanly with a variety of electrophiles.The N-O bond of these products can be reduced with Raney nickel to afford ortho-substituted-N-methylanilines.

MOLECULAR REARRANGEMENTS, XVIII. PHOTOLYSIS OF N-ALKYL-ARYLAMINES

Aly, Morsy M.,Badr, Mahmoud Zarif A.,Fahmy, Attiat M.,Mahgoub, Safaa A.

, p. 15 - 22 (2007/10/02)

The direct photolysis of N-benzyl-N-methyl-aniline in isopropanol at 25 deg C for 15 hours in air gives benzaldehyde, toluene, bibenzyl, N-methylaniline and a mixture of o- and p-benzyl-N-methylaniline.Analogous products are also obtained from the photolysis of N-α- or -β-phenethyl-N-methyl-aniline in addition to trans-2,3-diphenylbutene-2 and 9,10-dimethyl-phenanthrene.The results are interpreted in terms of an intramolecular free radical mechanism starting by homolysis of the N-aralkyl bond into N-methyl-anilino and aralkyl free radicals that subsequently contribute to the formation of the identified products.

Recyclization of 2-(2-Phenylethyl)pyridinium Salts

Yudin, L. G.,Rumyantsev, A. N.,Sagitullin, R. S.,Kost, A. N.

, p. 57 - 59 (2007/10/02)

Under the influence of aqueous solutions of alkylammonium sulfites 2-(2-phenylethyl)pyridinium salts undergo recyclization to 2-benzyl-N-alkylanilines.The effect of structural factors on the transamination, which takes place when a reagent with an alkyl g

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