72332-16-2

Basic information

• Product Name: m-TFO^(1-)
• Synonyms: m-TFO^(1-)
• CAS NO: 72332-16-2
• Molecular Weight: 161.103
• Mol File: 72332-16-2.mol

Chemical Properties

• CAS DataBase Reference: m-TFO^(1-)(CAS DataBase Reference)
• NIST Chemistry Reference: m-TFO^(1-)(72332-16-2)
• EPA Substance Registry System: m-TFO^(1-)(72332-16-2)

Safety Data

• Hazardous Substances Data: 72332-16-2(Hazardous Substances Data)

Upstream product

• 98-17-9 3-Trifluoromethylphenol 

Downstream Products

• 1163712-05-7 C₇H₁₁BP^(1-) 
• 98-17-9 3-Trifluoromethylphenol 
• 36701-89-0 2-(3-Trifluoromethyl-phenoxy)-nicotinic acid 

Relevant articles and documents

The rate of excited-state proton transfer to solvent from trifluoromethylphenols in water

The proton-transfer reactions to solvent from electronically excited o-, m-, and p-(trifluoromethyl)phenols (TFOHs) in water have been investigated by picosecond time-resolved fluorescence measurements. The rate constants for the proton dissociation of o-, m-, and p-TFOH are obtained to be 2.2 × 10 9, 8.6 × 108, and 2.5 × 108 s -1, respectively. On the basis of the rate constants, the effects of substituent and deuterium isotope effects on the proton-transfer reactions are revealed. copyright

Electrochemistry of electron transfer probes. α-aryloxyacetoveratrones and implications for the mechanism of photo-yellowing of pulp1

Standard potentials (Eo) of a series of substituted α-aryloxyacetoveratrone derivatives have been determined from a correlation of the 13C NMR chemical shifts of the carbonyl group and a similar correlation (Eo vs. 13C NMR shifts) within a series of α-anilinoacetoveratrones. Using these potentials the rate constants for fragmentation of the radical anions were determined by digital simulation of the voltammetric waves. The rate contants for C O cleavage in the radical anions correlate with the pKa of the corresponding phenols. The fragmentations are all in the activated region of a general free energy relationship for this class of compound (α = 0.5). The standard potential and rate constant for fragmention of the α-guaiacoxyacetoveratrone radical anion also were determined. This species is a model compound for one of the lignin substructures. The implication of these results on the currently accepted mechanism for photo-yellowing of lignin rich paper is discussed.

Electrochemistry of electron-transfer probes. The role of the leaving group in the cleavage of radical anions of α-aryloxyacetophenones

The formal reduction potential (E°) of α-phenoxyacetophenone has been determined from the voltammetric peak potential obtained by linear sweep voltammetry in combination with the rate constant for fragmentation of the radical anion which had been determin