61771-76-4Relevant articles and documents
Synthesis of Bicyclic Cyclopentanols by Photoreductive Cyclization of δ,ε-Unsaturated Ketones
Belotti, D.,Cossy, J.,Pete, J. P.,Portella, C.
, p. 4196 - 4200 (1986)
Bicyclic cyclopentanols were synthesized by intramolecular radical addition from photochemically induced electron transfer to δ,ε-unsaturated ketones.The donor was HMPA (neat) or Et3N (in CH3CN).Irradiation of δ,ε-ethylenic ketones and β-keto esters in HM
Highly selective hydrosilylation of equilibrating allylic azides
Liu, Ruzhang,Liu, Yongmei,Wang, Juan,Wei, Zhen,Xue, Huaiguo
supporting information, p. 5038 - 5041 (2020/05/18)
The Pt-catalyzed hydrosilylation of equilibrating allylic azides is reported. The reaction provides only one out of four possible hydrosilylation products in good yields and with very high chemoselectivity (alk-1-enevs.alk-2-ene), regioselectivity (linearvs.branched), and excellent functional group tolerance.
Synthesis of gem-difluoromethylenated bicyclo[ m.n. 0]alkan-1-ols and their ring-expansion to gem-difluoromethylenated macrocyclic lactones
Punirun, Teerachai,Peewasan, Krisana,Kuhakarn, Chutima,Soorukram, Darunee,Tuchinda, Patoomratana,Reutrakul, Vichai,Kongsaeree, Palangpon,Prabpai, Samran,Pohmakotr, Manat
supporting information; experimental part, p. 1820 - 1823 (2012/07/03)
Fluoride-catalyzed stereoselective nucleophilic addition of PhSCF 2SiMe3 (1) to α-carboethoxycycloalkanones 2 followed by intramolecular radical cyclization of the resulting cis-3 adduct afforded the corresponding gem-difluoromethyle
