60187-14-6

Basic information

• Product Name: (C₆H₅As)2Mo₆O₂₄^(4-)*4(C₄H₉)4N⁽¹⁺⁾=[(C₆H₅As)2Mo₆O₂₄](N(C₄H₉)4)4
• Synonyms: (C₆H₅As)2Mo₆O₂₄^(4-)*4(C₄H₉)4N⁽¹⁺⁾=[(C₆H₅As)2Mo₆O₂₄](N(C₄H₉)4)4
• CAS NO: 60187-14-6
• Molecular Weight: 2233.55
• Mol File: 60187-14-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (C₆H₅As)2Mo₆O₂₄^(4-)*4(C₄H₉)4N⁽¹⁺⁾=[(C₆H₅As)2Mo₆O₂₄](N(C₄H₉)4)4(CAS DataBase Reference)
• NIST Chemistry Reference: (C₆H₅As)2Mo₆O₂₄^(4-)*4(C₄H₉)4N⁽¹⁺⁾=[(C₆H₅As)2Mo₆O₂₄](N(C₄H₉)4)4(60187-14-6)
• EPA Substance Registry System: (C₆H₅As)2Mo₆O₂₄^(4-)*4(C₄H₉)4N⁽¹⁺⁾=[(C₆H₅As)2Mo₆O₂₄](N(C₄H₉)4)4(60187-14-6)

Safety Data

• Hazardous Substances Data: 60187-14-6(Hazardous Substances Data)

Upstream product

• 7631-95-0 sodium molybdate dihydrate 
• 98-05-5 phenylarsonic acid 
• 1643-19-2 tetrabutylammomium bromide 

Downstream Products

• 98509-06-9 (C₆H₅As)Mo₇O₂₅^(4-)*4(C₄H₉)4N⁽¹⁺⁾=[(C₆H₅As)Mo₇O₂₅](N(C₄H₉)4)4 

Relevant articles and documents

Mechanistic Polyoxoanion Chemistry: Intramolecular Rearrengements of the α-Mo8O26(4-), C6H5AsMo7O25(4-), and (C6H5As)2Mo6O24(4-) Anions

The dynamic behavior of the α-Mo8O26(4-), C6H5AsMo7O25(4-), and (C6H5As)2Mo6O24(4-) anions as (n-C4H9)4N(1+) salts in CH3CN has been studied by using variable-temperature (17)O NMR line-shape analysis, (17)O spin saturation transfer techniques, and (17)O label crossover experiments.The C6H5AsMo7O25(4-) anions shows two distinct types of fluxional behavior that can be related to the anion's structure, a puckered Mo6O18 ring capped on opposite sides by tridentate tetrahedral MoO4(2-) and C6H5AsO3(2-) units.The low-temperature process involves Mo6O18 ring inversion accompained by twisting of the C6H5AsO3(2-) subunit and twisting or flipping of the MoO4(2-) subunit.Only weak (> 2.2 Angstroem) molybdenum-oxygen bonds are broken and reformed.The higher temperature process, although mechanistically undefined, involves cleavage of stronger (1.7-2.0 Angstroem) molybdenum-oxygen bonds.Evidence is presented for related processes in the α-Mo8O26(4-) and (C6H5As)2Mo6O24(4-) anions.Possibilities for observing related ring inversions and reorientations of tetrahedral subunits in other early transition-metal polyoxoanions are also discussed.