77868-25-8

Basic information

• Product Name: 4-(phenylthio)benzohydroxamic acid
• CAS NO: 77868-25-8
• Molecular Weight: 245.302
• Mol File: 77868-25-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-(phenylthio)benzohydroxamic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(phenylthio)benzohydroxamic acid(77868-25-8)
• EPA Substance Registry System: 4-(phenylthio)benzohydroxamic acid(77868-25-8)

Safety Data

• Hazardous Substances Data: 77868-25-8(Hazardous Substances Data)

Upstream product

• 10129-07-4 4-(phenylsulfanyl)benzoic acid ethyl ester 
• 5470-11-1 hydroxylamine hydrochloride 

Downstream Products

• 1135-14-4 4-aminophenyl phenyl sulfide 
• 6310-24-3 4-(phenylthio)benzoic acid 

Relevant articles and documents

Studies in Rearrangement of 2-(Arylthio)benzohydroxamic Acids to the Corresponding 2-(Arylsulphinyl)benzamides

2-(2'-Methoxyphenylthio)-(III)-, 2-(4'-methoxyphenylthio)-(IV)-, 2-(2'-methylphenylthio)-(V)- and 2-(4'-methylphenylthio)-(VI)-benzohydroxamic acids on treatment with polyphosphoric acid yield 2-(2'-methoxyphenylsulphinyl)-(VII)-, 2-(4'-methoxyphenylsulphinyl)-(VIII)-, 2-(2'-methylphenylsulphinyl)-(IX)- and 2-(4'-methylphenylsulphinyl)-(X)-benzamides respectively, illustrating the generality of rearrangement reported earlier .The rearrangement can also be effected with other reagents like xylene-P2O5, perchloric acid- gl. acetic acid and trifluoracetic acid. 2-Methylthiobenzohydroxamic acid (XI) and 4-(phenylthio)benzohydroxamic acid (XII) when treated with PPA yield benzothiazolone (XIII) and 4-aminodiphenyl sulphide (XIV).Experimental evidence has been presented which points to a concerted mechanism for the intramolecular oxygen transfer.