74418-34-1Relevant articles and documents
Enantioselective epoxidation of tertiary allylic alcohols by chiral dihydroperoxides
Bunge, Alexander,Hamann, Hans-Jürgen,Dietz, Dennis,Liebscher, Jürgen
supporting information, p. 2446 - 2450 (2013/03/14)
gem-Dihydroperoxides were successfully used for the enantioselective epoxidation of tertiary and primary allylic alcohols. Epoxides derived from tertiary alcohols were obtained in yields up to 71% with ee's up to 52%.
Reaktionen des (+)-Thujons und (-)-Isothujons mit Formaldehyd
Brieskorn, Carl Heinz,Schwack, Wolfgang
, p. 1993 - 2000 (2007/10/02)
(+)-Thujone and (-)-isothujone react with formaldehyde to give 4β-(hydroxymethyl)thujone (1) and the 2-methylene derivatives 6 and 7.Oxidation of 1 gives thujone-4β-carboxylic acid (2) which decarboxylates to (+)-thujone. 1 is reduced to the isomeric 4β-(hydroxymethyl)- (3a, 3b) and 4-methylthujanols (4a, 4b). 3-Methylthujanol is oxidized to 4-methylthujone (5).