73870-54-9Relevant articles and documents
Enantioselective organo-SOMO cycloadditions: A catalytic approach to complex pyrrolidines from olefins and aldehydes
Jui, Nathan T.,Garber, Jeffrey A.O.,Finelli, Fernanda Gadini,MacMillan, David W.C.
supporting information; experimental part, p. 11400 - 11403 (2012/09/05)
A new method to rapidly generate pyrrolidines via a SOMO-activated enantioselective (3 + 2) coupling of aldehydes and conjugated olefins has been accomplished. A radical-polar crossover mechanism is proposed wherein olefin addition to a transient enamine
Synthesis of L-Epicapreomycidine
Teshima, Tadashi,Konishi, Kunikazu,Shiba, Tetsuo
, p. 508 - 511 (2007/10/02)
A cyclic guanidino amino acid, L-epicapreomycidine, isolated from hydrolyzates of protease inhibitors such as chymostatin and elastatinal was synthetised.This amino acid is as diastereomer of L-capreomycidine which is a component amino acid of tuberactino