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CAS

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6600-42-6

1-Vinyladamantane is an organic compound with the molecular formula C13H18. It is a derivative of adamantane, a highly symmetrical and stable carbon cage structure, with a vinyl group (C2H3) attached to one of its carbon atoms. This modification introduces a double bond and an additional carbon atom to the molecule, altering its chemical properties and reactivity. 1-Vinyladamantane is of interest in organic chemistry due to its unique structure and potential applications in the synthesis of various compounds, such as polymers and pharmaceuticals. Its stability and resistance to chemical reactions make it a valuable building block for creating new materials with specific properties.

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  • 6600-42-6 Structure

  • Basic information

    1. Product Name: 1-vinyladamantane
    2. Synonyms: 1-vinyladamantane
    3. CAS NO:6600-42-6
    4. Molecular Formula:
    5. Molecular Weight: 162.275
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 6600-42-6.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 1-vinyladamantane(CAS DataBase Reference)
    10. NIST Chemistry Reference: 1-vinyladamantane(6600-42-6)
    11. EPA Substance Registry System: 1-vinyladamantane(6600-42-6)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 6600-42-6(Hazardous Substances Data)

6600-42-6 Usage

Derived from

Adamantane

Structure

Cage-like, diamondoid

Usage

Monomer for polymerization

Usage

Precursor in the synthesis of various organic compounds

Usage

Production of polymers with high thermal stability

Usage

Resistance to chemicals and solvents

Potential use

Drug delivery systems

Potential use

Building block for the synthesis of novel materials

Applications

Industrial and research purposes

Check Digit Verification of cas no

The CAS Registry Mumber 6600-42-6 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,6,0 and 0 respectively; the second part has 2 digits, 4 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 6600-42:
(6*6)+(5*6)+(4*0)+(3*0)+(2*4)+(1*2)=76
76 % 10 = 6
So 6600-42-6 is a valid CAS Registry Number.

6600-42-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-(1-adamantyl)ethene

1.2 Other means of identification

Product number -
Other names 1-vinyl-adamantane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:6600-42-6 SDS

6600-42-6Relevant articles and documents

A short-cut from 1-acetyl adamantane to 2-(1-adamantyl)pyrroles

Trofimov, Boris A.,Schmidt, Elena Yu.,Zorina, Nadezhda V.,Senotrusova, Elena Yu.,Protsuk, Nadezhda I.,Ushakov, Igor A.,Mikhaleva, Al'bina I.,Méallet-Renault, Rachel,Clavier, Gilles

, p. 4362 - 4365 (2008/09/21)

The oxime of 1-acetyl adamantane 2 is added to acetylene (KOH/DMSO, 70 °C, initial acetylene pressure 13 atm, 30 min) to afford the corresponding O-vinyl oxime 5 in 80% yield. The latter upon heating (DMSO, 120 °C, 1 h) gives 2-(1-adamantyl)pyrrole 3, 1-acetyl adamantane 1, and adamantane (6:3:1 mass ratio), the yield of the pyrrole 3 being 83% (based on 1-acetyl adamantane 1 consumed). Under harsher conditions (NaOH/DMSO, 130 °C, atmospheric pressure of acetylene, 4 h) oxime 2 reacts with acetylene to furnish pyrrole 3, 1-acetyl adamantane 1, 1-vinyl adamantane 9, and adamantane (6:7:3:1 mass ratio), with the isolated yield of pyrrole 3 reaching 34%. Under pressure (NaOH/DMSO, 120 °C, initial acetylene pressure 14 atm, 1 h) the same reaction leads to 2-(1-adamantyl)-1-vinylpyrrole 4 and ketone 1 in 48% (based on consumed ketone 1) and 24% yields, respectively. The pyrrole 4 is easily deprotected to the corresponding 1H-pyrrole 3 in 77% yield by treatment (aqueous MeCN) with Hg(OAc)2 and NaBH4.

Preparation of olefins and acetylenes via reductive elimination with Sml2-HMPA

Ihara, Masataka,Suzuki, Shuichi,Taniguchi, Takahiko,Tokunaga, Yuji,Fukumoto, Keiichiro

, p. 9873 - 9890 (2007/10/02)

Reaction of β-hydroxy or acetoxy sulfones with Sml2 in the presence of HMPA caused effectively reductive elimination to provide olefins. Treatment of enol phosphates, readily synthesized from β-hydroxy sulfones via keto sulfones, under the same conditions efficiently produced mono- and disubstituted acetylenes.

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