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METHYL 4-METHOXY-3-METHYLBENZOATE, also known as methyl ferulate, is an organic compound with the chemical formula C10H12O3. It is a colorless to pale yellow liquid characterized by a sweet, fruity odor. METHYL 4-METHOXY-3-METHYLBENZOATE is recognized for its potential applications in various industries, including its use as a flavoring agent in the food industry, its role in the synthesis of pharmaceuticals, and its potential in medicine and cosmetics due to its antioxidant and anti-inflammatory properties.

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  • 70347-04-5 Structure
  • Basic information

    1. Product Name: METHYL 4-METHOXY-3-METHYLBENZOATE
    2. Synonyms: METHYL 4-METHOXY-3-METHYLBENZOATE;RARECHEM AL BF 0539;BENZOIC ACID, 4-METHOXY-3-METHYL-, METHYL ESTER
    3. CAS NO:70347-04-5
    4. Molecular Formula: C10H12O3
    5. Molecular Weight: 180.2
    6. EINECS: N/A
    7. Product Categories: Acids & Esters;Anisoles, Alkyloxy Compounds & Phenylacetates
    8. Mol File: 70347-04-5.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 269.5 °C at 760 mmHg
    3. Flash Point: 107.5 °C
    4. Appearance: /
    5. Density: 1.075 g/cm3
    6. Refractive Index: N/A
    7. Storage Temp.: Sealed in dry,Room Temperature
    8. Solubility: N/A
    9. CAS DataBase Reference: METHYL 4-METHOXY-3-METHYLBENZOATE(CAS DataBase Reference)
    10. NIST Chemistry Reference: METHYL 4-METHOXY-3-METHYLBENZOATE(70347-04-5)
    11. EPA Substance Registry System: METHYL 4-METHOXY-3-METHYLBENZOATE(70347-04-5)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 70347-04-5(Hazardous Substances Data)

70347-04-5 Usage

Uses

Used in the Food Industry:
METHYL 4-METHOXY-3-METHYLBENZOATE is used as a flavoring agent for its sweet, fruity odor, particularly in the production of fruit-flavored products, enhancing the taste and aroma of these items.
Used in Pharmaceutical Synthesis:
METHYL 4-METHOXY-3-METHYLBENZOATE is used as a key intermediate in the synthesis of various pharmaceuticals, contributing to the development of new medications.
Used in Medicine and Cosmetics:
METHYL 4-METHOXY-3-METHYLBENZOATE is used as an ingredient in medicine and cosmetics due to its antioxidant and anti-inflammatory properties, which are beneficial for skin health and the treatment of various conditions.
Used in Health and Wellness Products:
Given its natural antioxidant and anti-inflammatory properties, METHYL 4-METHOXY-3-METHYLBENZOATE is used in the development of natural-based health and wellness products, catering to consumers seeking natural alternatives for health maintenance and improvement.

Check Digit Verification of cas no

The CAS Registry Mumber 70347-04-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,0,3,4 and 7 respectively; the second part has 2 digits, 0 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 70347-04:
(7*7)+(6*0)+(5*3)+(4*4)+(3*7)+(2*0)+(1*4)=105
105 % 10 = 5
So 70347-04-5 is a valid CAS Registry Number.

70347-04-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name METHYL 4-METHOXY-3-METHYLBENZOATE

1.2 Other means of identification

Product number -
Other names methyl 4-methoxy-3-methyl-benzoate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:70347-04-5 SDS

70347-04-5Relevant articles and documents

Electro-Oxidative Selective Esterification of Methylarenes and Benzaldehydes

Yu, Congjun,?zkaya, Bünyamin,Patureau, Frederic W.

supporting information, p. 3682 - 3687 (2021/02/01)

A mild and green electro-oxidative protocol to construct aromatic esters from methylarenes and alcohols is herein reported. Importantly, the reaction is free of metals, chemical oxidants, bases, acids, and operates at room temperature. Moreover, the design of the electrolyte was found critical for the oxidation state and structure of the coupling products, a rarely documented effect. This electro-oxidative coupling process also displays exceptional tolerance of many fragile easily oxidized functional groups such as hydroxy, aldehyde, olefin, alkyne, as well as neighboring benzylic positions. The enantiomeric enrichment of some chiral alcohols is moreover preserved during this electro-oxidative coupling reaction, making it overall a promising synthetic tool.

NITROGEN-CONTAINING HETEROCYCLIC COMPOUND AND COMPOSITION THEREOF, PREPARATION METHOD THEREFOR, AND APPLICATION THEREOF

-

Paragraph 0328-0329, (2021/10/07)

Disclosed by the present invention are a nitrogen-containing heterocyclic compound, and a composition thereof, a preparation method therefor and an application thereof. The structure of the nitrogen-containing heterocyclic compound according to the presen

Divergent Diels-Alder methodology from methyl coumalate toward functionalized aromatics

Lee, Jennifer J.,Kraus, George A.

supporting information, p. 2366 - 2368 (2013/06/26)

An inverse electron-demand Diels-Alder reaction between methyl coumalate and electron-rich dienophiles produces substituted benzoates. A high-yielding, single-pot procedure transforms readily accessible vinyl ether, ketal, or orthoester dienophiles into functionalized aromatic systems in a versatile route.

CYCLYLAMINE DERIVATIVES AS CALCIUM CHANNEL BLOCKERS

-

Page/Page column 10-11, (2009/10/31)

Methods and compounds effective in ameliorating conditions characterized by unwanted calcium channel activity, particularly unwanted N-type and/or T-type calcium channel activity are disclosed. Specifically, a series of compounds of substituted or unsubstituted cyclylamine derivatives as shown in formulas (1).

Design, synthesis and identification of novel colchicine-derived immunosuppressant

Chang, Dong-Jo,Yoon, Eun-Young,Lee, Geon-Bong,Kim, Soon-Ok,Kim, Wan-Joo,Kim, Young-Myeong,Jung, Jong-Wha,An, Hongchan,Suh, Young-Ger

scheme or table, p. 4416 - 4420 (2010/04/05)

Synthesis and biological evaluation of various colchicine analogues through the mixed-lymphocyte reaction (MLR), lymphoproliferation, and inhibitory effects on the inflammatory genes are described. In addition, a new series of immunosuppressive agents developed on the structural basis of colchicine, as well as their structure-activity relationships is reported. The most potent analogue 20a exhibited an excellent immunosuppressive activity on in vivo skin-allograft model, which is comparable to that of cyclosporin A.

8-OXOADENINE COMPOUND

-

Page/Page column 139, (2010/11/24)

An 8-oxoadenine compound useful as an immuno-modulator having specific activity against Th1/Th2, specifically a prophylactic and therapeutic agent for a topical application for allergic diseases, viral siseases and cancers, which is represented by the following formula (1): , wherein A is a group of a formula represented by the formula (2): , wherein R2 is a substituted or unsubstituted alkyl group and so on, R3 is hydrogen atom or an alkyl group, R is a halogen atom and so on, n is 0-2, X1 is oxygen atom, Z is straight or branched chain alkylene, and R1 is an alkyl group which is optionally substituted by hydroxy group, an alkoxy group, alkoxycarbonyl group and so on, or its pharmaceutically acceptable salt.

Diels-Alder Reactions with 2H-Pyran-2-ones: Reactivity and Selectivity

Effenberger, Franz,Ziegler, Thomas

, p. 1339 - 1346 (2007/10/02)

2H-Pyran-2-ones 1 react with maleic anhydride (2) in a double Diels-Alder reaction to give bicyclooct-2-ene-5,6:7,8-tetracarboxylic dianhydrides 5; the syn/syn structure was established.As expected, the reactivity of 1 was increased by electron donor substituents (OR, alkyl) and diminished by electron withdrawing substituents (CO2R).The steric influence of substituents at C-6 also decrease the reactivity of 1. - Methyl propiolate (6) and phenylacetylene (9) react with 1 to form the Diels-Alder products 7 which suffer CO2 elimination to yield methyl benzoates 8 with low and biphenyls 10 with high regioselectivity, respectively.

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