74503-07-4

Basic information

• Product Name: allyl chlorooxoacetate
• Synonyms: allyl chlorooxoacetate;Oxalic acid monoallyl ester chloride;2-Chloro-2-oxoacetic acid 2-propenyl ester;2-Chloro-2-oxoacetic acid allyl ester;Oxochloroacetic acid allyl ester;Allyl oxalyl chloride;2-Propen-1-yloxy chloroacetate;Allyl 2-chloro-2-oxoacetate
• CAS NO: 74503-07-4
• Molecular Formula: C₅H₅ClO₃
• Molecular Weight: 148.5444
• EINECS: 277-900-7
• Product Categories: ester series;Alkenyl;Building Blocks;Chemical Synthesis;Halogenated Hydrocarbons;Organic Building Blocks
• Mol File: 74503-07-4.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 156.6 °C at 760 mmHg
• Flash Point: 56°C
• Appearance: /
• Density: 1.213g/mLat 25℃
• Vapor Pressure: 2.87mmHg at 25°C
• Refractive Index: n20/D 1.443
• CAS DataBase Reference: allyl chlorooxoacetate(CAS DataBase Reference)
• NIST Chemistry Reference: allyl chlorooxoacetate(74503-07-4)
• EPA Substance Registry System: allyl chlorooxoacetate(74503-07-4)

Safety Data

• Hazard Codes: C
• Statements: 22-34
• Safety Statements: 26-36/37/39-45
• RIDADR: UN 2920 3(8) / PGII
• WGK Germany: 3
• Hazardous Substances Data: 74503-07-4(Hazardous Substances Data)

Usage

General Description

Allyl chlorooxoacetate is a chemical compound with the molecular formula C4H5ClO3. It is a colorless liquid that is used in the production of pharmaceuticals, agrochemicals, and other organic compounds. Allyl chlorooxoacetate is an ester, meaning it is formed from the reaction between an alcohol and an organic or inorganic acid. It is known for its strong, pungent odor and is classified as a hazardous chemical. The compound is used as a building block in organic synthesis and can be a precursor to a wide range of other chemicals. Its reactivity and ability to form new bonds make it a versatile and useful compound in the field of organic chemistry.

InChI:InChI=1/C5H5ClO3/c1-2-3-9-5(8)4(6)7/h2H,1,3H2

Upstream product

• 79-37-8 oxalyl dichloride 
• 107-18-6 allyl alcohol 

Downstream Products

• 123201-07-0 C₃₁H₃₅N₂O₉PS 
• 123201-07-0 C₃₁H₃₅N₂O₉PS 
• 123201-07-0 C₃₁H₃₅N₂O₉PS 
• 123201-07-0 C₃₁H₃₅N₂O₉PS 
• 173040-47-6 [(2R,3S)-3-[(R)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2-((1R,3S)-3-fluoro-2-oxo-cyclohexyl)-4-oxo-azetidin-1-yl]-oxo-acetic acid allyl ester 
• 299177-88-1 {(2R,3S)-3-[(R)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2-[(1S,3S)-3-(tert-butyl-dimethyl-silanyloxymethyl)-2-oxo-cyclohexyl]-4-oxo-azetidin-1-yl}-oxo-acetic acid allyl ester 
• 299177-89-2 {(2R,3S)-3-[(R)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2-[(1R,3R)-3-(tert-butyl-dimethyl-silanyloxymethyl)-2-oxo-cyclohexyl]-4-oxo-azetidin-1-yl}-oxo-acetic acid allyl ester 
• 221678-42-8 (3S,4R)-1-allyloxalyl-4-[(2S,6R)-2-[(R)-(1-allyloxycarbonyl)pyrrolidin-3-ylmethylthio]cyclohexanon-6-yl]-3-[(R)-1-(tert-butyldimethylsilyloxy)ethyl]azetidin-2-one 
• 221678-47-3 (3S,4R)-1-allyloxalyl-4-[(2S,6R)-2-[(S)-(1-allyloxycarbonyl)pyrrolidin-3-ylmethylthio]cyclohexanon-6-yl]-3-[(R)-1-(tert-butyldimethylsilyloxy)ethyl]azetidin-2-one 
• 276240-46-1 (3S,4R)-1-allyloxalyl-4-[(2S,6R)-2-[(S)-(1-allyloxycarbonyl)pyrrolidin-3-ylthiomethyl]cyclohexanon-6-yl]-3-[(R)-1-(tert-butyldimethylsilyloxy)ethyl]azetidin-2-one 
• 221678-37-1 (3S,4R)-1-allyloxalyl-4-[(2S,6R)-2-[(S)-(1-allyloxycarbonyl)pyrrolidin-2-ylmethylthio]cyclohexanon-6-yl]-3-[(R)-1-(tert-butyldimethylsilyloxy)ethyl]azetidin-2-one 
• 950187-53-8 3-(S)-[1-(R)-(tert-butyldimethylsilyloxy)-ethyl]-4-(R)-((1S)-3-(R)-butoxy-2-oxo-cyclohexyl)-allyloxalyl-azetidin-2-on 
• 950187-54-9 3-(S)-[1-(R)-(tert-butyldimethylsilyloxy)-ethyl]-4-(R)-((1R)-3-(S)-butoxy-2-oxo-cyclohexyl)-allyloxalyl-azetidin-2-on 

Relevant articles and documents

Synthesis and application of oxalic acid monoester derivatives

The invention relates to synthesis and application of oxalic acid monoester-containing compounds as shown in a general formula (I) which is described in the specification. The compounds represent a broad-spectrum efficient insecticidal and bactericidal agent structure type. The oxalic acid monoester-containing compounds can well control aphids, plutella xylostella and spodoptera exigua when used as novel insecticidal bactericides; the compounds can also be used for preventing and treating cucumber brown blotch, cucumber bacterial angular leaf spot, cucumber fusarium wilt, cucumber downy mildew, cucumber powdery mildew, tomato bacterial leaf spot and rice sheath blight. R in the general formula (I) is as defined in the specification.

New Synthesis of Penems, the Oxalimide Cyclization Reaction

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