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7511-49-1

7511-49-1

Identification

Synonyms:Benzene,1,3,5-tris(p-bromophenyl)- (6CI,7CI);1,3,5-Tri(p-bromophenyl)benzene;1,3,5-Tris(4-bromophenyl)benzene;1,3,5-Tris(p-bromophenyl)benzene;NSC 30660;

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Safety information and MSDS view more

  • Pictogram(s):IrritantXi

  • Hazard Codes:Xi

  • Signal Word:Danger

  • Hazard Statement:H318 Causes serious eye damageH413 May cause long lasting harmful effects to aquatic life

  • First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

  • Fire-fighting measures: Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.

  • Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  • Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

  • Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

Supplier and reference price view more

  • Manufacture/Brand
  • Product Description
  • Packaging
  • Price
  • Delivery
  • Purchase
  • Manufacture/Brand:TRC
  • Product Description:1,3,5-tris(4-Bromophenyl)benzene
  • Packaging:500mg
  • Price:$ 90
  • Delivery:In stock
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  • Manufacture/Brand:TCI Chemical
  • Product Description:1,3,5-Tris(4-bromophenyl)benzene >98.0%(HPLC)
  • Packaging:5g
  • Price:$ 168
  • Delivery:In stock
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  • Manufacture/Brand:TCI Chemical
  • Product Description:1,3,5-Tris(4-bromophenyl)benzene >98.0%(HPLC)
  • Packaging:1g
  • Price:$ 50
  • Delivery:In stock
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  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:1,3,5-Tris(4-bromophenyl)benzene 97%
  • Packaging:1g
  • Price:$ 59.5
  • Delivery:In stock
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  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:1,3,5-Tris(4-bromophenyl)benzene 97%
  • Packaging:5g
  • Price:$ 190
  • Delivery:In stock
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  • Manufacture/Brand:Matrix Scientific
  • Product Description:4,4''-Dibromo-5'-(4-bromophenyl)-1,1':3',1''-terphenyl 95+%
  • Packaging:5g
  • Price:$ 404
  • Delivery:In stock
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  • Manufacture/Brand:Matrix Scientific
  • Product Description:4,4''-Dibromo-5'-(4-bromophenyl)-1,1':3',1''-terphenyl 95+%
  • Packaging:1g
  • Price:$ 152
  • Delivery:In stock
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  • Manufacture/Brand:Frontier Specialty Chemicals
  • Product Description:1,3,5-Tris(4-bromophenyl)benzene 97%
  • Packaging:1g
  • Price:$ 63
  • Delivery:In stock
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  • Manufacture/Brand:Frontier Specialty Chemicals
  • Product Description:1,3,5-Tris(4-bromophenyl)benzene 97%
  • Packaging:5g
  • Price:$ 230
  • Delivery:In stock
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  • Manufacture/Brand:Crysdot
  • Product Description:4,4''-Dibromo-5'-(4-bromophenyl)-1,1':3',1''-terphenyl 95+%
  • Packaging:100g
  • Price:$ 396
  • Delivery:In stock
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Relevant articles and documentsAll total 3 Articles be found

Zirconocene bis(perfluorooctanesulfonate) s-catalyzed highly efficient synthesis of 1,3,5-triaryl benzene via cyclotrimerization of ketones

Zhang, Guo Ping,Qiu, Ren Hua,Xu, Xin Hua,Zhou, Hai Hui,Kuang, Ya Fei,Chen, Si Hai

experimental part, p. 858 - 864 (2012/01/19)

Air-stable zirconocene bis(perfluoroctanesulfonate) s [Cp 2Zr]OSO2C8F17) 2] (1) with high Lewis acidity and high thermal stability was prepared by the reaction between Cp2ZrCl2 a

A New Approach to the Stereoselective Synthesis of β-methylchalcones

Elmorsy, Saad S.,Khalil, Abdel Galel M.,Girges, M. M.,Salama, Tarek A.

, p. 1537 - 1544 (2007/10/03)

Many β-methylchalcone derivatives have been prepared from self condensation of aralkyl ketones mediated by tetrachlorosilane-ethanol in mild conditions. - Key words: aralkyl ketones; tetrachlorosilane; β-methylchalcones; triarylbenzene derivatives

Process route upstream and downstream products

Process route

para-bromoacetophenone
99-90-1

para-bromoacetophenone

1,3,5-tris(4-bromophenyl)benzene
7511-49-1

1,3,5-tris(4-bromophenyl)benzene

4,4'-Dibromdypnon
7509-25-3

4,4'-Dibromdypnon

Conditions
Conditions Yield
With zirconocene bis(perfluorooctanesulfonate); In toluene; at 110 ℃; for 6h; chemoselective reaction;
85%
4-nitrobenzoic acid methyl ester
619-50-1

4-nitrobenzoic acid methyl ester

para-bromoacetophenone
99-90-1

para-bromoacetophenone

1,3,5-tris(4-bromophenyl)benzene
7511-49-1

1,3,5-tris(4-bromophenyl)benzene

2,6-bis(p-bromophenyl)-4-(p-nitrophenyl)pyrylium tetrafluoroborate

2,6-bis(p-bromophenyl)-4-(p-nitrophenyl)pyrylium tetrafluoroborate

Conditions
Conditions Yield
With boron trifluoride diethyl etherate; In toluene; for 2h; Heating;
65%
benzoic acid methyl ester
93-58-3,5705-52-2,80226-58-0

benzoic acid methyl ester

para-bromoacetophenone
99-90-1

para-bromoacetophenone

1,3,5-tris(4-bromophenyl)benzene
7511-49-1

1,3,5-tris(4-bromophenyl)benzene

2,6-bis-(4-bromo-phenyl)-4-phenyl-pyranylium; tetrafluoroborate

2,6-bis-(4-bromo-phenyl)-4-phenyl-pyranylium; tetrafluoroborate

Conditions
Conditions Yield
With boron trifluoride diethyl etherate; In toluene; for 2h; Heating;
55%
methyl 4-methoxybenzoate
121-98-2

methyl 4-methoxybenzoate

para-bromoacetophenone
99-90-1

para-bromoacetophenone

1,3,5-tris(4-bromophenyl)benzene
7511-49-1

1,3,5-tris(4-bromophenyl)benzene

4-(4-methoxyphenyl)-2,6-di(4-bromophenyl)pyrylium tetrafluoroborate

4-(4-methoxyphenyl)-2,6-di(4-bromophenyl)pyrylium tetrafluoroborate

Conditions
Conditions Yield
With boron trifluoride diethyl etherate; In toluene; for 2h; Heating;
61%
para-bromoacetophenone
99-90-1

para-bromoacetophenone

4-methoxybenzoic acid
100-09-4

4-methoxybenzoic acid

1,3,5-tris(4-bromophenyl)benzene
7511-49-1

1,3,5-tris(4-bromophenyl)benzene

4-(4-methoxyphenyl)-2,6-di(4-bromophenyl)pyrylium tetrafluoroborate

4-(4-methoxyphenyl)-2,6-di(4-bromophenyl)pyrylium tetrafluoroborate

Conditions
Conditions Yield
With boron trifluoride diethyl etherate; In toluene; for 2h; Heating;
51%
para-bromoacetophenone
99-90-1

para-bromoacetophenone

4-nitro-benzoic acid
62-23-7

4-nitro-benzoic acid

1,3,5-tris(4-bromophenyl)benzene
7511-49-1

1,3,5-tris(4-bromophenyl)benzene

2,6-bis(p-bromophenyl)-4-(p-nitrophenyl)pyrylium tetrafluoroborate

2,6-bis(p-bromophenyl)-4-(p-nitrophenyl)pyrylium tetrafluoroborate

Conditions
Conditions Yield
With boron trifluoride diethyl etherate; In toluene; for 2h; Heating;
53%
para-bromoacetophenone
99-90-1

para-bromoacetophenone

1,3,5-tris(4-bromophenyl)benzene
7511-49-1

1,3,5-tris(4-bromophenyl)benzene

1,3-bis-(4-bromo-phenyl)-but-2<i>c</i>-en-1-one
7509-25-3

1,3-bis-(4-bromo-phenyl)-but-2c-en-1-one

cis-4,4'-Dibrom-dypnon
7509-25-3

cis-4,4'-Dibrom-dypnon

Conditions
Conditions Yield
With tetrachlorosilane; In ethanol; for 4h; Ambient temperature;
60%
5%
23%
para-bromoacetophenone
99-90-1

para-bromoacetophenone

benzoic acid
65-85-0,8013-63-6

benzoic acid

1,3,5-tris(4-bromophenyl)benzene
7511-49-1

1,3,5-tris(4-bromophenyl)benzene

2,6-bis-(4-bromo-phenyl)-4-phenyl-pyranylium; tetrafluoroborate

2,6-bis-(4-bromo-phenyl)-4-phenyl-pyranylium; tetrafluoroborate

Conditions
Conditions Yield
With boron trifluoride diethyl etherate; In toluene; for 2h; Heating;
37%
4-Bromobenzoic acid
586-76-5

4-Bromobenzoic acid

para-bromoacetophenone
99-90-1

para-bromoacetophenone

1,3,5-tris(4-bromophenyl)benzene
7511-49-1

1,3,5-tris(4-bromophenyl)benzene

2,4,6-tris(4-bromophenyl)pyrylium tetrafluoroborate

2,4,6-tris(4-bromophenyl)pyrylium tetrafluoroborate

Conditions
Conditions Yield
With boron trifluoride diethyl etherate; In toluene; for 2h; Heating;
28%
4-methoxycarbonylphenyl bromide
619-42-1

4-methoxycarbonylphenyl bromide

para-bromoacetophenone
99-90-1

para-bromoacetophenone

1,3,5-tris(4-bromophenyl)benzene
7511-49-1

1,3,5-tris(4-bromophenyl)benzene

2,4,6-tris(4-bromophenyl)pyrylium tetrafluoroborate

2,4,6-tris(4-bromophenyl)pyrylium tetrafluoroborate

Conditions
Conditions Yield
With boron trifluoride diethyl etherate; In toluene; for 2h; Heating;
31%

Global suppliers and manufacturers

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  • Shaanxi BLOOM TECH Co.,Ltd
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  • SAGECHEM LIMITED
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  • Win-Win chemical Co.Ltd
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